(R,E)-2,4,6-trimethyloct-6-enal | 1323142-39-7

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 英文名称: (R,E)-2,4,6-trimethyloct-6-enal
• CAS: 1323142-39-7
• 化学式: C₁₁H₂₀O
• 分子量: 168.279
• InChiKey: FSBKGBOLMNPEDF-MTCBZDPGSA-N

反应信息

• 作为反应物：
  描述：

  (R,E)-2,4,6-trimethyloct-6-enal 在 哌啶 、 copper(II) acetate monohydrate 、 溶剂黄146 作用下， 以 乙醇 为溶剂， 反应 50.17h， 生成 (1R,9R,11S,14S)-9,11,14-trimethyl-13-methylidene-8-oxa-4-azatricyclo[7.5.0.02,7]tetradeca-2(7),5-dien-3-one
  参考文献：
  名称：

  Accessing the Structural Diversity of Pyridone Alkaloids: Concise Total Synthesis of Rac-Citridone A

  摘要：

  A unique route to the structural diversity of pyridone alkaloids is described based on the concept of a common synthetic strategy. Three different core structure analogues corresponding to akanthomycin, septoriamycin A, and cltridone A have been prepared by using a highly selective and novel carbocyclization reaction.

  DOI：

  10.1021/ol2017802
• 作为产物：
  描述：

  (R,E)-2,4,6-trimethyloct-6-en-1-ol 在 重铬酸吡啶 作用下， 以 二氯甲烷 为溶剂， 生成 (R,E)-2,4,6-trimethyloct-6-enal
  参考文献：
  名称：

  Accessing the Structural Diversity of Pyridone Alkaloids: Concise Total Synthesis of Rac-Citridone A

  摘要：

  A unique route to the structural diversity of pyridone alkaloids is described based on the concept of a common synthetic strategy. Three different core structure analogues corresponding to akanthomycin, septoriamycin A, and cltridone A have been prepared by using a highly selective and novel carbocyclization reaction.

  DOI：

  10.1021/ol2017802