bis[4-(dodecyloxy)phenyl]-1,2,4,5-tetrazine | 1492902-78-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: bis[4-(dodecyloxy)phenyl]-1,2,4,5-tetrazine
• 英文别名: 3,6-Bis(4-dodecoxyphenyl)-1,2,4,5-tetrazine；3,6-bis(4-dodecoxyphenyl)-1,2,4,5-tetrazine
• CAS: 1492902-78-9
• 化学式: C₃₈H₅₈N₄O₂
• 分子量: 602.904
• InChiKey: FOVMOJWXKNNXPC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13
• 重原子数：
  44
• 可旋转键数：
  26
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.63
• 拓扑面积：
  70
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  5-(4-dodecyloxyphenyl)tetrazole 在 potassium tert-butylate 作用下， 以 苯甲腈 、 N,N-二甲基甲酰胺 为溶剂， 反应 22.0h， 生成 bis[4-(dodecyloxy)phenyl]-1,2,4,5-tetrazine
  参考文献：
  名称：

  Liquid Crystalline Symmetrical 3,6-Diaryl-1,2,4,5-Tetrazines

  摘要：

  A new series of symmetrical 3,6-diphenyl-1,2,4,5-tetrazines with four alkoxy tails were synthesized along with new examples with two alkoxy tails. Mesogenic properties were studied by differential scanning calorimetry and polarizing optical microscopy. The influence of the number and length of alkoxy chains attached to the 3,6-diphenyl-1,2,4,5-tetrazine core is discussed. Compared with the two-tailed tetrazines, 6 the four-tailed liquid crystalline tetrazines, 5e-g possess lower smectic-C phase transitions, and clearing point temperatures.

  DOI：

  10.1080/15421406.2013.791585

文献信息

• Liquid Crystalline Symmetrical 3,6-Diaryl-1,2,4,5-Tetrazines
  作者：Farid Fouad、Brett Ellman、Scott Bunge、Patrik Miller、Robert Twieg

  DOI：10.1080/15421406.2013.791585

  日期：2013.10.1

  A new series of symmetrical 3,6-diphenyl-1,2,4,5-tetrazines with four alkoxy tails were synthesized along with new examples with two alkoxy tails. Mesogenic properties were studied by differential scanning calorimetry and polarizing optical microscopy. The influence of the number and length of alkoxy chains attached to the 3,6-diphenyl-1,2,4,5-tetrazine core is discussed. Compared with the two-tailed tetrazines, 6 the four-tailed liquid crystalline tetrazines, 5e-g possess lower smectic-C phase transitions, and clearing point temperatures.