morpholinium 3-cyano-7,7-dimethyl-4-(2-nitro-phenyl)-5-oxo-1,4,5,6,7,8-hexahydroquinoline-2-thiolate | 1331829-66-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: morpholinium 3-cyano-7,7-dimethyl-4-(2-nitro-phenyl)-5-oxo-1,4,5,6,7,8-hexahydroquinoline-2-thiolate
• CAS: 1331829-66-3
• 化学式: C₄H₉NO*C₁₈H₁₇N₃O₃S
• 分子量: 442.539
• InChiKey: ILPMUWZLUJTERH-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  morpholinium 3-cyano-7,7-dimethyl-4-(2-nitro-phenyl)-5-oxo-1,4,5,6,7,8-hexahydroquinoline-2-thiolate 以 乙醇 为溶剂， 反应 8.0h， 生成 7,7-dimethyl-4-(2-nitrophenyl)-5-oxo-3-(propa-1,2-dien-1-yl)-2-thioxo-1,2,3,4,5,6,7,8-octahydroquinoline3-carbonitrile
  参考文献：
  名称：

  First example of [3,3]-sigmatropic rearrangement in the series of 2-(prop-2-yn-1-ylsulfanyl)-1,4,5,6,7,8-hexahydroquinolines

  摘要：

  DOI：

  10.1134/s1070428011070268

文献信息

• Synthesis and structure of 3-allenyl-4-aryl-7,7-dimethyl-5-oxo-2-thioxo-1,2,3,4,5,6,7,8-octahydroquinoline-3-carbonitriles
  作者：V. D. Dyachenko、M. V. Solodukha

  DOI：10.1134/s1070428011090144

  日期：2011.9

  3-Allenyl-4-aryl-7,7-dimethyl-5-oxo-2-thioxo-1,2,3,4,5,6,7,8-octahydroquinoline-3-carbonitriles were synthesized via [3,3]-sigmatropic rearrangement of 4-aryl-7,7-dimethyl-5-oxo-2-(prop-2-yn-1-ylsulfanyl)-1,4,5,6,7,8-hexahydroquinoline-3-carbonitriles. The structure of 3-allenyl-7,7-dimethyl-4-(2-nitrophenyl)-5-oxo-2-thioxo-1,2,3,4,5,6,7,8-octahydroquinolin-3-carbonitrile was determined by X-ray analysis.