ethyl-α-D-xyloside | 22348-13-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: ethyl-α-D-xyloside
• 英文别名: ethyl α-D-xylopyranose；Ethyl-α-D-xylopyranosid；Aethyl-(α-D-xylopyranosid)；(2S,3R,4S,5R)-2-ethoxyoxane-3,4,5-triol
• CAS: 22348-13-6
• 化学式: C₇H₁₄O₅
• 分子量: 178.185
• InChiKey: UBUITGRMYNAZAX-UCROKIRRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.6
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  79.2
• 氢给体数：
  3
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  D-吡喃木糖 、 乙醇 在 1-甲基-3-丁基咪唑硫酸氢盐 、 硫酸 作用下， 以 水 为溶剂， 反应 3.0h， 生成 糠醛 、 2-糠醛缩二乙醇 、 ethyl β-D-xylofuranose 、 ethyl α-D-xylofuranose 、 ethyl-α-D-xyloside 、 Ethyl-β-D-xylopyranosid
  参考文献：
  名称：

  Ethanolysis of selected catalysis by functionalized acidic ionic liquids: an unexpected effect of ILs structural functionalization on selectivity phenomena

  摘要：

  酸性咪唑类离子液体的官能化（加入OH基团，去活化C2-H质子）改变了碳水化合物乙醇解反应的选择性。

  DOI：

  10.1039/d1nj04885f

文献信息

• [EN] MULTIVINYLAMINOSILANES AS BRANCHING AGENTS FOR FUNCTIONALIZED ELASTOMERIC POLYMERS<br/>[FR] MULTIVINYLAMINOSILANES UTILISÉS COMME AGENTS DE RAMIFICATION POUR DES POLYMÈRES ÉLASTOMÈRES FONCTIONNALISÉS
  申请人：TRINSEO EUROPE GMBH

  公开号：WO2016131590A1

  公开（公告）日：2016-08-25

  The present invention relates to novel polymerizable multivinylaminosilanes which are useful as branching agents for synthetic and natural rubber. The compounds of the invention can be used as such in the polymerization of conjugated diene monomers, optionally together with aromatic vinyl monomers, thus producing polymers, specifically elastomeric polymers, which can favorably be used in rubber articles such as tires.

  本发明涉及一种新型可聚合的多乙烯胺硅烷，可用作合成和天然橡胶的分支剂。该发明的化合物可直接用于共轭二烯单体的聚合反应中，可选地与芳香族乙烯单体一起使用，从而产生聚合物，特别是弹性聚合物，可有利地用于橡胶制品，如轮胎。
• Methods for improving the efficiency of simultaneous saccharification and fermentation reactions
  申请人：Gutierrez Christina

  公开号：US10138499B2

  公开（公告）日：2018-11-27

  The present disclosure is directed, in a first aspect, to the use of inverting beta-xylosidase enzymes to reduce byproduct formation and increase the yield of fermentation products, as well as, in a second aspect, to the use of retaining beta-xylosidase enzymes to improve production of alkyl-beta-xylopyranoside compounds, in a simultaneous saccharification and fermentation reactions.

  本公开的内容在第一方面是关于在同时进行的糖化和发酵反应中，使用倒置β-木糖苷酶来减少副产品的形成并提高发酵产品的产量，以及在第二方面是关于使用保留β-木糖苷酶来提高烷基-β-木吡喃糖苷化合物的产量。
• Separation of lignin and sugars from biomass pre-treatment liquors
  申请人：Stichting Energieonderzoek Centrum Nederland

  公开号：US10793927B2

  公开（公告）日：2020-10-06

  The invention relates to an improved process for separating lignin and monomeric sugars from a liquor comprising lignin and monomeric sugars in a solvent mixture of water and at least one organic solvent, which employs membrane filtration techniques such as nanofiltration and selective water removal, preferably by permeation through a membrane which is selective for water molecules. The invention further relates to a modular system for executing the process according to the invention. The process and system according to the invention are particularly suitable to be incorporated with pre-treatment of lignocellulosic biomass, in particular by organosolv fractionation or solvolysis.

  本发明涉及一种改进的工艺，用于从在水和至少一种有机溶剂的混合溶剂中含有木质素和单体糖的液体中分离木质素和单体糖，该工艺采用膜过滤技术，如纳滤和选择性脱水，最好是通过对水分子有选择性的膜进行渗透。本发明还涉及一种用于执行本发明工艺的模块化系统。根据本发明的工艺和系统特别适合与木质纤维素生物质的预处理相结合，尤其是通过有机溶胶分馏或溶解。
• METHODS FOR IMPROVING THE EFFICIENCY OF SIMULTANEOUS SACCHARIFICATION AND FERMENTATION REACTIONS
  申请人：Danisco US Inc.

  公开号：EP2516663B1

  公开（公告）日：2020-02-12
• Methods for Improving the Efficiency of Simultaneous Saccharification and Fermentation Reactions
  申请人：Gutierrez Christina

  公开号：US20130143277A1

  公开（公告）日：2013-06-06

  The present disclosure is directed, in a first aspect, to the use of inverting beta-xylosidase enzymes to reduce byproduct formation and increase the yield of fermentation products, as well as, in a second aspect, to the use of retaining beta-xylosidase enzymes to improve production of alkyl-beta-xylopyranoside compounds, in a simultaneous saccharification and fermentation reactions.