(3S,4R,5R)-1-Allyloxy-3,4,5,6-tetrahydroxy-hexan-2-one | 85973-53-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (3S,4R,5R)-1-Allyloxy-3,4,5,6-tetrahydroxy-hexan-2-one
• 英文别名: (3S,4R,5R)-3,4,5,6-tetrahydroxy-1-prop-2-enoxyhexan-2-one
• CAS: 85973-53-1
• 化学式: C₉H₁₆O₆
• 分子量: 220.222
• InChiKey: AGRKHBAFIROKJY-FTLITQJKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.1
• 重原子数：
  15
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  107
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  乙酸酐 、 (3S,4R,5R)-1-Allyloxy-3,4,5,6-tetrahydroxy-hexan-2-one 在 硫酸 作用下， 生成 Acetic acid (2R,3S,4R,5R)-4,5-diacetoxy-2-allyloxymethyl-2-hydroxy-tetrahydro-pyran-3-yl ester 、 Acetic acid (2S,3S,4R,5R)-3,4,5-triacetoxy-2-allyloxymethyl-tetrahydro-pyran-2-yl ester
  参考文献：
  名称：

  Distribution of tautomers in acylated ketoses an important factor in ketoside synthesis

  摘要：

  DOI：

  10.1016/s0040-4039(00)81407-0
• 作为产物：
  描述：

  (4aR,5aR,9aR,9bS)-4a-Allyloxy-2,2,8,8-tetramethyl-hexahydro-furo[3,2-d;4,5-d']bis[1,3]dioxine 在 硫酸 作用下， 反应 2.0h， 生成 (3S,4R,5R)-1-Allyloxy-3,4,5,6-tetrahydroxy-hexan-2-one
  参考文献：
  名称：

  Distribution of tautomers in acylated ketoses an important factor in ketoside synthesis

  摘要：

  DOI：

  10.1016/s0040-4039(00)81407-0

文献信息

• METHODS FOR MANAGING HERBICIDE VAPORIZATION
  申请人：Agquam LLC

  公开号：EP3471540A1

  公开（公告）日：2019-04-24
• Drift Reduction Compositions for Agricultural Use
  申请人：AgQuam LLC

  公开号：US20150045224A1

  公开（公告）日：2015-02-12

  The present disclosure relates generally to the field of agricultural chemicals and, more particularly, to compositions which can be added to agricultural chemicals for the purpose of improving efficacy and reducing drift of sprayed chemicals away from target areas. Further disclosed are processes for preparing combination water conditioning adjuvant and drift reduction compositions as well as methods of drift reduction utilizing such compositions.
• US9854795B2
  申请人：——

  公开号：US9854795B2

  公开（公告）日：2018-01-02
• [EN] METHODS FOR MANAGING HERBICIDE VAPORIZATION<br/>[FR] PROCÉDÉS DE GESTION DE LA VAPORISATION D'HERBICIDES
  申请人：AGQUAM LLC

  公开号：WO2017222992A1

  公开（公告）日：2017-12-28

  The present disclosure relates generally to the field of methods for conditioning water in the preparation of agricultural sprays for application of herbicides. The methods further relate to drift reduction of such agricultural sprays. In particular, while providing water conditioning and potentially drift reduction as well, the methods do not increase or effectively reduce vaporization of the herbicides carried within the agricultural sprays.