(2-{2-[2-(2-乙氧基-乙氧基)-乙氧基]-乙氧基}-乙氧基)-乙烯 | 60558-75-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: (2-{2-[2-(2-乙氧基-乙氧基)-乙氧基]-乙氧基}-乙氧基)-乙烯
• 英文名称: (2-{2-[2-(2-ethoxy-ethoxy)-ethoxy]-ethoxy}-ethoxy)-ethene
• 英文别名: 1-[2-[2-(2-ethenoxyethoxy)ethoxy]ethoxy]-2-ethoxyethane
• CAS: 60558-75-0
• 化学式: C₁₂H₂₄O₅
• 分子量: 248.32
• InChiKey: NOXDFJPKXNNWPR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  17
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  46.2
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  (2-{2-[2-(2-乙氧基-乙氧基)-乙氧基]-乙氧基}-乙氧基)-乙烯 在 盐酸 作用下， 生成 3,6,9,12-四氧十四烷-1-醇
  参考文献：
  名称：

  Hiratani,K. et al., Israel Journal of Chemistry, 1979, vol. 18, p. 208 - 213

  摘要：

  DOI：

文献信息

• Composition and method for preparing linear copolymers of polar and non-polar olefins absent free radical addition polymer
  申请人：Rohm and Haas Company

  公开号：EP1964862A1

  公开（公告）日：2008-09-03

  A polynnerizable composition including a late transition metal complex, a non-polar olefin, a polar olefin, and a free radical scavenger, wherein the polymerizable composition is capable of forming a linear poly[(non-polar olefin)-(polar olefin)] substantially free of free radical addition polymer, is disclosed. A method of copolymerizing a non-polar olefin with a polar olefin, catalyzed by a late transition metal complex in the presence of a free radical scavenger, to produce a linear poly[(non-polar olefin)-(polar olefin)] substantially free of free radical addition polymer is also disclosed.

  本发明公开了一种可聚合组合物，该组合物包括晚过渡金属络合物、非极性烯烃、极性烯烃和自由基清除剂，其中该可聚合组合物能够形成基本上不含自由基加成聚合物的线性聚[（非极性烯烃）-（极性烯烃）]。本发明还公开了一种在游离基清除剂存在下，通过后期过渡金属配合物催化，使非极性烯烃与极性烯烃共聚，从而生成基本上不含游离基加成聚合物的线性聚[（非极性烯烃）-（极性烯烃）]的方法。
• A porous linear polymer composition
  申请人：Rohm and Haas Company

  公开号：EP1964859A1

  公开（公告）日：2008-09-03

  A porous polymer composition including plural linear mixed polarity polymer particles, wherein the particles include a linear poly[(non-polar olefin)-(polar olefin)] and at least one pore, is disclosed, as are those particles further including a catalytic component. A method of forming the plural linear mixed polarity polymer particles is also disclosed. A method of using plural linear mixed polarity polymer particles which include a catalytic component to catalyze polymerization is further disclosed. A porous polymer composition including plural linear non-polar polymer particles and a catalytic component is further disclosed, along with a method of making those linear non-polar polymer particles including the catalytic component and a method of using them to catalyze polymerization.

  本发明公开了一种多孔聚合物组合物，包括多个线性混合极性聚合物颗粒，其中颗粒包括线性聚[（非极性烯烃）-（极性烯烃）]和至少一个孔，这些颗粒还包括催化成分。还公开了一种形成复数线性混合极性聚合物颗粒的方法。还公开了一种使用包含催化成分的复数线性混合极性聚合物颗粒催化聚合的方法。进一步公开了一种包括复数线性非极性聚合物颗粒和催化组分的多孔聚合物组合物，以及制造这些包括催化组分的线性非极性聚合物颗粒的方法和使用它们催化聚合的方法。
• METHOD FOR PRODUCING OXYETHYLENE CHAIN-CONTAINING VINYL ETHER POLYMER BY RADICAL POLYMERIZATION
  申请人：Maruzen Petrochemical Co., Ltd.

