Trimethylolpropan-dichlorhydrin | 5381-54-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Trimethylolpropan-dichlorhydrin
• 英文别名: 2,2-bis-chloromethyl-butan-1-ol；2,2-Bis-chlormethyl-butan-1-ol；1,1-bis(chloromethyl)-1-hydroxymethylpropane；2,2-Bis(chloromethyl)butan-1-ol
• CAS: 5381-54-4
• 化学式: C₆H₁₂Cl₂O
• mdl: MFCD20622178
• 分子量: 171.067
• InChiKey: BIFYPMIIDSCISR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  9
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  吗啉 、 Trimethylolpropan-dichlorhydrin 反应 5.0h， 生成 2,2-bis-morpholin-4-ylmethyl-butan-1-ol
  参考文献：
  名称：

  Morpholine derivatives

  摘要：

  DOI：

  10.1007/bf00470150
• 作为产物：
  描述：

  2,2-bis-chloromethyl-butyric acid methyl ester 在 lithium aluminium tetrahydride 作用下， 生成 Trimethylolpropan-dichlorhydrin
  参考文献：
  名称：

  Free-Radical, Chain Reactions of Diazomethane with Polybromo- and Polyiodomethanes

  摘要：

  DOI：

  10.1021/ja01561a038

文献信息

• Oxetane polymers and methods of preparation thereof
  申请人：RENSSELAER POLYTECHNIC INSTITUTE

  公开号：US10377855B2

  公开（公告）日：2019-08-13

  The invention is directed to processes for preparation of oxetane polymers, wherein an epoxide accelerant is reacted with one or more equivalents of a 3-monosubstituted oxetane or a 3,3-disubstituted oxetane, wherein the epoxide accelerant is selected from the group consisting of 2,2-substituted epoxide, 2,2,3-substituted epoxide, 2,2,3,3-substituted epoxide, and mixtures thereof. Also disclosed are oxetane polymers prepared by the processes of the invention.

  本发明涉及制备氧杂环丁烷聚合物的工艺，其中环氧化物促进剂与一种或多种当量的3-单取代氧杂环丁烷或3,3-二取代氧杂环丁烷反应，其中环氧化物促进剂选自由2,2-取代环氧化物、2,2,3-取代环氧化物、2,2,3,3-取代环氧化物及其混合物组成的组。还公开了通过本发明工艺制备的氧杂环丁烷聚合物。
• Crosslinking p-dopants for p-doping organic hole conductors
  申请人：OSRAM OLED GmbH

  公开号：US11258020B2

  公开（公告）日：2022-02-22

  A method produces cross-linked hole-conducting electric layers by converting functionalized p-dopants. The functionalized p-dopants are organic metal complexes containing at least one central atom and organic ligands, wherein the central atom is selected from a metal of the groups 6-15 of the periodic table, and at least one of the organic ligands is selected from the following formulas I-V, in which E independently of one another is oxygen, sulfur, selenium, or N(E1)x, and each Rv has at least one functionalizing group selected from the group RF including —OH, —COOH, —NH2, —NHR′, halogen, C2-C40-alkenyl, -dienyl, -alkinyl, -alkenyloxy, -dienyloxy, -alkinyloxy, acrylic acid, oxetan, oxiran, silane, acrylic acid, anhydride, and cyclobutane or consists of the groups, and G=C(RF)uHvFw where u+v+w=3 and n=1-4.

  一种通过转换功能化 p 掺杂剂生产交联空穴导电电层的方法。官能化 p-掺杂剂是含有至少一个中心原子和有机配体的有机金属配合物，其中中心原子选自元素周期表中第 6-15 族的金属，至少一个有机配体选自以下式子 I-V，其中 E 相互独立地为氧、硫、硒或 N(E1)x，每个 Rv 具有至少一个选自包括 -OH 在内的 RF 组的官能化基团、或 N(E1)x，且每个 Rv 具有至少一个官能团，该官能团选自包括-OH、-COOH、-NH2、-NHR′、卤素、C2-C40-烯基、-二烯基、-烷基、-烯氧基、-二烯氧基、-炔氧基、丙烯酸、氧杂环丁烷、氧杂环戊烷、硅烷、丙烯酸、酸酐和环丁烷或由这些基团组成，以及 G=C(RF)uHvFw 其中 u+v+w=3 和 n=1-4.
• PHOTOSTRUKTURIERBARE NEUE ORGANISCHE HALBLEITERMATERIALIEN
  申请人：OSRAM Opto Semiconductors GmbH

  公开号：EP1410448B1

  公开（公告）日：2015-03-25
• OXETANE POLYMERS AND METHODS OF PREPARATION THEREOF
  申请人：RENSSELAER POLYTECHNIC INSTITUTE

  公开号：US20170198093A1

  公开（公告）日：2017-07-13

  The invention is directed to processes for preparation of oxetane polymers, wherein an epoxide accelerant is reacted with one or more equivalents of a 3-monosubstituted oxetane or a 3,3-disubstituted oxetane, wherein the epoxide accelerant is selected from the group consisting of 2,2-substituted epoxide, 2,2,3-substituted epoxide, 2,2,3,3-substituted epoxide, and mixtures thereof. Also disclosed are oxetane polymers prepared by the processes of the invention.
• CROSSLINKING P-DOPANTS FOR P-DOPING ORGANIC HOLE CONDUCTORS
  申请人：OSRAM OLED GmbH

  公开号：US20190140190A1

  公开（公告）日：2019-05-09

  A method produces cross-linked hole-conducting electric layers by converting functionalized p-dopants. The functionalized p-dopants are organic metal complexes containing at least one central atom and organic ligands, wherein the central atom is selected from a metal of the groups 6-15 of the periodic table, and at least one of the organic ligands is selected from the following formulas I-V, in which E independently of one another is oxygen, sulfur, selenium, or N(E 1 ) x , and each R v has at least one functionalizing group selected from the group R F including —OH, —COOH, —NH 2 , —NHR′, halogen, C2-C40-alkenyl, -dienyl, -alkinyl, -alkenyloxy, -dienyloxy, -alkinyloxy, acrylic acid, oxetan, oxiran, silane, acrylic acid, anhydride, and cyclobutane or consists of the groups, and G=C(R F ) u H v F w where u+v+w=3 and n=1-4.