| 1350890-45-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• CAS: 1350890-45-7
• 化学式: C₂₄H₂₄N₂O
• 分子量: 356.467
• InChiKey: UGRJVVSKUKKNFD-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  在 gold(III) chloride 作用下， 以 甲苯 为溶剂， 反应 1.0h， 以95%的产率得到3,6-Diethyl-2-phenyl-1-prop-2-enylpyrrolo[3,2-f]quinolin-7-one
  参考文献：
  名称：

  Gold-catalyzed heteroannulation and allyl migration: synthesis of highly functionalized indole derivatives

  摘要：

  Highly substituted indole derivatives have been prepared in good to excellent yields by a novel gold-catalyzed cyclization accompanied by [3,3]-migration of the allyl strategy. We have been able to introduce an allyl group at the Cl position of pyrano[3,2-e]indol-6(7H)-one and pyrrolo[3,2-f]quinolin-7(6H)-one moieties that provide a scope for further transformation. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.09.108
• 作为产物：
  描述：

  、 3-溴丙烯 在 potassium carbonate 、 sodium iodide 作用下， 以 丁酮 为溶剂， 反应 20.0h， 生成
  参考文献：
  名称：

  Gold-catalyzed heteroannulation and allyl migration: synthesis of highly functionalized indole derivatives

  摘要：

  Highly substituted indole derivatives have been prepared in good to excellent yields by a novel gold-catalyzed cyclization accompanied by [3,3]-migration of the allyl strategy. We have been able to introduce an allyl group at the Cl position of pyrano[3,2-e]indol-6(7H)-one and pyrrolo[3,2-f]quinolin-7(6H)-one moieties that provide a scope for further transformation. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.09.108