1,9-dihydroxyphenanthrene | 85337-40-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 1,9-dihydroxyphenanthrene
• 英文别名: phenanthrene-1,9-diol；Phenanthren-1,9-diol；1.9-Dihydroxy-phenanthren；1,9-Phenanthrenediol
• CAS: 85337-40-2
• 化学式: C₁₄H₁₀O₂
• 分子量: 210.232
• InChiKey: ACQLQQHWNCHBLM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  重氮甲烷 、 1,9-dihydroxyphenanthrene 生成 1,9-dimethoxy-phenanthrene
  参考文献：
  名称：

  Oxygen sensitization of electron capture response to isomers of polycyclic aromatic amines and hydroxides

  摘要：

  DOI：

  10.1021/ac00259a034
• 作为产物：
  描述：

  2-bromo-9-methoxy-1-oxo-1,2,3,4-tetrahydrophenanthrene 在 氢溴酸 、 sodium acetate 、 溶剂黄146 、 苯 作用下， 生成 1,9-dihydroxyphenanthrene
  参考文献：
  名称：

  Studies in the Phenanthrene Series. XVII. Amino Alcohols Derived from 9-Hydroxy-1,2,3,4-tetrahydrophenanthrene¹

  摘要：

  DOI：

  10.1021/ja01274a004

文献信息

• Elimination of acetic acid from protonated 4,5-diacetoxyphenanthrene and 2,2′-diacetoxybiphenyl: An example of an ion chemistry proximity effect
  作者：M. Orlando、M. George、M. L. Gross

  DOI：10.1002/oms.1210281033

  日期：1993.10

  AbstractProtonated 4,5‐diacetoxyphenanthrene and 2,2′‐diacetoxybiphenyl dissociate, owing to the interaction of the two acetoxy groups, by eliminating a molecule of acetic acid. This novel proximity effect, which occurs for a fast atom bombardment‐produced closed‐shell ion, was examined in detail using tandem mass spectrometric methods. This process, which was first observed in the decompositions of acetylated complex natural products such as stentorin and hypericin, may serve as a general process for determining the proximity of hydroxyl groups in polycyclic aromatic compounds.
• METHODS AND SYSTEMS OF GRAFT POLYMERIZATION ON A FUNCTIONALIZED SUBSTRATE
  申请人：Spevacek John A.

  公开号：US20140296366A1

  公开（公告）日：2014-10-02

  Graft polymerization is fullfiled on a functionalized substrate. The functionalized substrate is prepared from a disulfide bond-containing feedstock and has been prepared for polymerization through the introduction of one or more polyfunctional monomers containing a disulfide bond breaking material functional group.
• US9267009B2
  申请人：——

  公开号：US9267009B2

  公开（公告）日：2016-02-23
• US9676907B2
  申请人：——

  公开号：US9676907B2

  公开（公告）日：2017-06-13