2-benzoyl-2-dimethylamino-3-phenylpropane | 69262-52-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 直链 1,3-二芳基丙烷
• 英文名称: 2-benzoyl-2-dimethylamino-3-phenylpropane
• 英文别名: 2-dimethylamino-2-methyl-1,3-diphenyl-propan-1-one；2-Dimethylamino-2-methyl-1,3-diphenyl-propan-1-on；2-benzyl-2-(dimethylamino)-1-phenyl-propan-1-one；2-(Dimethylamino)-2-methyl-1,3-diphenylpropan-1-one
• CAS: 69262-52-8
• 化学式: C₁₈H₂₁NO
• 分子量: 267.371
• InChiKey: YMRJHYMRLWNYHC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  20.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-benzoyl-2-dimethylamino-3-phenylpropane 在 溶剂黄146 、 锌 作用下， 反应 1.25h， 以90%的产率得到2-甲基-1,3-二苯基丙烷-1-酮
  参考文献：
  名称：

  Chantrapromma, Kan; Ollis, W. David; Sutherland, Ian O., Journal of the Chemical Society. Perkin transactions I, 1983, # 5, p. 1049 - 1062

  摘要：

  DOI：
• 作为产物：
  描述：

  N-benzyl-N-(1-benzoylethyl)-N,N-dimethylammonium bromide 在 lithium alkoxide of (-)-borneol 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以29%的产率得到2-benzoyl-2-dimethylamino-3-phenylpropane
  参考文献：
  名称：

  使用糖衍生的醇盐作为手性促进剂的对映选择性 [1,2]-史蒂文斯重排

  摘要：

  通过使用新开发的 D-葡萄糖衍生的醇锂作为手性促进剂，实现了对映选择性碱基诱导的 [1,2]-史蒂文斯重排的第一个例子。这种重排提供了具有对映体富集形式的假季铵手性中心的α-氨基酮。

  DOI：

  10.1055/s-2008-1032107

文献信息

• 263. Degradation of quaternary ammonium salts. Part VII. New cases of radical migration
  作者：Thomas Thomson、Thomas Stevens Stevens

  DOI：10.1039/jr9320001932

  日期：——
• CHANTRAPROMMA, K.;OLLIS, W. D.;SUTHERLAND, I. O., J. CHEM. SOC. PERKIN TRANS., 1983, N 5, 1049-1061
  作者：CHANTRAPROMMA, K.、OLLIS, W. D.、SUTHERLAND, I. O.

  DOI：——

  日期：——
• Neue alpha-Aminoacetophenone als Photoinitiatoren
  申请人：CIBA-GEIGY AG

  公开号：EP0284561B1

  公开（公告）日：1993-05-12
• FORMING CATALYTIC SITES FROM REDUCIBLE SILVER-HETEROCYCLIC COMPLEXES
  申请人：Shukla Deepak

  公开号：US20160167037A1

  公开（公告）日：2016-06-16

  A non-aqueous metal catalytic composition includes (a) a complex of silver and a hindered aromatic N-heterocycle comprising reducible silver ions in an amount of at least 2 weight %, (b) a silver ion photoreducing composition in an amount of at least 1 weight %, and (c) a photocurable component, a non-curable polymer, or a combination of a photocurable component and a non-curable polymer. This non-aqueous metal catalytic composition can be used to form silver metal particles in situ during suitable reducing conditions. The silver metal can be provided in a suitable layer or pattern on a substrate, which can then be subsequently subjected to electroless plating to form electrically-conductive layers or patterns for use in various articles or as touch screen displays in electronic devices.
• FORMING SILVER CATALYTIC SITES FROM SILVER PHOSPHITE CARBOXYLATES
  申请人：Shukla Deepak

  公开号：US20160167019A1

  公开（公告）日：2016-06-16

  A non-aqueous metal catalytic composition includes (a) a silver carboxylate-trialkyl(triaryl)phosphite complex comprising reducible silver ions in an amount of at least 2 weight %, (b) a silver ion photoreducing composition in an amount of at least 1 weight %, and (c) a photocurable component or a non-curable polymer or a combination of a photocurable component and a non-curable polymer. This non-aqueous metal catalytic composition can be used to form silver metal particles in situ during suitable reducing conditions. The silver metal can be provided in a suitable layer or pattern on a substrate, which can then be subsequently subjected to electroless plating to form electrically-conductive layers or patterns for use in various articles or as touch screen displays in electronic devices.