N-(2-(4-methoxybenzylsulfanyl)ethyl)salicylaldimine | 942480-10-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: N-(2-(4-methoxybenzylsulfanyl)ethyl)salicylaldimine
• 英文别名: 2-[2-[(4-Methoxyphenyl)methylsulfanyl]ethyliminomethyl]phenol
• CAS: 942480-10-6
• 化学式: C₁₇H₁₉NO₂S
• 分子量: 301.409
• InChiKey: MWTBIDNZMGXVCZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  21
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  67.1
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  甲醇 、 N-(2-(4-methoxybenzylsulfanyl)ethyl)salicylaldimine 、 iron(II) chloride 在 Na 作用下， 以 甲醇 为溶剂， 以64%的产率得到[diiron(II) tetra(N-(2-(4-methoxybenzylsulfanyl)ethyl)salicylaldiminate)(μ-methanol)] - methanol (1/1)
  参考文献：
  名称：

  Unexpected assembly of a novel triply bridged diiron(II) core by a bidentate Schiff base ligand

  摘要：

  The unusual dinucleating properties of a simple bidentate Schiff base (LH, 1) in the presence of weakly coordinating methanol solvent lead to the self-assembly of [Fe-2(II)(L-b)(2) (L-t)(2)(mu-MeOH)] (2) (b and t refer to bridging and terminally bound ligands, respectively). Complex 2 is the first diiron(II) species in which the two metal centers are triply bridged by single atoms in an asymmetric fashion, involving both mu-O-Ph and mu-OHMe bridges. This binding mode produces an Fe center dot center dot center dot Fe distance of 3.139(1) angstrom. Dinucleation appears to be driven by a combination of ligand deficiency and solvent-mediated chemistry reminiscent of host-guest interactions. The presence of a mu-MeOH ligand is unprecedented in iron chemistry. Parallel-mode EPR spectra of complex 2 recorded at 4 K show an intense negative signal at g(parallel to) approximate to 16, suggesting the dimeric form exists in solution. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.01.001