申请人:FUJI PHOTO FILM CO., LTD.
公开号:EP0416591A2
公开(公告)日:1991-03-13
An electrophotographic light-sensitive material comprising a support having provided thereon at least one photoconductive layer containing an inorganic photoconductive substance and a binder resin, wherein the binder resin comprises (A) at least one resin having a weight average molecular weight of from 1 x 103 to 2x 104 and containing not less than 30% by weight of a copolymerizable component corresponding to a repeating unit represented by the general formula (I) described below and having at least one acidic group selected from the group consisting of -P03H2, -SO3H, -COOH, -OH,
(wherein R represents a hydrocarbon group or -OR (wherein R represents a hydrocarbon group)) and a cyclic acid anhydride-containing group at one of the terminals of the main chain thereof;
wherein a1 and a2 each represents a hydrogen atom, a halogen atom, a cyano group or a hydrocarbon group; and R1 represents a hydrocarbon group; and (B) at least one copolymer having a weight average molecular weight of from 5×104 to 1 x106 and comprising at least a monofunctional macromonomer (M) having a weight average molecular weight of not more than 2×104 and a monomer represented by the general formula (V) described below, the macromonomer (M) comprising at least one polymerizable component corresponding to a repeating unit represented by the general formulae (IVa) and (IVb) described below, and at least one polymerizable component containing at least one acidic group selected from -COOH, -P03H2, -SO3H, -OH,
(wherein Ro represents a hydrocarbon group or -ORo (wherein Ro represents a hydrocarbon group)), -CHO, and an acid anhydride-containing group, and the macromonomer (M) having a polymerizable double bond group represented by the general formula (III) described below bonded to only one terminal of the main chain of the polymer;
wherein Xo represents -COO-, -OCO-, -CH20CO-, -CH2COO-, -0-, S02-, CO-, -CONHCOO-, CONHCONH-,
(wherein R31 represents a hydrogen atom or a hydrocarbon group), and c1 and c2, which may be the same or different, each represents a hydrogen atom, a halogen atom, a cyano group, a hydrocarbon group, -COO-Z1 or -COO-Z1 bonded via a hydrocarbon group (wherein Z1 represents a hydrogen atom or a hydrocarbon group which may be substituted);
wherein X1 has the same meaning as Xo in the general formula (III); Q1 represents an aliphatic group having from 1 to 18 carbon atoms or an aromatic group having from 6 to 12 carbon atoms; d1 and d2, which may be the same or different, have the same meaning as c1 and c2 in the general formula (III); and Qo represents -CN, -CONH2, or
(wherein Y represents a hydrogen atom, a halogen atom, an alkoxy group or -COOZ2 (wherein Z2 represents an alkyl group, an aralkyl group, or an aryl'group));
wherein X2 has the same meaning as X1 in the general formula (IVa); Q2 has the same meaning as Q1 in the general formula (lVa); and e1 and e2, which may be the same of different, have the same meaning as c1 and c2 in the general formula (III).
The electrophotographic light-sensitive material exhibits excellent electrostatic characteristics and mechanical strength even under severe conditions. Also it is advantageously employed in the scanning exposure system using a semiconductor laser beam.
一种电致发光感光材料,包括一个支撑体,支撑体上至少有一层光电导层,该层含有一种无机光电导物质和一种粘结剂树脂,其中粘结剂树脂包括 (A) 至少一种树脂,该树脂的重量平均分子量为 1 x 103 至 2x 104,并含有不少于 30%(按重量计)的可共聚组分,该组分与下述通式(I)所代表的重复单元相对应,并具有至少一个酸性基团,该酸性基团选自由-P03H2、-SO3H、-COOH、-OH 组成的组、
(其中 R 代表烃基或-OR(其中 R 代表烃基))组成的组中选出,并在其主链的一个末端具有一个含环状酸酐的基团;
其中 a1 和 a2 分别代表氢原子、卤素原子、氰基或烃基;R1 代表烃基;和(B) 至少一种共聚物,其重量平均分子量为 5×104 至 1×106 并至少包括一种单官能团大单体(M),其重量平均分子量不大于 2×104 和一种由下述通式(V)代表的单体、大单体(M)包括至少一种与下述通式(IVa)和(IVb)所代表的重复单元相对应的可聚合组分,以及至少一种含有至少一种选自-COOH、-P03H2、-SO3H、-OH的酸性基团的可聚合组分、
(其中 Ro 代表烃基或-ORo(其中 Ro 代表烃基))、-CHO 和含酸酐的基团,以及大单体(M)具有仅与聚合物主链的一个末端键合的由下述通式(III)表示的可聚合双键基团;
其中 Xo 代表-COO-、-OCO-、-CH20CO-、-CH2COO-、-0-、S02-、CO-、-CONHCOO-、CONHCONH-、
(其中 R31 代表氢原子或烃基,c1 和 c2 可以相同或不同,各自代表氢原子、卤素原子、氰基、烃基、-COO-Z1 或通过烃基键合的-COO-Z1(其中 Z1 代表氢原子或可被取代的烃基);
其中 X1 与通式(III)中的 Xo 意义相同;Q1 代表具有 1 至 18 个碳原子的脂肪族基团或具有 6 至 12 个碳原子的芳香族基团;d1 和 d2(可以相同或不同)与通式(III)中的 c1 和 c2 意义相同;以及 Qo 代表-CN、-CONH2 或 Y(其中 Y 代表氢原子)。
(其中 Y 代表氢原子、卤素原子、烷氧基或 -COOZ2(其中 Z2 代表烷基、芳烷基或芳基));
其中 X2 与通式(IVa)中的 X1 意义相同;Q2 与通式(lVa)中的 Q1 意义相同;e1 和 e2(可以相同或不同)与通式(III)中的 c1 和 c2 意义相同。
这种电子照相感光材料即使在苛刻的条件下也能表现出优异的静电特性和机械强度。此外,在使用半导体激光束的扫描曝光系统中使用这种材料也非常有利。