3,4-Diethyl-oxetan-2-one | 115367-78-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 内酯类
• 英文名称: 3,4-Diethyl-oxetan-2-one
• 英文别名: 3,4-Diethyloxetan-2-one
• CAS: 115367-78-7
• 化学式: C₇H₁₂O₂
• 分子量: 128.171
• InChiKey: LWMLAFXOJZZZII-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3,4-Diethyl-oxetan-2-one 在 magnesium bromide ethyl etherate 作用下， 以 乙醚 为溶剂， 反应 10.0h， 以89.8%的产率得到dihydro-3-ethyl-5-methyl-2(3H)-furanone
  参考文献：
  名称：

  Black, T. Howard; Fields, John D., Synthetic Communications, 1988, vol. 18, # 2, p. 125 - 130

  摘要：

  DOI：
• 作为产物：
  描述：

  2-Ethyl-3-hydroxypentanoic acid 在 吡啶 、 苯磺酰氯 作用下， 以80.5%的产率得到3,4-Diethyl-oxetan-2-one
  参考文献：
  名称：

  Black, T. Howard; Fields, John D., Synthetic Communications, 1988, vol. 18, # 2, p. 125 - 130

  摘要：

  DOI：

文献信息

• BLACK, T. HOWARD;FIELDS, JOHN D., SYNTH. COMMUN., 18,(1988) N 2, 125-130
  作者：BLACK, T. HOWARD、FIELDS, JOHN D.

  DOI：——

  日期：——
• METAL-ORGANIC FRAMEWORK CATALYSTS, AND USES THEREOF
  申请人：Novomer, Inc.

  公开号：US20210277028A1

  公开（公告）日：2021-09-09

  Provided herein are metal-organic frameworks having a repeating core structure that generally includes a linker coordinated to a secondary building unit through O-metal-O bonds. The linkers create a framework with a plurality of pores, where a cobalt carbonyl moiety occupies at least a portion of the plurality of pores. Provided are also methods of making such metal-organic frameworks via a solvothermal reaction. The metal-organic frameworks are suitable for use in carbonylation reactions, such as carbonylation of epoxides. The metal-organic frameworks may be used for producing acrylic acid from ethylene oxide and carbon monoxide on an industrial scale. The production may involve various unit operations, including for example a beta-propiolactone production system configured to produce beta-propiolactone from ethylene oxide and carbon monoxide; a polypropiolactone production system configured to produce polypropiolactone from beta-propiolactone; and an acrylic acid production system configured to produce acrylic acid with a high purity by thermolysis of polypropiolactone.
• Black, T. Howard; Fields, John D., Synthetic Communications, 1988, vol. 18, # 2, p. 125 - 130
  作者：Black, T. Howard、Fields, John D.

  DOI：——

  日期：——