2,6-Dimethyl-3,5-dihydro-benzo<1,2-d:4,5-d'>diimidazol | 17377-07-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: 2,6-Dimethyl-3,5-dihydro-benzo<1,2-d:4,5-d'>diimidazol
• 英文别名: 2,6-Dimethyl-benzo<1,2-d:4,5-d'>diimidazol；2,6-dimethylbenzo[1,2-d:4,5-d']diimidazole；2,6-dimethyl-1,5-dihydro-benzo[1,2-d;4,5-d']diimidazole；1,2,4,5-bis(methylimidazo)benzene；2,6-Dimethylbenzo[1,2-d:4,5-d']bisimidazole；2,6-dimethyl-3,5-dihydroimidazo[4,5-f]benzimidazole
• CAS: 17377-07-0
• 化学式: C₁₀H₁₀N₄
• 分子量: 186.216
• InChiKey: NWMVVTVYNHVTQJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  57.4
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,6-Dimethyl-3,5-dihydro-benzo<1,2-d:4,5-d'>diimidazol 在 盐酸 、 水 、 氯 作用下， 生成 4,8-dichloro-2,6-dimethyl-1,5-dihydro-benzo[1,2-d;4,5-d']diimidazole; dihydrochloride
  参考文献：
  名称：

  Efros, Zhurnal Obshchei Khimii, 1952, vol. 22, p. 1015,1018,1022;engl.Ausg.S.1069,1070,1073,1074

  摘要：

  DOI：
• 作为产物：
  描述：

  N-(3-乙酰氨基苯基)乙酰胺 在 盐酸 、 硝酸 、 tin(ll) chloride 作用下， 生成 2,6-Dimethyl-3,5-dihydro-benzo<1,2-d:4,5-d'>diimidazol
  参考文献：
  名称：

  Nietzki; Hagenbach, Chemische Berichte, 1887, vol. 20, p. 334

  摘要：

  DOI：

文献信息

• Benzimidazole, Benzoxazole and Benzothiazole Derivatives, Optical Film Comprising them and Method of Producing thereof
  申请人：Nokel Alexey

  公开号：US20100279122A1

  公开（公告）日：2010-11-04

  The present invention is relates to the synthesis of predominantly planar heterocyclic organic compound and the manufacture of optical films based on these compounds. Said organic compound has the general structural formula where Het is a predominantly planar heterocyclic molecular system possessing hydrophilic properties; B is a binding group; p is the number in the range from 3 to 8; S is a group providing solubility of the organic compound; m is a number in the range from 0 to 8. Said organic compound is transparent for electromagnetic radiation in the visible spectral range from 400 to 700 nm, and a solution of the compound or a salt thereof is capable of forming a substantially transparent optical layer on a substrate, with the heterocyclic molecular planes oriented predominantly parallel to the substrate surface.

  本发明涉及主要呈平面状的杂环有机化合物的合成以及基于这些化合物的光学薄膜的制造。所述有机化合物具有通用结构公式，其中Het是一个主要呈平面状的具有亲水性质的杂环分子体系；B是一个结合基团；p是一个3到8之间的数；S是一个提供有机化合物溶解度的基团；m是一个0到8之间的数。所述有机化合物对可见光谱范围内400到700纳米的电磁辐射是透明的，并且该化合物或其盐的溶液能够在基底上形成基本透明的光学层，其中杂环分子平面主要平行于基底表面。
• Zinc(II) Coordination Frameworks Based on Benzobisimidazole: The Role of the Methyl Substituent
  作者：Hana Bunzen、Farah Mahmood、Maciej Grzywa、Dirk Volkmer

  DOI：10.1002/ejic.201701015

  日期：2017.12.8

  We report on three Zn(II) coordination frameworks based on benzobisimidazole which were prepared utilizing organic ligands containing methyl groups in the 2-position of the imidazole rings. The molecular structure of the prepared coordination frameworks was revealed by single crystal X-ray structure analysis. The influence of the methyl group on the crystal packing motifs of the materials was investigated

