4b,5,10b,11-Tetrahydro-chrysene-6,12-dione | 731853-76-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 4b,5,10b,11-Tetrahydro-chrysene-6,12-dione
• 英文别名: 4b,5,10b,11-Tetrahydrochrysene-6,12-dione
• CAS: 731853-76-2
• 化学式: C₁₈H₁₄O₂
• 分子量: 262.308
• InChiKey: QXNOHQMRONMROP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  20
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4b,5,10b,11-Tetrahydro-chrysene-6,12-dione 在 palladium on activated charcoal sodium tetrahydroborate 、 氢气 、 硝酸 、 4-甲基苯磺酸吡啶 作用下， 以 乙醇 、 苯 为溶剂， 生成 2,8-diamino crysene
  参考文献：
  名称：

  Samarium-induced reductive dimerization of methyl cinnamate: synthesis of 2,8-diamino chrysene

  摘要：

  Samarium metal-induced reductive dimerization of methyl cinnamate was performed for the first time. A unique role for aluminum was indicated in the dimerization reaction. The intermediate adipate ester was converted to 2,8-diamino chrysene. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.04.087
• 作为产物：
  描述：

  meso-3,4-diphenyladipic acid dimethyl ester 在 硫酸 作用下， 以60%的产率得到4b,5,10b,11-Tetrahydro-chrysene-6,12-dione
  参考文献：
  名称：

  Samarium-induced reductive dimerization of methyl cinnamate: synthesis of 2,8-diamino chrysene

  摘要：

  Samarium metal-induced reductive dimerization of methyl cinnamate was performed for the first time. A unique role for aluminum was indicated in the dimerization reaction. The intermediate adipate ester was converted to 2,8-diamino chrysene. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.04.087

文献信息

• COMPOUND FOR ORGANIC THIN FILM TRANSISTOR AND ORGANIC THIN FILM TRANSISTOR USING THE SAME
  申请人：Nakano Yuki

  公开号：US20110180790A1

  公开（公告）日：2011-07-28

  A compound for an organic thin film transistor having a structure represented by the following formula (1): wherein at least one of R 1 to R 6 is a substituent, and the remaining R 1 to R 6 are a hydrogen atom.
• US8963128B2
  申请人：——

  公开号：US8963128B2

  公开（公告）日：2015-02-24
• Samarium-induced reductive dimerization of methyl cinnamate: synthesis of 2,8-diamino chrysene
  作者：Bimal K. Banik、M.S. Venkatraman、Indrani Banik、Manas K. Basu

  DOI：10.1016/j.tetlet.2004.04.087

  日期：2004.6

  Samarium metal-induced reductive dimerization of methyl cinnamate was performed for the first time. A unique role for aluminum was indicated in the dimerization reaction. The intermediate adipate ester was converted to 2,8-diamino chrysene. (C) 2004 Elsevier Ltd. All rights reserved.