2-(2-(pentafluoroethoxy)tetrafluoroethoxy)-2,2-difluoroethanol | 14548-75-5

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代醇
• 英文名称: 2-(2-(pentafluoroethoxy)tetrafluoroethoxy)-2,2-difluoroethanol
• 英文别名: 2,2-Difluoro-2-[1,1,2,2-tetrafluoro-2-(1,1,2,2,2-pentafluoroethoxy)ethoxy]ethanol
• CAS: 14548-75-5
• 化学式: C₆H₃F₁₁O₃
• 分子量: 332.07
• InChiKey: SHUGKWOBLGLDQR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  20
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  38.7
• 氢给体数：
  1
• 氢受体数：
  14

反应信息

• 作为反应物：
  描述：

  2-(2-(pentafluoroethoxy)tetrafluoroethoxy)-2,2-difluoroethanol 、 3-溴丙烯 在 氢氧化钾 作用下， 以 水 、 二甲基亚砜 为溶剂， 反应 16.0h， 生成 3-(2-(2-(pentafluoroethoxy)tetrafluoroethoxy)-2,2-difluoroethoxy)prop-1-ene
  参考文献：
  名称：

  [EN] FLUOROCHEMICAL TREATMENT FOR SILICON ARTICLES
  [FR] TRAITEMENT FLUOROCHIMIQUE D'ARTICLES EN SILICIUM

  摘要：

  公开号：

  WO2003101888A3

文献信息

• METHOD FOR PRODUCING CARBONATE COMPOUND
  申请人：Asahi Glass Company, Limited

  公开号：US20150284314A1

  公开（公告）日：2015-10-08

  The present invention relates to a production process capable of selectively producing various kinds of carbonate compounds without restraint in high yields without using toxic compounds such as phosgene and crown ethers, without producing corrosive gases such as hydrogen chloride as a by-product, and without necessity of removing the chloroform as a by-product by distillation, and to a method for producing a carbonate compound, containing reacting compound (1) with a compound having an OH group in the presence of a metal salt and 0.2 to 4.0 mol of compound (2) per mol of the metal salt to obtain a carbonate compound, in which m is an integer of 1-10, Q is an alkylene group having 1 to 4 carbon atoms, etc, and R 10 and R 11 are alkyl groups having 1 to 5 carbon atoms, etc.

  本发明涉及一种生产过程，能够在高产率下有选择地生产各种碳酸盐化合物，而不使用像光气和冠醚这样的有毒化合物，也不产生像氯化氢这样的腐蚀性气体作为副产品，也不需要通过蒸馏去除氯仿作为副产品，以及一种制备碳酸盐化合物的方法，其中包括在金属盐和化合物（1）的存在下，将化合物（1）与具有羟基的化合物反应，每摩尔金属盐添加0.2到4.0摩尔的化合物（2），以获得碳酸盐化合物，其中m是1-10的整数，Q是具有1到4个碳原子的烷基基团，R10和R11是具有1到5个碳原子的烷基基团等。
• Antireflection film, polarizing plate, and image display device
  申请人：Okamoto Yasuhiro

  公开号：US20070065660A1

  公开（公告）日：2007-03-22

  An antireflection film comprising a support and a low refractive index layer made from a coating composition containing: a fluorine-containing polymer containing at least one fluorine-containing vinyl monomer polymerization unit and at least one hydroxyl group-containing vinyl monomer polymerization unit; and a particle having a conductive metal oxide-coated layer.

  一种防反射膜，包括支撑层和低折射率层，所述低折射率层由一种涂层组合物制成，所述涂层组合物包含：一种含有至少一种含氟乙烯单体聚合单元和至少一种含羟基乙烯单体聚合单元的含氟聚合物；以及一种具有导电金属氧化物涂层层的粒子。
• ANTIREFLECTIVE FILM, POLARIZING PLATE, IMAGE DISPLAY DEVICE AND COATING COMPOSITION FOR FORMING LOW REFRACTIVE INDEX LAYER
  申请人：ASAHI Miho

  公开号：US20100246014A1

  公开（公告）日：2010-09-30

  An antireflective film includes: a transparent substrate film; and at least one low refractive index layer, the low refractive index layer is formed with a composition containing: a fluorine-containing antifouling agent having a weight average molecular weight of less than 10,000 and a structure represented by the following formula (F); a polyfunctional monomer having a polymerizable unsaturated group; and (C) an inorganic particle, and a content of the fluorine-containing antifouling agent is 1% by weight or more and less than 25% by weight based on a total solid content of the coating composition: (Rf)-[(W)-(R A ) n ] m Formula (F) wherein, Rf represents a (per)fluoroalkyl group or a (per)fluoropolyether group, W represents a connecting group, R A represents a functional group having a polymerizable unsaturated group, n represents an integer of from 1 to 3, and m represents an integer of from 1 to 3.

  一种防反射膜包括：一个透明基底膜；和至少一层低折射率层，该低折射率层由含有以下化合物的组合物形成：具有分子量小于10,000和结构表示为以下公式（F）的含氟防污剂；具有聚合可不饱和基团的多官能单体；和（C）一种无机颗粒，其中含氟防污剂的含量基于涂层组合物的总固体含量为重量的1％或更多但小于25％：（Rf）- [（W）-（RA）n] m 公式（F）中，Rf表示（全）氟烷基或（全）氟聚醚基，W表示连接基团，RA表示具有聚合可不饱和基团的官能基团，n表示1至3的整数，m表示1至3的整数。
• Hardcoat film, polarizing plate, liquid crystal display, and method for manufacturing hardcoat film
  申请人：FUJIFILM Corporation

  公开号：US10365411B2

  公开（公告）日：2019-07-30

  A hardcoat film including a support and a hardcoat layer, in which the support contains a resin as a main component, a film thickness of the hardcoat layer exceeds 20 μm, the hardcoat layer contains a structure derived from a compound which has one alicyclic epoxy group and one ethylenically unsaturated double bond group and has a molecular weight equal to or less than 300, and a structure derived from a compound which has 3 or more ethylenically unsaturated double bond groups, a radical polymerization initiator and a cationic polymerization initiator.

  一种硬涂层薄膜，包括支撑体和硬涂层，其中支撑体包含作为主要成分的树脂，硬涂层的膜厚超过 20 μm，硬涂层包含一种由具有一个脂环族环氧基团和一个乙烯基不饱和双键基团且分子量等于或小于 300 的化合物衍生的结构，以及一种由具有 3 个或更多乙烯基不饱和双键基团的化合物衍生的结构、一种自由基聚合引发剂和一种阳离子聚合引发剂。
• PROCESS FOR CONTROLLING CONE TILT ANGLE IN MIXTURES OF SMECTIC LIQUID CRYSTAL COMPOUNDS
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0868501B1

  公开（公告）日：2003-08-13