| 892123-71-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 892123-71-6
• 化学式: C₃₉H₄₄N₄O₈
• 分子量: 696.8
• InChiKey: WDHDMIZDEGYJBL-IZRQRQPJSA-N

反应信息

• 作为反应物：
  描述：

  以 乙腈 为溶剂， 生成 、
  参考文献：
  名称：

  Dynamic Control of Racemization Rate through E−Z Photoisomerization of Azobenzene and Subsequent Partial Photoresolution under Circular Polarized Light

  摘要：

  We have synthesized bicyclic azobenzene dimers that possess enantiomers whose racemization rates could be controlled reversibly through E-Z photoisomerization of the azobenzene units. Upon alternating the exposure to r- and l-CPL, we were able to repeatedly perform partial enrichment of (S)- and (R)- enantiomers, respectively.

  DOI：

  10.1021/ja058398s
• 作为产物：
  描述：

  2,2-bis{4-{2-{2-[2-(4-nitrophenoxy)ethoxy]ethoxy}ethoxy}-3-nitrophenyl}propane 在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 以3.6%的产率得到
  参考文献：
  名称：

  Dynamic Control of Racemization Rate through E−Z Photoisomerization of Azobenzene and Subsequent Partial Photoresolution under Circular Polarized Light

  摘要：

  We have synthesized bicyclic azobenzene dimers that possess enantiomers whose racemization rates could be controlled reversibly through E-Z photoisomerization of the azobenzene units. Upon alternating the exposure to r- and l-CPL, we were able to repeatedly perform partial enrichment of (S)- and (R)- enantiomers, respectively.

  DOI：

  10.1021/ja058398s