(4-methoxy)butyl vinyl ether | 44860-33-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (4-methoxy)butyl vinyl ether
• 英文别名: 1-(Ethenyloxy)-4-methoxybutane；1-ethenoxy-4-methoxybutane
• CAS: 44860-33-5
• 化学式: C₇H₁₄O₂
• 分子量: 130.187
• InChiKey: RCRRYCRTBURQSZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  9
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (4-methoxy)butyl vinyl ether 在 [(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)NiH(OTf)] 、 硝基苯 作用下， 以 甲苯 为溶剂， 反应 24.0h， 以92%的产率得到2,3-Bis(4-methoxybutoxy)but-1-ene
  参考文献：
  名称：

  Nitrate-Enhanced NHC-NiH Catalyzed Tail-to-Tail Vinyl Ether Dimerization

  摘要：

  The first tail-to-tail vinyl ether dimerization has been developed by using a newly identified synergistic effect between the NHC-NiH catalyst and organonitrate additive (PhNO2 or t-BuNO2). The additive enhanced the desired C-C bond-forming reactivity by a proposed competitive coordination with the alkoxyl group of the hydrometallated vinyl ether species to the Ni center. This combination addressed complications related to -alkoxy (-OR) elimination and polymerization, and gave unexpected dimerization regioselectivity.

  DOI：

  10.1055/s-0034-1379219

文献信息

• Method for producing n-alkenyl amides
  申请人：——

  公开号：US20030028035A1

  公开（公告）日：2003-02-06

  A process for preparing N-alkenyl-amides by reacting the corresponding NH-amides with acetylenes in the liquid phase in the presence of basic alkali metal compounds and of a cocatalyst comprises using as the cocatalyst compounds of the general formulae (Ia) and/or (Ib) R 1 O—(CH 2 CH 2 CH 2 CH 2 O) n —H  (Ia): R 1 O—(CH 2 CH 2 CH 2 CH 2 O) n —R 2 ,  (Ib): where n is 1, 2 or 3 and R 1 and R 2 are independently C 1 - to C 6 -alkyl or C 2 - to C 6 -alkenyl, or together a butenyl unit.

  制备N-烯基酰胺的过程包括通过在液相中让相应的NH-酰胺与炔烃反应，在碱性金属化合物和共催化剂的存在下，作为共催化剂使用的是具有以下通式(Ia)和/或(Ib)的化合物：R1O—(CH2CH2CH2CH2O)n—H  (Ia):R1O—(CH2CH2CH2CH2O)n—R2,  (Ib):其中n为1、2或3，R1和R2独立地为C1至C6烷基或C2至C6烯基，或者共同构成一个丁烯基团。
• ORGANIC ELECTRONIC MATERIAL, POLYMERIZATION INITIATOR AND THERMAL POLYMERIZATION INITIATOR, INK COMPOSITION, ORGANIC THIN FILM AND PRODUCTION METHOD FOR SAME, ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTROLUMINESCENT ELEMENT, LIGHTING DEVICE, DISPLAY ELEMENT, AND DISPLAY DEVICE
  申请人：Ishitsuka Kenichi

  公开号：US20130037753A1

  公开（公告）日：2013-02-14

  Disclosed is an organic electronic material comprising charge transporting compounds and ionic compounds having electron-accepting properties and high solubility in a solvent. The organic electronic material is characterized by comprising charge transporting compounds and ionic compounds, and in that at least one of the ionic compounds is any one kind of compounds represented by general formulas (1b)-(3b). (In the formulas Y 1 -Y 6 each independently represent a divalent linking group, R 1 -R 6 each independently represent an electron-attracting organic substituent (these structures can further have substituents and hetero-atoms, and R 1 , R 2 and R 3 , or, R 4 -R 6 can respectively combine and become a ring shape or a polymer shape) and L + represents a monovalent cation.)

  本文揭示了一种有机电子材料，包括具有电荷传输化合物和具有接受电子性质且在溶剂中具有高溶解度的离子化合物。该有机电子材料的特点在于包括电荷传输化合物和离子化合物，并且至少其中一个离子化合物是由通用式（1b）-（3b）表示的化合物中的任意一种。（在式中，Y1-Y6分别表示二价连接基团，R1-R6分别表示吸引电子的有机取代基（这些结构可以进一步具有取代基和杂原子，且R1、R2和R3，或者R4-R6可以分别结合形成环状或聚合物形状），L+表示一价阳离子。）
• Method for producing alkenyl ethers
  申请人：——

  公开号：US20030114715A1

  公开（公告）日：2003-06-19

  Alkenyl ethers are prepared by reacting the corresponding alcohols or phenols with acetylenes in the liquid phase in the presence of basic alkali metal compounds and a cocatalyst comprising compounds of the formula (Ia) and/or (Ib) R 1 O—(CH 2 CH 2 CH 2 CH 2 O) n— H  (Ia) R 1 O—(CH 2 CH 2 CH 2 CH 2 O) n— H 2 ,  (Ia) where R 1 , R 2 are, independently of one another, C 1 -C 6 -alkyl or C 2 -C 6 -alkenyl, or R 1 and R 2 together form a butyl unit and n is 1, 2, 3, 4 or 5.