  公开号：EP3677603A1

  公开（公告）日：2020-07-08

  [Object] To provide a method for producing a vinyl ether polymer containing an oxyethylene chain in a stable and efficient manner, wherein decomposition of the monomer and generation of polyacetal are suppressed. [Means for solving problem] The method for producing a vinyl ether polymer containing an oxyethylene chain according to the present invention comprises the step of polymerizing vinyl ether represented by the following formula (1): wherein R1 represents an alkyl group having 1 to 3 carbons, and n represents an integer from 1 to 10, in the presence of water as a polymerization solvent, a basic compound as an additive, and an organic azo-based compound as a radical polymerization initiator, and in pH of 5 or more.

  [目的]提供一种稳定、高效地生产含有氧乙烯链的乙烯基醚聚合物的方法，该方法可抑制单体的分解和聚缩醛的生成。 [解决问题的方法] 根据本发明，生产含氧乙烯链的乙烯基醚聚合物的方法包括以下步骤：聚合下式 (1) 所代表的乙烯基醚： 其中 R1 代表具有 1 至 3 个碳原子的烷基，n 代表 1 至 10 的整数、 在有作为聚合溶剂的水、作为添加剂的碱性化合物和作为自由基聚合引发剂的有机偶 氮化合物存在的情况下，pH 值为 5 或以上。
• COMPOSITION, SLURRY FOR POSITIVE ELECTRODE, AND BATTERY
  申请人：Denka Company Limited

  公开号：EP3922653A1

  公开（公告）日：2021-12-15

  A composition serving as a binder with well-balanced peel strength, high-rate discharge capacity retention ratio, and penetration resistance, a slurry for positive electrode, and a secondary battery using the composition is provided. According to the present invention, a composition containing a graft copolymer is provided. The graft copolymer has a stem polymer and a plurality of branch polymers, the stem polymer has a polyvinyl alcohol structure, each of a first monomer unit and a second monomer unit is included in at least one of the plurality of branch polymers, the second monomer unit is different from the first monomer unit, when a content of the polyvinyl alcohol structure in the composition is CPVA% by mass and a total content of the first monomer unit and the second monomer unit in the composition is CM% by mass, the ratio of the content of the polyvinyl alcohol structure to the total content of the first monomer unit and the second monomer unit (CPVA/(CM+CPVA)) is 0.05 to 0.7, and the composition has a swelling degree of 200 to 900% with respect to propylene carbonate.

  本发明提供了一种可用作粘合剂的组合物，该组合物具有均衡的剥离强度、高倍率放电容量保持率和抗穿透性，还提供了一种用于正极的浆料和一种使用该组合物的二次电池。 根据本发明，提供了一种含有接枝共聚物的组合物。该接枝共聚物具有干聚合物和多个支聚合物，干聚合物具有聚乙烯醇结构，多个支聚合物中至少有一个包含第一单体单元和第二单体单元，第二单体单元与第一单体单元不同、当组合物中聚乙烯醇结构的含量为 CPVA%（质量百分比），且组合物中第一单体单元和第二单体单元的总含量为 CM%（质量百分比）时，聚乙烯醇结构的含量与第一单体单元和第二单体单元的总含量之比（CPVA/(CM+CPVA)）为 0.05 至 0.7，相对于碳酸丙烯酯，该组合物的溶胀度为 200 至 900%。
• COMPOSITION
  申请人：Denka Company Limited

  公开号：EP3954721A1

  公开（公告）日：2022-02-16

  A composition with an excellent cycle capacity retention rate at high temperatures is provided. According to the present invention, a composition comprising a graft copolymer, wherein the graft copolymer has a stem polymer and a plurality of branch polymers, the stem polymer has a polyvinyl alcohol structure, each of a first monomer unit and a second monomer unit is included in at least one of the plurality of branch polymers, the second monomer unit is different from the first monomer unit, a glass transition temperature of the composition is 260K to 365K is provided.

  本发明提供了一种在高温下具有优异循环容量保持率的组合物。 根据本发明，提供了一种包含接枝共聚物的组合物，其中接枝共聚物具有干聚合物和多个支聚合物，干聚合物具有聚乙烯醇结构，第一单体单元和第二单体单元中的每一个都包含在多个支聚合物中的至少一个中，第二单体单元与第一单体单元不同，组合物的玻璃化转变温度为 260K 至 365K。