Bz(-2)[Bz(-3)][Bz(-4)][Bz(-6)]Man(a1-2)[Bz(-2)[Bz(-3)][Bz(-4)]Man6Ac(a1-6)][Bz(-3)][Bz(-4)]Man(a)-O-allyl | 414878-10-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Bz(-2)[Bz(-3)][Bz(-4)][Bz(-6)]Man(a1-2)[Bz(-2)[Bz(-3)][Bz(-4)]Man6Ac(a1-6)][Bz(-3)][Bz(-4)]Man(a)-O-allyl
• 英文别名: [(2R,3R,4S,5S,6R)-6-[(2S,3S,4S,5R,6R)-6-[[(2S,3S,4S,5R,6R)-6-(acetyloxymethyl)-3,4,5-tribenzoyloxyoxan-2-yl]oxymethyl]-4,5-dibenzoyloxy-2-prop-2-enoxyoxan-3-yl]oxy-3,4,5-tribenzoyloxyoxan-2-yl]methyl benzoate
• CAS: 414878-10-7
• 化学式: C₈₆H₇₄O₂₆
• 分子量: 1523.52
• InChiKey: FABONDDMCYQVHA-PPOZYKMBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.4
• 重原子数：
  112
• 可旋转键数：
  39
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  318
• 氢给体数：
  0
• 氢受体数：
  26

反应信息

• 作为反应物：
  描述：

  Bz(-2)[Bz(-3)][Bz(-4)][Bz(-6)]Man(a1-2)[Bz(-2)[Bz(-3)][Bz(-4)]Man6Ac(a1-6)][Bz(-3)][Bz(-4)]Man(a)-O-allyl 在 盐酸 作用下， 以 甲醇 为溶剂， 反应 14.0h， 以93%的产率得到Bz(-2)[Bz(-3)][Bz(-4)][Bz(-6)]Man(a1-2)[Bz(-2)[Bz(-3)][Bz(-4)]Man(a1-6)][Bz(-3)][Bz(-4)]Man(a)-O-allyl
  参考文献：
  名称：

  Facile syntheses of d-mannose hexa- and nonasaccharides: the di- and trimer of the trisaccharide repeating unit of the cell-wall mannans of Epidermophyton floccosum, Trychophyton mentagrophytes, Microsporum canis and related species of Microsporum

  摘要：

  A highly efficient strategy for the preparation Of D-mannose hexa- and nonasaccharides, the dimer and trimer of the alpha-D-Manp-(1 --> 6)-[alpha-D-Manp-(1 --> 2)-]D-Manp trisaccharide repeating unit of the cell-wall mannans from the fungi Epidermophyton flovcosum, Trychophyton mentagrophytes, Microsporum canis, ill. cookei and V racemosum, has been developed Using 1,2,6-tri-O-acetyl-3,4-di-O-benzoyl-alpha-D-mannopyranose (6) as the key synthon. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(01)02232-8
• 作为产物：
  描述：

  [(2R,3R,4S,5S,6S)-3,4,5-三苯甲酰氧基-6-(2,2,2-三氯亚氨代乙酰)氧基-四氢吡喃-2-基]甲基苯甲酸酯 、 Bz(-2)[Bz(-3)][Bz(-4)]Man6Ac(a1-6)[Bz(-3)][Bz(-4)]Man(a)-O-allyl 在 三氟甲磺酸三甲基硅酯 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 以85%的产率得到Bz(-2)[Bz(-3)][Bz(-4)][Bz(-6)]Man(a1-2)[Bz(-2)[Bz(-3)][Bz(-4)]Man6Ac(a1-6)][Bz(-3)][Bz(-4)]Man(a)-O-allyl
  参考文献：
  名称：

  Facile syntheses of d-mannose hexa- and nonasaccharides: the di- and trimer of the trisaccharide repeating unit of the cell-wall mannans of Epidermophyton floccosum, Trychophyton mentagrophytes, Microsporum canis and related species of Microsporum

  摘要：

  A highly efficient strategy for the preparation Of D-mannose hexa- and nonasaccharides, the dimer and trimer of the alpha-D-Manp-(1 --> 6)-[alpha-D-Manp-(1 --> 2)-]D-Manp trisaccharide repeating unit of the cell-wall mannans from the fungi Epidermophyton flovcosum, Trychophyton mentagrophytes, Microsporum canis, ill. cookei and V racemosum, has been developed Using 1,2,6-tri-O-acetyl-3,4-di-O-benzoyl-alpha-D-mannopyranose (6) as the key synthon. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(01)02232-8