4,5-Difluoro-2,2-bis-pentafluoroethyl-[1,3]dioxole | 130760-26-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4,5-Difluoro-2,2-bis-pentafluoroethyl-[1,3]dioxole
• 英文别名: 4,5-Difluoro-2,2-bis(1,1,2,2,2-pentafluoroethyl)-1,3-dioxole
• CAS: 130760-26-8
• 化学式: C₇F₁₂O₂
• 分子量: 344.057
• InChiKey: HBWGPNJPCBADFN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  21
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  14

反应信息

• 作为反应物：
  描述：

  4,5-Difluoro-2,2-bis-pentafluoroethyl-[1,3]dioxole 以90%的产率得到2-Fluoro-3,3-bis-pentafluoroethyl-oxirane-2-carbonyl fluoride
  参考文献：
  名称：

  Hung, Ming-H.; Resnick, Paul R., Journal of the American Chemical Society, 1990, vol. 112, # 26, p. 9671 - 9672

  摘要：

  DOI：
• 作为产物：
  描述：

  2,2-bis(pentafluoroethyl)-4,5-dichloro-1,3-dioxol 在 potassium fluoride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 5.8h， 生成 4,5-Difluoro-2,2-bis-pentafluoroethyl-[1,3]dioxole
  参考文献：
  名称：

  4,5-二氟-2,2-二(全氟取代基)-1,3-二氧杂 环戊烯类化合物的合成方法

  摘要：

  本发明公开了一种4,5‑二氟‑2,2‑二(全氟取代基)‑1,3‑二氧杂环戊烯类化合物的合成方法，具体包括：将4,4,5,5‑四氯‑2,2‑二(全氟取代基)‑1,3‑二氧杂环戊烷类化合物先经脱卤反应得到4,5‑二氯‑2,2‑二(全氟取代基)‑1,3‑二氧杂环戊烯，再经氟化反应得到所述的4,5‑二氟‑2,2‑二(全氟取代基)‑1,3‑二氧杂环戊烯类化合物。本发明方法有效避免了传统工艺中先进行氟化反应会得到顺式和反式两种异构体的问题，消除了反应选择性的问题，大大提高了反应收率，降低了生产成本，工业化应用可行性高，可提高产品的市场竞争力。

  公开号：

  CN109867655B

文献信息

• Fluorine-containing resin composition
  申请人：Asahi Glass Company Ltd.

  公开号：EP0905179A1

  公开（公告）日：1999-03-31

  A fluorine-containing resin composition comprising at least one fluorine-containing polycyclic compound (A) selected from the group consisting of the following compounds (A1), (A2) and (A3), and a polymer (B) having a fluorine-containing alicyclic structure: (A1) a fluorine-containing non-condensed polycyclic compound having at least two fluorine-containing rings bonded by a bond containing at least one member selected from the group consisting of a triazine ring, an oxygen atom, a sulfur atom, a phosphorus atom and a metal atom, each of said fluorine-containing rings being a carbon ring or a heterocyclic ring, of which some or all of hydrogen atoms are substituted by a fluorine atom or a fluorine-containing group; (A2) a fluorine-containing non-condensed polycyclic compound having at least three fluorine-containing rings bonded directly or by a bond containing a carbon atom, each of said fluorine-containing rings being a carbon ring or a heterocyclic ring, of which some or all of hydrogen atoms are substituted by a fluorine atom or a fluorine-containing group; (A3) a fluorine-containing condensed polycyclic compound which is a condensed polycyclic compound composed of at least three carbon rings or heterocyclic rings, of which some or all of hydrogen atoms are substituted by a fluorine atom or a fluorine-containing group.

  一种含氟树脂组合物，包含至少一种从以下化合物（A1）、（A2）和（A3）组成的组中选出的含氟多环化合物（A），以及一种具有含氟脂环结构的聚合物（B）： (A1) 具有至少两个含氟环的含氟非缩合多环化合物，这两个含氟环通过含有至少一个选 自三嗪环、氧原子、硫原子、磷原子和金属原子组成的组的键结合，每个所述含氟环是 碳环或杂环，其中部分或全部氢原子被氟原子或含氟基团取代； (A2) 含氟非缩合多环化合物，至少有三个含氟环直接或通过含有碳原子的键结合在一起，每个含氟环是碳环或杂环，其中部分或全部氢原子被氟原子或含氟基团取代； (A3) 含氟缩合多环化合物，它是由至少三个碳环或杂环组成的缩合多环 化合物，其中部分或全部氢原子被氟原子或含氟基团取代。
• Method for producing ionic polymer membrane
  申请人：Asahi Glass Company, Limited

