trihydroxy-methyl-[1,4]benzoquinone | 91808-98-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: trihydroxy-methyl-[1,4]benzoquinone
• 英文别名: Trihydroxy-methyl-[1,4]benzochinon；2,3,5-Trihydroxy-6-methylcyclohexa-2,5-diene-1,4-dione
• CAS: 91808-98-9
• 化学式: C₇H₆O₅
• 分子量: 170.122
• InChiKey: QPQIDVRCLYCYSH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  94.8
• 氢给体数：
  3
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  trihydroxy-methyl-[1,4]benzoquinone 、 乙酸酐 在 锌 作用下， 生成 2,3,4,5,6-pentaacetoxy-toluene
  参考文献：
  名称：

  The Structure of Terreic Acid

  摘要：

  DOI：

  10.1021/ja01553a055

文献信息

• COORDINATION COMPOUNDS HAVING REDOX NON-INNOCENT LIGANDS AND FLOW BATTERIES CONTAINING THE SAME
  申请人：LOCKHEED MARTIN ADVANCED ENERGY STORAGE, LLC

  公开号：US20170291916A1

  公开（公告）日：2017-10-12

  Electrolyte solutions for flow batteries and other electrochemical systems can contain an active material capable of transferring more than one electron per oxidation-reduction cycle. Such active materials can include coordination compounds containing a metal center and at least one redox non-innocent ligand. Accordingly, flow batteries can include a first half-cell having a first electrolyte solution therein, where the first electrolyte solution contains a coordination compound having at least one redox non-innocent ligand coordinated to a metal center. Particular redox non-innocent ligands can include those bearing a quinone functional group, such as substituted catecholates bearing a quinone functional group. Some active materials can include compositions containing a coordination compound having at least one redox non-innocent ligand coordinated to a metal center, where the at least one redox non-innocent ligand is a substituted catecholate or a salt thereof bearing a quinone functional group.
• US9938308B2
  申请人：——

  公开号：US9938308B2

  公开（公告）日：2018-04-10