| 1065491-23-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 1065491-23-7
• 化学式: C₁₂H₁₆O₂
• 分子量: 192.258
• InChiKey: AVPJXJFPZQUEPM-JFUSQASVSA-N

反应信息

• 作为反应物：
  描述：

  在 lead(IV) acetate 、 lithium aluminium tetrahydride 作用下， 以 苯 、 乙醚 为溶剂， 反应 96.0h， 生成
  参考文献：
  名称：

  Microwave-assisted domino reactions: function-compatibility, modulation, and greening efforts

  摘要：

  Herein we report a microwave-assisted version of a domino protocol, providing ready access to a wide variety of complex oxygen heterocycles. The latter can be converted to stereochemically, well-defined, variously substituted carbocycles, since reaction conditions and the substitution pattern can be tailored to fit a particular type of transformation. Microwave assistance, the influence of solvent, temperature, the function compatibility, and the use of PhI(OAc)(2) as a domino promoter are investigated. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetasy.2008.06.026
• 作为产物：
  描述：

  (1S,7aR)-7a-Allyl-1-hydroxy-1,2,3,6,7,7a-hexahydro-inden-5-one 在 磷酸 、 三氟化硼乙醚 作用下， 以 二氯甲烷 为溶剂， 反应 49.5h， 生成
  参考文献：
  名称：

  Microwave-assisted domino reactions: function-compatibility, modulation, and greening efforts

  摘要：

  Herein we report a microwave-assisted version of a domino protocol, providing ready access to a wide variety of complex oxygen heterocycles. The latter can be converted to stereochemically, well-defined, variously substituted carbocycles, since reaction conditions and the substitution pattern can be tailored to fit a particular type of transformation. Microwave assistance, the influence of solvent, temperature, the function compatibility, and the use of PhI(OAc)(2) as a domino promoter are investigated. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetasy.2008.06.026