2-[2-[1-[2-[4-[2-Methyl-2-[1-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]propanoyl]phenoxy]ethoxy]ethoxy]ethoxy]ethyl prop-2-enoate | 1231708-01-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-[2-[1-[2-[4-[2-Methyl-2-[1-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]propanoyl]phenoxy]ethoxy]ethoxy]ethoxy]ethyl prop-2-enoate
• CAS: 1231708-01-2
• 化学式: C₃₀H₄₄O₁₂
• 分子量: 596.672
• InChiKey: DASRTYPCQGZMDQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  42
• 可旋转键数：
  27
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  134
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  丙烯酸乙烯基乙氧基乙酯 、 2-羟基-4'-(2-羟乙氧基)-2-甲基苯丙酮 在 poly(vinylpyridine) chlorohydrate, cross-linked with 2percent divinyl benzene 2,6-二叔丁基-4-甲基苯酚 作用下， 反应 16.0h， 生成 2-[2-[1-[2-[4-[2-Methyl-2-[1-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]propanoyl]phenoxy]ethoxy]ethoxy]ethoxy]ethyl prop-2-enoate
  参考文献：
  名称：

  Polymerizable photoinitiators and radiation curable compositions

  摘要：

  公开号：

  EP2199273B1

文献信息

• POLYMERIZABLE POLYMERIC PHOTOINITIATORS AND RADIATION CURABLE COMPOSITIONS
  申请人：Loccufier Johan

  公开号：US20120046376A1

  公开（公告）日：2012-02-23

  A polymerizable polymeric photoinitiator according to Formula (I): wherein: PL represents an n+m+p-functional polymeric core; n and m independently represent an integer from 1 to 30; p represents an integer from 0 to 10; o is 0 or 1; INI represents a group selected from the group consisting of a benzophenone, a thioxanthone, a carbazole, a anthraquinone, a camphor quinone, an α-hydroxyalkylphenone, an α-aminoalkylphenone, an acylphosphine oxide, a bisacyl phosphine oxide, an acylphosphine sulfide, a phenyl glyoxalate, a benzoin ether, a benzyl ketal, an α-dialkoxyacetophenone, a carbazolyl-O-acyl-oxime, an α-haloarylketone and an α-haloaryl sulfone; L 3 and L 4 represent a substituted or unsubstituted divalent linking group comprising 1 to 14 carbon atoms; A represents a radically polymerizable functional group selected from the group consisting of an acrylate, a methacrylate, a styrene, an acryl amide, a methacryl amide, a maleate, a fumarate, an itaconate, an vinyl ether, an allyl ether, an allyl ester, a maleimide, a vinyl nitrile and a vinyl ester; and R4 represents a substituted or unsubstituted alkyl group. Radiation curable compositions containing the polymerizable polymeric photoinitiator and methods for preparing the polymerizable polymeric photoinitiator are also disclosed.

  根据公式（I），提供一种可聚合的聚合物光引发剂： 其中： PL代表n+m+p-功能的聚合物核心； n和m分别表示1到30的整数； p表示0到10的整数； o为0或1； INI代表从苯基苯酮、噻吩酮、咔唑、蒽醌、樟脑酮、α-羟基烷基苯酮、α-氨基烷基苯酮、酰基膦氧化物、双酰膦氧化物、酰基膦硫化物、苯基乙二酸酯、苯甲醚、苄基酮、α-二烷氧基苯酮、咔唑基-O-酰基-肟、α-卤代芳基酮和α-卤代芳基磺酸盐组成的群中选择的基团； L3和L4代表含有1到14个碳原子的取代或未取代的二价连接基团； A代表从丙烯酸酯、甲基丙烯酸酯、苯乙烯、丙烯酰胺、甲基丙烯酰胺、马来酸酯、富马酸酯、顺丁烯二酸酯、乙烯基醚、烯丙基醚、烯丙酸酯、马来酰亚胺、乙烯基腈和乙烯酸酯组成的可自由基聚合的功能基团； R4代表取代或未取代的烷基。 还公开了含有可聚合的聚合物光引发剂的辐射固化组合物以及制备可聚合的聚合物光引发剂的方法。
• POLYMERIZABLE PHOTOINITIATORS AND RADIATION CURABLE COMPOSITIONS
  申请人：Loccufier Johan

  公开号：US20110224324A1

  公开（公告）日：2011-09-15

  A polymerizable photoinitiator is represented by Formula (I): wherein R1, R2 and R3 are independently selected from the group consisting of a hydrogen, an optionally substituted alkyl group and an optionally substituted aryl group or R1 and R3 represent the necessary atoms to form a five to eight membered ring; p, w, y and z are all integers with y representing a value 1 to 6; p representing the sum of w and z; p representing a value of 1 to 6; w=1 to (p−z) and z=0 to (p−w); L represents an optionally substituted (p+y)-valent linking group comprising 1 to 14 carbon atoms; A represents a radically polymerizable group selected from the group consisting of an acrylate group, a methacrylate group, a styrene group, an acryl amide group, a methacryl amide group, a maleate group, a fumarate group, an itaconate group, a vinyl ether group, an allyl ether group, an allyl ester group and a vinyl ester group; and X represents a photoinitiating moiety including at least one group capable of initiating a free radical polymerization reaction upon exposure to actinic radiation.
• US8492452B2
  申请人：——

  公开号：US8492452B2

  公开（公告）日：2013-07-23
• US8883873B2
  申请人：——

  公开号：US8883873B2

  公开（公告）日：2014-11-11