3-tert-Butylsulfanyl-propane-1,2-diol | 104236-16-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-tert-Butylsulfanyl-propane-1,2-diol
• 英文别名: 3-Tert-butylsulfanylpropane-1,2-diol
• CAS: 104236-16-0
• 化学式: C₇H₁₆O₂S
• 分子量: 164.269
• InChiKey: DVKAQAFYBCGLGC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  65.8
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-((t-butylthio)methyl)oxirane 在 氢氧化钾 、 乙酸酐 作用下， 生成 3-tert-Butylsulfanyl-propane-1,2-diol 、 2-(tert-butylthio)-1,3-propanediol
  参考文献：
  名称：

  Functionally substituted sulfur-containing compounds. 9. Reactions of 2-[(organylthio)methyl]oxiranes with acetic anhydride and acetyl chloride

  摘要：

  Reaction of 2-[(organylthio)methyl]oxiranes with acetic anhydride gives a mixture of 3-(organylthio)-1,2-diacetoxypropane and 2-(organylthio)-1,3-diacetoxypropane, and with acetyl chloride a mixture of 2-chloro-3-(organylthio)-1-acetoxypropane and 3-chloro-2-(organylthio)-1-acetoxypropane. In both cases, the ratio of the isomers depends on the nature of the organylthio group and on the nature of the electrophile.

  DOI：

  10.1007/bf00961238

文献信息

• KALUGIN, V. E.;LITVINOV, V. P., IZV. AN CCCP. CEP. XIM.,(1991) N, S. 1574-1578
  作者：KALUGIN, V. E.、LITVINOV, V. P.

  DOI：——

  日期：——
• PATTERNED, DENDRIMERIC SUBSTRATE SURFACES AND PRODUCTION AND USE THEREOF
  申请人：KARLSRUHER INSTITUT FÜR TECHNOLOGIE

  公开号：US20220119750A1

  公开（公告）日：2022-04-21

  The present invention relates to a patterned substrate comprising first regions having first dendrimer structures and second regions having second dendrimer structures on a surface of the substrate, as well as a to method for manufacturing a patterned substrate and the use of a patterned substrate for the chemical synthesis of a chemical synthesis product, as a characterizing platform and/or as a platform for cell treatment and/or cell cultivation.
• Functionally substituted sulfur-containing compounds. 9. Reactions of 2-[(organylthio)methyl]oxiranes with acetic anhydride and acetyl chloride
  作者：V. E. Kalugin、V. P. Litvinov

  DOI：10.1007/bf00961238

  日期：1991.7

  Reaction of 2-[(organylthio)methyl]oxiranes with acetic anhydride gives a mixture of 3-(organylthio)-1,2-diacetoxypropane and 2-(organylthio)-1,3-diacetoxypropane, and with acetyl chloride a mixture of 2-chloro-3-(organylthio)-1-acetoxypropane and 3-chloro-2-(organylthio)-1-acetoxypropane. In both cases, the ratio of the isomers depends on the nature of the organylthio group and on the nature of the electrophile.