Zn[Fe(CN)5(FEPA4)] | 1228259-23-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Zn[Fe(CN)5(FEPA4)]
• 英文别名: Zn[Fe(CN)5(1-phenacylpyridinium-4-aldoxime)]
• CAS: 1228259-23-1
• 化学式: C₁₉H₁₃FeN₇O₂*Zn
• 分子量: 492.595
• InChiKey: CYOVMAQBJWYBCQ-UHFFFAOYSA-O

反应信息

• 作为产物：
  描述：

  zinc(II) nitrate 、 [FEPA4]2[Fe(CN)5(FEPA4)]*3H2O 以 水 、 溶剂黄146 为溶剂， 生成 Zn[Fe(CN)5(FEPA4)]
  参考文献：
  名称：

  Preparation, characterization and reactivity of 1-benzylpyridinium-4-aldoxime chloride and 1-phenacylpyridinium-4-aldoxime chloride and their complexes with the aquapentacyanoferrate(II) ion

  摘要：

  A detailed structural characterization of the biologically active 1-benzylpyridinium-4-aldoxime chloride and 1-phenacylpyridinium-4-aldoxime chloride was performed using NMR and vibrational and electronic spectroscopy, as well as X-ray diffraction. The complexes of these compounds with the aquapentacyanoferrate(II) ion were examined in solution, isolated as solids and characterized by elemental analysis, electronic, FT-IR and NMR spectral data. They were found to be mononuclear substituted pentacyanoferrates(II) containing the aldoxime group coordinated to the iron through the nitrogen atom. The complexes were also precipitated in the form of the respective zinc salts; the analysis of these complexes revealed a molar Fe/Zn ratio of 1, thus confirming the charge of the complex anions to be -2. The ionization constants of the aldoxime group in the free ligands and in the respective cyano complexes were also determined. Despite the presence of two donor sites in 1-phenacylpyridinium-4-aldoxime chloride, only the aldoxime group was found to be reactive. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.01.041