| 1171059-37-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• CAS: 1171059-37-2
• 化学式: C₂₉H₃₅N₂O₄*Cd*Cl
• 分子量: 623.471
• InChiKey: SMYFSQTYIIBSGT-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  1,3-bis(4-carboxy-2,6-diisopropylphenyl)imidazolium chloride 、 cadmium(II) nitrate 以 N,N-二甲基甲酰胺 为溶剂， 生成
  参考文献：
  名称：

  Concomitant Formation of N-Heterocyclic Carbene−Copper Complexes within a Supramolecular Network in the Self-Assembly of Imidazolium Dicarboxylate with Metal Ions

  摘要：

  A new building block containing an imidazolium salt was synthesized and used for the construction of supramolecular networks with metal ions. We discovered the concomitant formation of the N-heterocyclic carbene-copper complex (CN = 2) in the self-assembly of imidazolium dicarboxylates and copper nitrates in N,N-dimethylformamide under heating. The proton in the 2 position of the imidazolium salt was abstracted, and Cu-II was reduced to Cu-I during the self-assembly process.

  DOI：

  10.1021/ic900846s