  公开号：US10022716B2

  公开（公告）日：2018-07-17

  To provide a simple method whereby an ionic polymer membrane having a high ion exchange capacity and a low water uptake can be produced by converting a —SO2F group in a polymer to a pendant group having multiple ion exchange groups, while preventing a cross-linking reaction. At the time of obtaining an ionic polymer membrane by converting —SO2F (group (1)) in a polymer sequentially to —SO2NZ1Z2 (group (2)), —SO2N−(Mα+)SO2(CF2)2SO2F (group (3)), —SO2N−(H+)SO2(CF2)2SO2F (group (4)) and —SO2N−(Mβ+)SO2(CF2)2SO3−Mβ+ (group (5)), the polymer is formed into a polymer membrane in the state of any one of the groups (1) to (4), and the polymer membrane is thermally treated in the state of group (4). Here, Z1 and Z2 are hydrogen atoms, etc., Mα+ is a monovalent cation, and Mβ+ is a hydrogen ion or a monovalent cation.

  提供一种简单的方法，通过将聚合物中的 -SO2F 基团转化为具有多个离子交换基团的悬垂基团，在防止发生交联反应的同时，生产出具有高离子交换能力和低吸水性的离子聚合物膜。 将聚合物中的-SO2F（基团(1)）依次转化为-SO2NZ1Z2（基团(2)）、-SO2N-(Mα+)SO2(CF2)2SO2F（基团(3)），从而获得离子聚合物膜、-SO2N-(H+)SO2(CF2)2SO2F（第(4)组）和-SO2N-(Mβ+)SO2(CF2)2SO3-Mβ+（第(5)组），聚合物在第(1)至(4)组中任意一组的状态下形成聚合物膜，聚合物膜在第(4)组的状态下进行热处理。这里，Z1 和 Z2 是氢原子等，Mα+ 是一价阳离子，Mβ+ 是氢离子或一价阳离子。
• METHOD FOR MANUFACTURING IONIC POLYMER FILM
  申请人：Asahi Glass Company, Limited

  公开号：EP2922127B1

  公开（公告）日：2017-11-29
• IONIC POLYMER AND PROCESS FOR ITS PRODUCTION
  申请人：Tayanagi Junichi

  公开号：US20130053459A1

  公开（公告）日：2013-02-28

  To obtain an ionic polymer having a high ion exchange capacity and a low moisture content, by simply converting a —SO 2 F group in a polymer to a pendant group having a plurality of ion exchange groups, while preventing a cross-linking reaction. A process for producing an ionic polymer, which comprises (A) a step of converting a —SO 2 F group in a polymer to a —SO 2 NZ 1 Z 2 group (each of Z 1 and Z 2 which are independent of each other, is a group selected from a hydrogen atom, a monovalent metal element and a trimethylsilyl group), (B) a step of reacting the polymer obtained in the step (A) with FSO 2 (CF 2 ) 2 SO 2 F, and (C) a step of converting a terminal —SO 2 F group of a side chain in the polymer obtained in the step (B) to an ion exchange group such as a —SO 3 H group; and an ionic polymer obtained by such a process.
• METHOD FOR PRODUCING IONIC POLYMER MEMBRANE
  申请人：Asahi Glass Company, Limited

  公开号：US20150202617A1

  公开（公告）日：2015-07-23

  To provide a simple method whereby an ionic polymer membrane having a high ion exchange capacity and a low water uptake can be produced by converting a —SO 2 F group in a polymer to a pendant group having multiple ion exchange groups, while preventing a cross-linking reaction. At the time of obtaining an ionic polymer membrane by converting —SO 2 F (group (1)) in a polymer sequentially to —SO 2 NZ 1 Z 2 (group (2)), —SO 2 N − (M α + )SO 2 (CF 2 ) 2 SO 2 F (group (3)), —SO 2 N − (H + )SO 2 (CF 2 ) 2 SO 2 F (group (4)) and —SO 2 N − (M β + )SO 2 (CF 2 ) 2 SO 3 − M β + (group (5)), the polymer is formed into a polymer membrane in the state of any one of the groups (1) to (4), and the polymer membrane is thermally treated in the state of group (4). Here, Z 1 and Z 2 are hydrogen atoms, etc., M α + is a monovalent cation, and M β + is a hydrogen ion or a monovalent cation.