  烯丙醚通过在液相中存在碱性金属化合物和协同催化剂的情况下，将相应的醇或酚与乙炔反应制备而成，其中所述协同催化剂包括化合物(Ia)和/或(Ib)的公式，(Ia)R1O—(CH2CH2CH2CH2O)n—H  (Ia)R1O—(CH2CH2CH2CH2O)n—H2,  (Ia)其中，R1，R2是独立的C1-C6烷基或C2-C6烯基，或R1和R2共同形成丁基单元，n为1、2、3、4或5。
• Organic Electronic Material, Ink Composition Containing Same, and Organic Thin Film, Organic Electronic Element, Organic Electroluminescent Element, Lighting Device, and Display Device Formed Therewith
  申请人：Funyuu Shigeaki

  公开号：US20120074360A1

  公开（公告）日：2012-03-29

  Provided are: an organic electronic material which can be easily multilayered and that can be used in substrates, such as resin, that cannot be processed at high temperatures; an ink composition containing the same; an organic thin film formed using said organic electronic material or said ink composition; and an organic electronic element and an organic EL element that are formed using said organic thin film and that have a superior luminous efficacy and emission lifespan than conventional elements. Specifically, provided are: an organic electronic material that is characterized by containing an oligomer or a polymer having a structure that branches into three or more directions and has at least one polymerizable substituent; an ink composition containing said organic electronic material; and an organic thin film prepared using the aforementioned organic electronic material. Further, provided are an organic electronic element and an organic electroluminescent element containing said organic thin film.

  提供了以下内容：一种有机电子材料，可以轻松地多层堆叠，并可用于无法在高温下加工的基板，例如树脂；包含相同材料的墨水组合物；使用该有机电子材料或该墨水组合物形成的有机薄膜；以及使用该有机薄膜形成的有机电子元件和有机EL元件，其具有比传统元件更优异的发光效率和发射寿命。具体而言，提供了一种有机电子材料，其特征在于包含具有分支结构且向三个或更多方向分支的寡聚物或聚合物，并具有至少一个可聚合取代基；包含该有机电子材料的墨水组合物；以及使用上述有机电子材料制备的有机薄膜。此外，还提供了包含该有机薄膜的有机电子元件和有机电致发光元件。
• COMPOUND, ORGANIC ELECTROLUMINESCENCE ELEMENT MATERIAL, INK COMPOSITION, ORGANIC ELECTROLUMINESCENCE ELEMENT, ELECTRONIC DEVICE, AND METHOD FOR PRODUCING COMPOUND
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20160197288A1

  公开（公告）日：2016-07-07

  A compound represented by formula (1): wherein *a, *b, R 1 , X 1 , L 1 , L 2 , n, A 1 , and A 2 are as defined in the description, and a production method of the compound represented by formula (1) are provide. In the production method, A 1 is introduced under a reaction condition in which the reactivity of Hal 2 in a compound represented by formula (I): wherein *c, *d, R 1 , X 1 , L 1 , L 2 , n, A 1 , A 2 , Hal 1 , and Hal 2 are as defined in the description, is extremely low as compared with that of Hal 1 and then A 2 which is different from A 1 is introduced under a reaction condition in which the reactivity of Hal 2 is high. The compound represented by formula (1) is formed into a layer by a coating method and meets various performance requirements of an organic EL device.

  公式（1）所表示的化合物：其中*a，*b，R1，X1，L1，L2，n，A1和A2的定义如说明书中所定义，并且提供了化合物（1）的生产方法。在生产方法中，A1在反应条件下引入，其中在化合物（I）所表示的卤素2的反应性在Hal1相比下极低，其中* c，* d，R1，X1，L1，L2，n，A1，A2，Hal1和Hal2的定义如说明书中所定义，然后在Hal2的反应性高的反应条件下引入不同于A1的A2。化合物（1）通过涂覆方法形成一层，并满足有机EL器件的各种性能要求。