  我们报告了三种基于苯并双咪唑的 Zn(II) 配位骨架，这些骨架是利用在咪唑环的 2 位含有甲基的有机配体制备的。通过单晶X射线结构分析揭示了制备的配位骨架的分子结构。研究了甲基对材料晶体堆积基序的影响，并与在咪唑环的 2-位不含甲基的结构相关化合物（在相同或非常相似的反应条件下制备）进行比较。此外，还报告了通过变温 XRPD 和热重分析研究的制备的配位框架的热稳定性及其光致发光性能。
• COMPOSITES COMPRISING RIGID-ROD POLYMERS AND GRAPHENE NANOPARTICLES AND PROCESS FOR MAKING THE SAME
  申请人：DANG Thuy D.

  公开号：US20150218730A1

  公开（公告）日：2015-08-06

  The present invention relates to composites comprising rigid-rod polymers and graphene nanoparticles, processes for the preparation thereof, nanocomposite films and fibers comprising such composites and articles containing such nanocomposite films and fibers.

  本发明涉及由刚性杆聚合物和石墨烯纳米颗粒组成的复合材料，其制备过程，包含此类复合材料的纳米复合膜和纤维以及包含此类纳米复合膜和纤维的物品。
• A CRYSTALLINE, TWO DIMENSIONAL POLYMERS AND A PROCESS FOR THE PREPARATION THEREOF
  申请人：COUNCIL OF SCIENTIFIC AND INDUSTRIAL RESEARCH

  公开号：US20220185963A1

  公开（公告）日：2022-06-16

  The present invention relates to a crystalline, two dimensional polymer of Formula I and a process for the preparation thereof.

  本发明涉及一种公式I的晶体二维聚合物及其制备方法。
• Thin-film materials, thin films and producing method thereof
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP2003123A2

  公开（公告）日：2008-12-17

  An N-substituted benzimidazole-containing bridged alicyclic compound is provided. The compound is represented by following Formula (1-1): In the formula, Z3 represents a bridged alicyclic skeleton; Y11 represents a single bond or a divalent organic group; Y2 represents a single bond or a di- or tri-valent organic group; X3 represents a hydrogen atom or a reactive functional group; Ra represents a hydrogen atom or a hydrocarbon group; A3 represents a group represented by one of following Formulae (a) and (b) : wherein R10 represents a monovalent organic group, wherein, in each of Formulae (a) and (b), the left side is to be bonded to Y11, and the right side is to be bonded to Y2; "n4" denotes an integer of 2 to 7; "m3" denotes an integer of 0 to 5; and "k2" denotes an integer of 0 to 2, wherein the total of "n4" and "m3" equals 2 to 7, and wherein two or more Y11s, Y2s, X3s, A3s, and R10s per molecule, and two or more X3s and Ras, if present per molecule, may be the same as or different from one another, respectively.

  本发明提供了一种含 N-取代苯并咪唑桥联脂环族化合物。该化合物由下式（1-1）表示： 式中，Z3 代表桥式脂环族骨架；Y11 代表单键或二价有机基团；Y2 代表单键或二价或三价有机基团；X3 代表氢原子或活性官能团；Ra 代表氢原子或烃基团；A3 代表下式（a）和（b）之一所代表的基团： 其中 R10 代表一价有机基团，在式(a)和(b)中，左边与 Y11 键合，右边与 Y2 键合；"n4 "表示 2 至 7 的整数；"m3 "表示 0 至 5 的整数；k2 "表示 0 至 2 的整数，其中 "n4 "和 "m3 "的总和等于 2 至 7，每个分子中的两个或多个 Y11、Y2、X3、A3 和 R10，以及每个分子中的两个或多个 X3 和 Ras（如果存在）可分别彼此相同或不同。