N-(4,4"-di-tert-butyl-1,1':3',1"-terphenyl-2'-yl)acetamide | 1403669-89-5

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: N-(4,4"-di-tert-butyl-1,1':3',1"-terphenyl-2'-yl)acetamide
• CAS: 1403669-89-5
• 化学式: C₂₈H₃₃NO
• 分子量: 399.576
• InChiKey: ITKPCFJFXYPDSP-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  N-(4,4"-di-tert-butyl-1,1':3',1"-terphenyl-2'-yl)acetamide 在 碘苯二乙酸 作用下， 以 六氟异丙醇 为溶剂， 反应 5.0h， 以75%的产率得到9-acetyl-7-tert-butyl-1-(4-tert-butylphenyl)-9H-carbazole
  参考文献：
  名称：

  Metal-Free Electrocyclization at Ambient Temperature: Synthesis of 1-Arylcarbazoles

  摘要：

  An efficient novel protocol for the construction of an hyellazole-inspired compound collection is described. Starting from 2,6-diarylacetanilides, the desired products were obtained using hypervalent iodine promoted electrocyclization. The mechanism of product formation was investigated through intramolecular competition experiments.

  DOI：

  10.1055/s-0032-1316743