4-(acryloyloxy)butanoic acid | 141681-03-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 4-(acryloyloxy)butanoic acid
• 英文别名: 4-propenoyloxybutanoic acid；3-carboxypropyl acrylate；acryloyloxy-butyric acid；acryloyloxybutanoic acid；Butanoic acid, 4-[(1-oxo-2-propenyl)oxy]-；4-prop-2-enoyloxybutanoic acid
• CAS: 141681-03-0
• 化学式: C₇H₁₀O₄
• 分子量: 158.154
• InChiKey: HEMYIEDNNZJZSV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  11
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4-(acryloyloxy)butanoic acid 在 N,N-二甲基甲酰胺 氯化亚砜 作用下， 以 甲苯 为溶剂， 反应 0.33h， 生成 (4-Chloro-4-oxobutyl) prop-2-enoate
  参考文献：
  名称：

  [EN] LIQUID-CRYSTALLINE COMPOUNDS, COMPOSITIONS AND THIN FILMS
  [FR] COMPOSÉ, COMPOSITION ET FILM MINCE

  摘要：

  公开号：

  WO2006016724A3
• 作为产物：
  描述：

  1H-吲唑,6-溴-4-氯- 在 chromium(VI) oxide 、 硫酸 作用下， 以 水 、 丙酮 为溶剂， 反应 5.0h， 生成 4-(acryloyloxy)butanoic acid
  参考文献：
  名称：

  [EN] LIQUID-CRYSTALLINE COMPOUNDS, COMPOSITIONS AND THIN FILMS
  [FR] COMPOSÉ, COMPOSITION ET FILM MINCE

  摘要：

  公开号：

  WO2006016724A3

文献信息

• RHODAMINE-BASED COLORING COMPOSITION
  申请人：WAKO PURE CHEMICAL INDUSTRIES, LTD.

  公开号：US20170145216A1

  公开（公告）日：2017-05-25

  A colored resin composition using a conventional rhodamine derivative has not provided heat resistance in a practical range. Therefore, it is an object of the present invention to provide a coloring composition having higher heat resistance as compared with the conventional coloring composition. The present invention relates to a compound represented by the following general formula (1), and a polymer having a monomer unit derived from the compound, and the like. (wherein R 1 to R 4 each independently represent a hydrogen atom, an alkyl group, and the like; R 7 represents a hydrogen atom or a methyl group; R 8 and R 9 each independently represent a hydrogen atom or an alkyl group; Y represents a nitrogen atom or a group represented by the following formula (1-1): A 1 represents an alkylene group which has at least one group selected from —O—, —OCO—, —COO—, —NHCO—, —CONH—, —NHCONH— and an arylene group in the chain, and the like; A 2 represents —NH— or —O—; An − represents an anion containing an aryl group having an electron-withdrawing substituent, and the like; n represents an integer of 0 to 3; R 8 and R 9 may form a cyclic structure of a 5 to 6 membered ring together with —N—(CH 2 ) n —Y— bonding thereto.)

  使用传统的罗丹明衍生物的有色树脂组合物在实际范围内未提供耐热性。因此，本发明的目的是提供一种比传统着色组合物具有更高耐热性的着色组合物。本发明涉及由以下通式（1）所代表的化合物，以及具有源自该化合物的单体单位的聚合物等。（其中R1至R4分别独立地代表氢原子、烷基基团等；R7代表氢原子或甲基基团；R8和R9分别独立地代表氢原子或烷基基团；Y代表氮原子或由以下式（1-1）所代表的基团：A1代表在链中至少具有一种从—O—，—OCO—，—COO—，—NHCO—，—CONH—，—NHCONH—和芳基基团中选择的基团的亚烷基基团等；A2代表—NH—或—O—；An−代表含有具有电子吸引取代基的芳基团的阴离子等；n表示0至3的整数；R8和R9可以与结合其的—N—（CH2）n—Y—共同形成5至6元环的环状结构。）
• POLYMERIZABLE DENTAL COMPOSITION BASED ON CONDENSED SILANES
  申请人：VOCO GmbH

  公开号：US20210052469A1

  公开（公告）日：2021-02-25

  The present invention relates to novel polymerizable dental compositions comprising, (A) polysiloxanes, wherein the polysiloxanes comprise a mixture of the condensates of the three silanes (a1), (a2) and (a3) and/or a cocondensate of a mixture of the three silanes (a1), (a2) and (a3) and/or a mixture of at least two of the cocondensates (a1)/(a2), (a1)/(a3) and (a2)/(a3) and/or a mixture of the condensate of one of the three silanes (a1), (a2) or (a3) with the cocondensate of the other two silanes, (B) fillers and (C) initiators and/or catalysts and/or activators for the polymerization.

