N-[(2R,3R,4R,5S,6R)-6-Benzyloxymethyl-2-methoxy-5-((2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-4-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl]-acetamide | 164216-94-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: N-[(2R,3R,4R,5S,6R)-6-Benzyloxymethyl-2-methoxy-5-((2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-4-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl]-acetamide
• CAS: 164216-94-8
• 化学式: C₄₉H₆₁NO₁₅
• 分子量: 904.021
• InChiKey: WEMDRENYBKGLIO-WZZUUHIYSA-N

反应信息

• 作为反应物：
  描述：

  N-[(2R,3R,4R,5S,6R)-6-Benzyloxymethyl-2-methoxy-5-((2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-4-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl]-acetamide 在 三甲基铵三氧化硫共聚物 、 二正丁基氧化锡 作用下， 生成 、
  参考文献：
  名称：

  Synthesis of mono-, di- and trisulfated Lewis x trisaccharides

  摘要：

  3'-Sulfated and 3',6'-disulfated Lewis x trisaccharides have been prepared through selective sulfation of methyl 2-acetamido-6-O-benzyl-2-deoxy-4-O-beta-D-galactopyranosyl-3-O-(2,3,4-tri-O-benzyl-alpha-L-fucopyranosyl)-beta-D-glucopyranoside, followed by catalytic hydrogenolysis. In a similar manner, 3',6-disulfated and 3',6,6'-trisulfated Lewis x trisaccharides have been !;electively obtained from methyl 2-acetamido-2-deoxy-4-O-beta-D-galactopyranosyl-3-O-(2,3,4-tri-O-benzyl-alpha-L-fucopyranosyl)-beta-D-glucopyranoside. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0957-4166(98)00246-8
• 作为产物：
  描述：

  在 甲醇 、 sodium methylate 作用下， 以 二氯甲烷 为溶剂， 生成 N-[(2R,3R,4R,5S,6R)-6-Benzyloxymethyl-2-methoxy-5-((2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-4-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl]-acetamide
  参考文献：
  名称：

  Synthesis of mono-, di- and trisulfated Lewis x trisaccharides

  摘要：

  3'-Sulfated and 3',6'-disulfated Lewis x trisaccharides have been prepared through selective sulfation of methyl 2-acetamido-6-O-benzyl-2-deoxy-4-O-beta-D-galactopyranosyl-3-O-(2,3,4-tri-O-benzyl-alpha-L-fucopyranosyl)-beta-D-glucopyranoside, followed by catalytic hydrogenolysis. In a similar manner, 3',6-disulfated and 3',6,6'-trisulfated Lewis x trisaccharides have been !;electively obtained from methyl 2-acetamido-2-deoxy-4-O-beta-D-galactopyranosyl-3-O-(2,3,4-tri-O-benzyl-alpha-L-fucopyranosyl)-beta-D-glucopyranoside. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0957-4166(98)00246-8

文献信息

• Jain, Rakesh K.; Vig, Rakesh; Rampal, Rajit, Journal of the American Chemical Society, <hi>1994</hi>, vol. 116, # 26, p. 12123 - 12124
  作者：Jain, Rakesh K.、Vig, Rakesh、Rampal, Rajit、Chandrasekaran、Matta, Khushi L.

  DOI：——

  日期：——