potassium;dichloroplatinum;1-(4-nitrosophenyl)ethanone;chloride | 219141-81-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: potassium;dichloroplatinum;1-(4-nitrosophenyl)ethanone;chloride
• CAS: 219141-81-8
• 化学式: C₈H₇Cl₃NO₂Pt*K
• 分子量: 489.686
• InChiKey: FLDZEPVDVKYOAP-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -2.33
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  46.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 1-(4-亚硝基苯基)乙酮 以 水 、 丙酮 为溶剂， 生成 potassium;dichloroplatinum;1-(4-nitrosophenyl)ethanone;chloride
  参考文献：
  名称：

  Preparative and spectroscopic studies of [PtCl3(4-XC6H4NO)]− K+ complexes

  摘要：

  sigma(N)-Coordinated compounds [PtCl3(4-X-C6H4NO)](-) K+ have been prepared and studied by C-13 NMR spectroscopy and by variable temperature H-1 NMR spectroscopy. It is shown that the anomalous behaviour of the NO group on the C-13 chemical shifts is modified by coordination but where X = N(CH3)(2) or OCH, the free energy barriers to rotation of the NO group determined by H-1 NMR studies are closely similar to those of the free ligands. Restricted rotation of the N(CH3)(2) group was also studied in [PtCl3(2-CH3-4-N(CH3)(2)-C6H3NO)](-) K+. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00137-5