  本发明涉及一种新型可聚合的牙科组合物，包括（A）聚硅氧烷，其中聚硅氧烷包括三种硅烷（a1）、（a2）和（a3）的缩聚物混合物和/或三种硅烷（a1）、（a2）和（a3）的混合物的共缩聚物和/或至少两种共缩聚物（a1）/（a2）、（a1）/（a3）和（a2）/（a3）的混合物以及三种硅烷（a1）、（a2）或（a3）的缩聚物与其他两种硅烷的共缩聚物的混合物，（B）填料和（C）聚合的引发剂和/或催化剂和/或活性剂。
• GRADIENT OPTICAL POLYMER NANOCOMPOSITES
  申请人：State of Oregon acting by and through the State Board of Higher Education on behalf of the Univers

  公开号：US20150023643A1

  公开（公告）日：2015-01-22

  Gradient index optical materials are formed by drop by drop dispensing of nanoparticle/monomer suspensions. Refractive index variations are defined by nanoparticle concentrations that can vary in three dimensions. Droplets of differing compositions can be mixed, and droplets or layers or droplets are partially cross-linked by exposure to ultraviolet radiation prior to dispensing additional droplets. Gradient index optical elements such as lenses, prisms, and waveguides can be formed in flexible polymer layers.

  渐变折射率光学材料是通过滴滴分配纳米颗粒/单体悬浮液形成的。折射率变化由纳米颗粒浓度在三个维度上变化定义。不同成分的液滴可以混合，液滴或液滴层可以在分配额外液滴之前通过紫外线辐射部分交联。可以在柔性聚合物层中形成渐变折射率光学元件，如透镜、棱镜和波导。
• ACTIVE ENERGY RAY-CURABLE RESIN COMPOSITION, MANUFACTURING METHOD FOR ACTIVE ENERGY RAY-CURABLE RESIN COMPOSITION, COATING MATERIAL, COATING FILM, AND FILM
  申请人：DIC Corporation

  公开号：US20150361293A1

  公开（公告）日：2015-12-17

  Provided are a coating with good blocking resistance, transparency, and scratch resistance, a laminated film including such a coating, an active-energy-radiation-curable resin composition, and a method for manufacturing such a resin composition. The laminated film includes a coating layer and a plastic film layer. The coating layer is made of a resin composition containing, as essential components, fine inorganic particles (A) and a resin component (b) in a mass ratio [(A)/(b)] of 30/70 to 60/40. The coating has an arithmetic mean roughness (Ra) of 1 to 30 nm and a haze of 1.4 or less for a thickness of 100 μm or less.

  提供了一种具有良好阻塞抗性、透明性和耐刮擦性的涂层、包括这样一种涂层的层压膜、一种活性能量辐射固化树脂组合物以及一种制造这样的树脂组合物的方法。层压膜包括涂层层和塑料膜层。涂层层由含有精细无机颗粒(A)和树脂成分(b)的树脂组合物制成，其中(A)/(b)的质量比为30/70至60/40。对于100μm或更薄的厚度，涂层的算术平均粗糙度(Ra)为1至30nm，混浊度为1.4或更低。
• MEDICAL PRESSURE-SENSITIVE ADHESIVE TAPE
  申请人：Nichiban Company Limited

  公开号：EP1060719A1

  公开（公告）日：2000-12-20

  A medical pressure sensitive adhesive tape includes a base material and a pressure sensitive adhesive layer formed on at least one side of the base material. The medical pressure sensitive adhesive tape is greatly lightened in skin irritation and has the following characteristics: (a) the stress at 5% elongation being within a range of 0.1 to 8.0 N/24 mm as measured at a temperature of 23°C and an extension rate of 100 mm/min; (b) the viscosity (unit: Pa·s) of a pressure sensitive adhesive being within a range of 5.0 to 6.7 in terms of logarithm as determined from an initial slippage under shear load; and (c) the water-vapor transmission rate being within a range of 800 to 8,000 g/m2·24 hr as measured at a temperature of 40°C and a relative humidity of 90%.

  一种医用压敏胶带包括基材和形成于基材至少一面的压敏胶层。医用压敏胶带对皮肤的刺激性大大降低，并具有以下特点： (a) 在温度为 23°C 和延伸率为 100 毫米/分钟的条件下测量，5% 延伸率时的应力在 0.1 至 8.0 牛顿/24 毫米的范围内； (b) 压敏粘合剂的粘度（单位：帕-秒）在 5.0 至 6.7 的对数范围内（根据剪切负荷下的初始滑动测定）；以及 (c) 在温度为 40℃、相对湿度为 90%的条件下测得的水蒸气透过率为 800 至 8 000 克/平方米-24 小时。