2,9-bis(4-(9H-carbazol-9-yl)phenyl)-4,7-diphenyl-1,10-phenanthroline | 1009362-84-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 2,9-bis(4-(9H-carbazol-9-yl)phenyl)-4,7-diphenyl-1,10-phenanthroline
• 英文别名: 2,9-Bis(4-carbazol-9-ylphenyl)-4,7-diphenyl-1,10-phenanthroline
• CAS: 1009362-84-8
• 化学式: C₆₀H₃₈N₄
• 分子量: 814.989
• InChiKey: IVOQSFSFOZHNHJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.2
• 重原子数：
  64
• 可旋转键数：
  6
• 环数：
  13.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  35.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  9-(4-溴苯基)咔唑 、 4,7-二苯基-1,10-菲罗啉 在 正丁基锂 、 manganese(IV) oxide 作用下， 以 乙醚 、 正己烷 、 甲苯 、 二氯甲烷 为溶剂， 反应 32.0h， 以52.3%的产率得到2,9-bis(4-(9H-carbazol-9-yl)phenyl)-4,7-diphenyl-1,10-phenanthroline
  参考文献：
  名称：

  Novel Bipolar Bathophenanthroline Containing Hosts for Highly Efficient Phosphorescent OLEDs

  摘要：

  The electronic structures of eight bathophenanthroline derivatives were elucidated by DFT calculations, and four representatives of which CZBP, m-CZBP, m-TPAP, and BPABP were synthesized and employed as the hosts to afford highly efficient phosphorescent OLEDs. The calculated molecular orbital energies agree well with the experimental results, which further demonstrates that the localization of HOMO and LUMO at the respective hole- and electron-transporting moieties is desirable in bipolar molecular designs.

  DOI：

  10.1021/ol702773d

文献信息

• Metal complex organic electroluminescent material and organic electroluminescent device
  申请人：SHIJIAZHUANG CHENGZHI YONGHUA DISPLAY MATERIAL CO., LTD.

  公开号：US11424418B2

  公开（公告）日：2022-08-23

  The present invention relates to an organic electroluminescent material, an organic electroluminescent device, and a method for preparing the organic electroluminescent device. Due to comprising an organic compound A with 3.0 eV>ET≥2.0 eV and a compound B of M(LA)x(LB)y(LC)z, the organic electroluminescent material of the present invention has the advantages of an increased luminescence lifetime and/or a reduced operating voltage on the basis of maintaining other electronic properties at a certain level.

  本发明涉及一种有机电致发光材料、一种有机电致发光器件和一种制备有机电致发光器件的方法。由于包含 3.0 eV>ET≥2.0 eV 的有机化合物 A 和 M(LA)x(LB)y(LC)z 的化合物 B，本发明的有机电致发光材料具有在保持其他电子特性在一定水平的基础上提高发光寿命和/或降低工作电压的优点。
• ORGANIC ELECTROLUMINESCENT MATERIAL AND ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：SHIJIAZHUANG CHENGZHI YONGHUA DISPLAY MATERIAL CO., LTD.

  公开号：US20200381633A1

  公开（公告）日：2020-12-03

  The present invention relates to an organic electroluminescent material, an organic electroluminescent device, and a method for preparing the organic electroluminescent device. Due to comprising an organic compound A with 3.0 eV>ET≥2.0 eV and a compound B of M(LA)x(LB)y(LC)z, the organic electroluminescent material of the present invention has the advantages of an increased luminescence lifetime and/or a reduced operating voltage on the basis of maintaining other electronic properties at a certain level.
• US7517596B2
  申请人：——

  公开号：US7517596B2

  公开（公告）日：2009-04-14
• Novel Bipolar Bathophenanthroline Containing Hosts for Highly Efficient Phosphorescent OLEDs
  作者：Ziyi Ge、Teruaki Hayakawa、Shinji Ando、Mitsuru Ueda、Toshiyuki Akiike、Hidetoshi Miyamoto、Toru Kajita、Masa-aki Kakimoto

  DOI：10.1021/ol702773d

  日期：2008.2.1

  The electronic structures of eight bathophenanthroline derivatives were elucidated by DFT calculations, and four representatives of which CZBP, m-CZBP, m-TPAP, and BPABP were synthesized and employed as the hosts to afford highly efficient phosphorescent OLEDs. The calculated molecular orbital energies agree well with the experimental results, which further demonstrates that the localization of HOMO and LUMO at the respective hole- and electron-transporting moieties is desirable in bipolar molecular designs.