di-n-butylbis(2,4-dihydroxybenzoato)tin(IV) | 171056-90-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: di-n-butylbis(2,4-dihydroxybenzoato)tin(IV)
• CAS: 171056-90-9
• 化学式: C₂₂H₂₈O₈Sn
• 分子量: 539.17
• InChiKey: ROHAGJQRQMQJQX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,4-二羟基苯甲酸 、 二正丁基氧化锡 以 甲苯 为溶剂， 生成 di-n-butylbis(2,4-dihydroxybenzoato)tin(IV)
  参考文献：
  名称：

  Synthesis and characterization of di-n-butylbis(2,4-dihydroxybenzoato tin(IV)

  摘要：

  The compound di-n-butylbis(2,4-dihydroxybenzoato)tin(IV), (C4H9)(2)Sn[2,4-(OH)(2)C6H3COO](2) has been synthesized and characterized by elemental analysis, IR and NMR (H-1, C-13 and Sn-119) spectroscopy and X-ray diffraction techniques. The compound is monomeric with the Sn atom existing in a skew-trapezoidal bipyramidal geometry, in which the asymmetrically chelating carboxylate ligands comprise the trapezoidal plane and the butyl groups occupy the axial positions with the C-Sn-C angle 139.0(3)degrees. Both of the oxygen atoms from the hydroxy groups residing on the ligand do not participate in bonding to the tin atom. However, in the crystal lattice, there are intermolecular hydrogen bonds of OH...O' type which bond the related molecules together. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00152-6