Trifluoro-methanesulfonic acid 6-decyl-naphthalen-2-yl ester | 146204-05-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: Trifluoro-methanesulfonic acid 6-decyl-naphthalen-2-yl ester
• 英文别名: (6-Decylnaphthalen-2-yl) trifluoromethanesulfonate
• CAS: 146204-05-9
• 化学式: C₂₁H₂₇F₃O₃S
• 分子量: 416.505
• InChiKey: FLKPESKZWDFWPW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.1
• 重原子数：
  28
• 可旋转键数：
  11
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.52
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  4-decylphenylboronic acid 、 Trifluoro-methanesulfonic acid 6-decyl-naphthalen-2-yl ester 在 四(三苯基膦)钯 、 水 、 sodium carbonate 作用下， 以 乙二醇二甲醚 为溶剂， 生成 2-Decyl-6-(4-decyl-phenyl)-naphthalene
  参考文献：
  名称：

  Synthesis and Characterization of Liquid Crystalline Semiconducting Materials, Dialkyl-2-phenylnaphthalene Derivatives—Mesomorphic behavior and Charge carrier transport

  摘要：

  For establishment of high electronic charge carrier transport at ambient temperature, dialkyl derivatives of 2-phenylnaphthalene have been synthesized and characterized their liquid crystalline behaviors and photoelectrical properties. These materials exhibited smectic mesophases (Smectic A, B and E phases), at fairly low temperature range extended down below ambient temperature. Fast electronic transport of positive carriers was observed in SmE phase of 2-(4'-octylphenyl)-6-butylnaphthalene at 30degreesC, whose mobility was over 10(-2) cm(2)/Vs.

  DOI：

  10.1080/15421400490435251
• 作为产物：
  描述：

  2-萘甲醚 在 吡啶 、 氢氧化钾 、 三氯化铝 、 氢溴酸 、 一水合肼 、 溶剂黄146 作用下， 以 乙二醇 、 硝基苯 为溶剂， 生成 Trifluoro-methanesulfonic acid 6-decyl-naphthalen-2-yl ester
  参考文献：
  名称：

  Synthesis and Characterization of Liquid Crystalline Semiconducting Materials, Dialkyl-2-phenylnaphthalene Derivatives—Mesomorphic behavior and Charge carrier transport

  摘要：

  For establishment of high electronic charge carrier transport at ambient temperature, dialkyl derivatives of 2-phenylnaphthalene have been synthesized and characterized their liquid crystalline behaviors and photoelectrical properties. These materials exhibited smectic mesophases (Smectic A, B and E phases), at fairly low temperature range extended down below ambient temperature. Fast electronic transport of positive carriers was observed in SmE phase of 2-(4'-octylphenyl)-6-butylnaphthalene at 30degreesC, whose mobility was over 10(-2) cm(2)/Vs.

  DOI：

  10.1080/15421400490435251

文献信息

• Liquid crystal compounds and compositions
  申请人：SANYO CHEMICAL INDUSTRIES LTD.

  公开号：EP0517498A1

  公开（公告）日：1992-12-09

  Liquid crystal naphtalene compounds, represented by the following formula (1) are disclosed.         R-Z-A-NAP-Z′-R′   (1) In the formula (1), R is an alkyl group containing 1 to 18 carbon atoms; R′ is an alkyl group containing 1 to 21 carbon atoms; NAP represents 2,6-naphthylene group; A, Z and Z′ are as follows: 1) A is Pyr> and (a) Z is - or # and Z′ is O, or (b) Z is - and Z′ is COO; 2) if A is Pym>, (a) Z is - and Z′ is O, or (b) Z is O and Z′ is -, O or #; 3) A is FPhF and (a) Z is - or O and Z′ is -, O or COO, (b) Z is OCO and Z′ is - or O, or (c) Z is # and Z′ is O; 4) A is PhF and (a) Z is - or # and Z′ is O, (b) Z is O and Z′ is -, or (c) Z is - and Z′ is COO; 5) A is FPh and (a) Z is O and Z′ is-, (b) Z is -, O, # or OCO and Z′ is O, or (c) Z is O and Z′ is COO; 6) A is

  液晶萘化合物的化学式如下所示：R-Z-A-NAP-Z′-R′。在这个化学式中，R是含有1到18个碳原子的烷基基团；R′是含有1到21个碳原子的烷基基团；NAP代表2,6-萘基团；A、Z和Z′的具体定义如下： 1）如果A是Pyr，(a) Z是-或#，Z′是O；或者(b) Z是-，Z′是COO； 2）如果A是Pym，(a) Z是-，Z′是O；或者(b) Z是O，Z′是-、O或#； 3）如果A是FPhF，(a) Z是-或O，Z′是-、O或COO；(b) Z是OCO，Z′是-或O；或者(c) Z是#，Z′是O； 4）如果A是PhF，(a) Z是-或#，Z′是O；(b) Z是O，Z′是-；或者(c) Z是-，Z′是COO； 5）如果A是FPh，(a) Z是O，Z′是-；(b) Z是-、O、#或OCO，Z′是O；或者(c) Z是O，Z′是COO； 6）如果A是
• Synthesis and Characterization of Liquid Crystalline Semiconducting Materials, Dialkyl-2-phenylnaphthalene Derivatives—Mesomorphic behavior and Charge carrier transport
  作者：Yukiko Takayashiki、Jun-Ich Hanna

  DOI：10.1080/15421400490435251

  日期：2004.1

  For establishment of high electronic charge carrier transport at ambient temperature, dialkyl derivatives of 2-phenylnaphthalene have been synthesized and characterized their liquid crystalline behaviors and photoelectrical properties. These materials exhibited smectic mesophases (Smectic A, B and E phases), at fairly low temperature range extended down below ambient temperature. Fast electronic transport of positive carriers was observed in SmE phase of 2-(4'-octylphenyl)-6-butylnaphthalene at 30degreesC, whose mobility was over 10(-2) cm(2)/Vs.