2,5-bis(4-(9H-carbazol-9-yl)phenyl)pyridine | 1029944-02-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 2,5-bis(4-(9H-carbazol-9-yl)phenyl)pyridine
• 英文别名: 2,5-bis(4',4''-9H-9-carbazolyl)phenyl pyridine；bcpp；2,5-Bis(4-(carbazol-9-yl)phenyl)pyridine；9-[4-[5-(4-carbazol-9-ylphenyl)pyridin-2-yl]phenyl]carbazole
• CAS: 1029944-02-2
• 化学式: C₄₁H₂₇N₃
• 分子量: 561.685
• InChiKey: OFBIWCOKVPBIQJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.3
• 重原子数：
  44
• 可旋转键数：
  4
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  22.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  氯化铱(III) 水合物 、 2,5-bis(4-(9H-carbazol-9-yl)phenyl)pyridine 以 乙二醇乙醚 、 水 为溶剂， 生成 [bcpp2Ir(μ-Cl)]2
  参考文献：
  名称：

  Carbazole and arylamine functionalized iridium complexes for efficient electro-phosphorescent light-emitting diodes

  摘要：

  We report the synthesis and characterization of four cyclometalated iridium complexes based on carbazole and arylamine modified 2-phenylpyridine. The carbazole and arylamine groups are linked to 2-phenyl pyridine backbone to enhance the energy harvesting and transfer from host to guest materials. The electrochemical and photophysical properties of the complexes are studied and electroluminescent devices are fabricated. The results show that the complexes with ligands containing carbazole moieties have desirable phosphorescent properties. The device with complex 3 doped PVK (poly (vinylcarbazole)) as emission layer achieves maximum luminous efficiency of 6.56 cd A (1) and maximum brightness of 14448 cd m (2). (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.01.095
• 作为产物：
  描述：

  9-(4-溴苯基)咔唑 在 四(三苯基膦)钯 、 正丁基锂 、 potassium carbonate 作用下， 以 四氢呋喃 、 乙醇 、 甲苯 为溶剂， 反应 42.0h， 生成 2,5-bis(4-(9H-carbazol-9-yl)phenyl)pyridine
  参考文献：
  名称：

  Carbazole and arylamine functionalized iridium complexes for efficient electro-phosphorescent light-emitting diodes

  摘要：

  We report the synthesis and characterization of four cyclometalated iridium complexes based on carbazole and arylamine modified 2-phenylpyridine. The carbazole and arylamine groups are linked to 2-phenyl pyridine backbone to enhance the energy harvesting and transfer from host to guest materials. The electrochemical and photophysical properties of the complexes are studied and electroluminescent devices are fabricated. The results show that the complexes with ligands containing carbazole moieties have desirable phosphorescent properties. The device with complex 3 doped PVK (poly (vinylcarbazole)) as emission layer achieves maximum luminous efficiency of 6.56 cd A (1) and maximum brightness of 14448 cd m (2). (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.01.095

文献信息

• ORGANIC EL DEVICE
  申请人：Nishimura Kazuki

  公开号：US20100207110A1

  公开（公告）日：2010-08-19

  An organic EL device includes: an anode for injecting holes; a phosphorescent-emitting layer; a fluorescent-emitting layer; and a cathode for injecting electrons. The phosphorescent-emitting layer contains a phosphorescent host and a phosphorescent dopant for phosphorescent emission. The fluorescent-emitting layer contains a fluorescent host and a fluorescent dopant for fluorescent emission. The fluorescent host is at least one of an asymmetric anthracene derivative represented by a formula (1) below and a pyrene derivative represented by a formula (2) below.
• ORGANIC EL ELEMENT AND ORGANIC EL MATERIAL-CONTAINING SOLUTION
  申请人：Nishimura Kazuki

  公开号：US20100270539A1

  公开（公告）日：2010-10-28

  An organic EL device ( 1 ) includes an anode ( 3 ), a cathode ( 4 ) and an organic thin-film layer ( 5 ) provided between the anode ( 3 ) and the cathode ( 4 ). The organic thin-film layer ( 5 ) includes a single-layered mixed-color emitting layer ( 51 ) for providing mixed-color emission. The mixed-color emitting layer ( 51 ) contains a host, a fluorescent dopant for blue fluorescent emission and a phosphorescent dopant for red or green phosphorescent emission.
• ORGANIC EL DEVICE AND ANTHRACENE DERIVATIVE
  申请人：NISHIMURA Kazuki

  公开号：US20130187143A1

  公开（公告）日：2013-07-25

  An organic EL device includes: an anode for injecting holes; a phosphorescent-emitting layer; a fluorescent-emitting layer; and a cathode for injecting electrons. The phosphorescent-emitting layer contains a phosphorescent host and a phosphorescent dopant for phosphorescent emission. The fluorescent-emitting layer contains a fluorescent host and a fluorescent dopant for fluorescent emission. The fluorescent host is at least one of an asymmetric anthracene derivative represented by a formula (1) below and a pyrene derivative represented by a formula (2) below.
• US8294142B2
  申请人：——

  公开号：US8294142B2

  公开（公告）日：2012-10-23
• US8426036B2
  申请人：——

  公开号：US8426036B2

  公开（公告）日：2013-04-23