3-methylimino-2,4-dioxo-1,5-dioxaspiro[5.5]undecane N-oxide | 205595-15-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-methylimino-2,4-dioxo-1,5-dioxaspiro[5.5]undecane N-oxide
• 英文别名: N-methyl-2,4-dioxo-1,5-dioxaspiro[5.5]undecan-3-imine oxide
• CAS: 205595-15-9
• 化学式: C₁₀H₁₃NO₅
• 分子量: 227.217
• InChiKey: LVGUITLQRPFXSG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  81.4
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  3-methylimino-2,4-dioxo-1,5-dioxaspiro[5.5]undecane N-oxide 以 乙腈 为溶剂， 反应 52.0h， 以90%的产率得到2-Methyl-1,5,12-trioxa-2-aza-dispiro[3.1.5.2]tridecane-3,13-dione
  参考文献：
  名称：

  Methylation of 5-Isonitroso-1,3-dioxine- 4,6-diones with Diazomethane and Some Reactions of Its Products

  摘要：

  Methylation of 5-isonitroso-1,3-dioxine-4,6-diones (1) with diazomethane afforded 5-methoxyimino-1,3-dioxine-4,6-diones (4) and 5-methylimino-1,3-dioxine-4,6-dione N-oxides (5) together with a cyclic nitrone (7) as a minor product. Compound (5) reacted with two molar equivalents of triphenylphosphine to give phosphonium betaines (8) whereas photoreaction of 5 formed novel spiro compounds (9)via oxaziridine intermediates (G).

  DOI：

  10.3987/com-97-s(n)42
• 作为产物：
  描述：

  重氮甲烷 、 3-isonitroso-2,4-dioxo-1,5-dioxaspiro[5.5]undecane 以 乙醚 为溶剂， 反应 0.5h， 以2%的产率得到3-methoxycarbonyl-2-oxo-4-oxy-4-aza-1-oxaspiro[5.4]dec-3-ene
  参考文献：
  名称：

  Methylation of 5-Isonitroso-1,3-dioxine- 4,6-diones with Diazomethane and Some Reactions of Its Products

  摘要：

  Methylation of 5-isonitroso-1,3-dioxine-4,6-diones (1) with diazomethane afforded 5-methoxyimino-1,3-dioxine-4,6-diones (4) and 5-methylimino-1,3-dioxine-4,6-dione N-oxides (5) together with a cyclic nitrone (7) as a minor product. Compound (5) reacted with two molar equivalents of triphenylphosphine to give phosphonium betaines (8) whereas photoreaction of 5 formed novel spiro compounds (9)via oxaziridine intermediates (G).

  DOI：

  10.3987/com-97-s(n)42