quinolino[6,5-f]quinoline | 218-14-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: quinolino[6,5-f]quinoline
• 英文别名: 1,7-Diazachrysen；quino[6,5-f]quinoline；Chino[6,5-f]chinolin；Quino[6,5-f]quinoline
• CAS: 218-14-4
• 化学式: C₁₆H₁₀N₂
• 分子量: 230.269
• InChiKey: QEVBPWGFJKJQHA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  8-硝基苯并[f]喹啉 在 乙醇 、 硫酸 、 砷酸、原砷酸 、 镍 作用下， 生成 quinolino[6,5-f]quinoline
  参考文献：
  名称：

  CLEAVAGE STUDIES ON PHTHALIDEISOQUINOLINES

  摘要：

  DOI：

  10.1021/jo01369a028

文献信息

• PHOTOELECTRIC CONVERSION ELEMENT, AND SOLAR CELL USING THE SAME
  申请人：FUJIFILM Corporation

  公开号：US20180102222A1

  公开（公告）日：2018-04-12

  Provided is a photoelectric conversion element including: a first electrode that includes a photosensitive layer containing a light absorbing agent on a conductive support; and a second electrode that is opposite to the first electrode. The light absorbing agent includes a compound having a perovskite-type crystal structure that includes a cation of an element of Group 1 in the periodic table or a cationic organic group A, a cation of a metal atom M other than the element of Group 1 in the periodic table, and an anion of an anionic atom or atomic group X. A hole transport layer, which includes a hole transporting material, is provided between the first electrode and the second electrode. The hole transporting material includes a compound represented by any one of the following Formulae (1) to (4).

  提供的是一种光电转换元件，包括：第一电极，包括在导电支撑上含有吸光剂的光敏层；和与第一电极相对的第二电极。吸光剂包括具有钙钛矿型晶体结构的化合物，其中该结构包括周期表中第1族元素的阳离子或阳离子有机基A，除了周期表中第1族元素之外的金属原子M的阳离子，以及阴离子或阴性原子团X的阴离子。第一电极和第二电极之间设置有包括传输孔的传输层。传输孔材料包括由以下任一式（1）至（4）表示的化合物。
• Homologisierung der Fischer‐Indol‐Synthese: Chinoline via Homo‐Diaza‐Cope‐Umlagerung
  作者：Gabriela Guillermina Gerosa、Sebastian Armin Schwengers、Rajat Maji、Chandra Kanta De、Benjamin List

  DOI：10.1002/ange.202005798

  日期：2020.11.9

  AbstractWir beschreiben eine neuartige Strategie zur Synthese von Chinolinen basierend auf einer Brønsted‐Säure‐induzierten Homo‐Diaza‐Cope‐Umlagerung von N‐Aryl‐N′‐Cyclopropylhydrazinen. Unsere Strategie kann als Homologisierung der klassischen Fischer‐Indol‐Synthese verstanden werden und ermöglicht die Bildung sechsgliedriger N‐Heterocyclen inklusive weiterer, vorher nicht zugänglicher Pyridinderivate

  摘要我们描述了一种基于布朗斯台德酸诱导的同二氮杂-Cope 重排的喹啉合成新策略氮‐芳基‐N′‐环丙基肼。我们的策略可以理解为经典费歇尔吲哚合成的同系物，并且能够形成六元N-杂环，包括额外的、以前无法获得的吡啶衍生物。此外，该方法可用作制备多环多杂芳烃的吡啶环化策略。理论计算用于了解合理的活化模式和催化剂的影响。
• ORGANIC ELECTROLUMINESCENT ELEMENT MATERIAL HAVING SILICON-CONTAINING FOUR MEMBERED RING STRUCTURE, AND ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Nippon Steel & Sumikin Chemical Co., Ltd.

  公开号：EP2762483A1

  公开（公告）日：2014-08-06

  Provided are a material for an organic electroluminescent element formed of a silicon-containing four-membered ring compound, and an organic electroluminescent element using the material. The material for an organic electroluminescent element is formed of a compound represented by the following formula (1) and is used for, for example,a light-emitting layer containing a phosphorescent light-emitting dopant in an organic electroluminescent element. In the formula, X represents nitrogen or phosphorus, L's each represent an (n+1)-valent aromatic hydrocarbon group or aromatic heterocyclic group, and at least one of the L's represents an aromatic heterocyclic group. A1 to A6 each represent an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aromatic hydrocarbon group, an aromatic heterocyclic group, or an amino group, and n represents an integer of 0 to 3.

  提供了一种用含硅四元环化合物制备有机电致发光元件的材料，以及使用该材料的有机电致发光元件。该有机电致发光元件的材料由以下式子（1）所表示的化合物组成，例如用于含有荧光杂质的发光层的有机电致发光元件。在该式中，X代表氮或磷，L分别代表（n+1）价芳香族烃基或芳香族杂环基，至少一个L代表芳香族杂环基。A1至A6分别代表烷基、环烷基、烯基、炔基、芳香族烃基、芳香族杂环基或氨基，n代表0至3的整数。
• Organic-electroluminescent-element material and organic electroluminescent element using same
  申请人：NIPPON STEEL & SUMIKIN CHEMICAL CO., LTD.

  公开号：US10446767B2

  公开（公告）日：2019-10-15

  Disclosed is an organic electroluminescent device (organic EL device) that is improved in luminous efficiency, sufficiently secures driving stability, and has a simple construction. The device is an organic electroluminescent device having organic layers including a light-emitting layer between an anode and a cathode laminated on a substrate, in which a carborane compound is incorporated into at least one layer of the organic layers, or is incorporated as a host material into a light-emitting layer containing a phosphorescent light-emitting dopant and the host material. The carborane compound has a structure in which a N-containing fused aromatic ring is bonded to a carborane ring. The N-containing fused aromatic ring is a quinoline ring or has a structure obtained by substituting 1 to 3 ring-forming carbon atoms in a quinoline ring with N atoms.

  本发明公开了一种有机电致发光器件（有机EL器件），其具有提高的发光效率、足够的驱动稳定性和简单的结构。该器件是一种有机电致发光器件，包括在基板上层叠的阳极和阴极之间的有机层，其中至少一个有机层中掺入了碳硼烷化合物，或者将碳硼烷化合物作为宿主材料掺入含有磷光致发光剂和宿主材料的发光层中。碳硼烷化合物具有将含N的融合芳香环连接到碳硼烷环的结构。含N的融合芳香环是喹啉环或通过将喹啉环中1至3个环形碳原子替换为N原子获得的结构。
• Material for organic electroluminescent elements, and organic electroluminescent element using same
  申请人：NIPPON STEEL & SUMIKIN CHEMICAL CO., LTD.

  公开号：US10283721B2

  公开（公告）日：2019-05-07

  Disclosed are an organic electroluminescent device (organic EL device) having improved luminous efficiency, sufficiently secured driving stability, and a simple construction, and a material for an organic EL device. The material for an organic EL device includes a carborane compound having a structure in which at least one carborane ring and at least one dibenzothiophene ring are present, and the at least one carborane ring is bonded to the at least one dibenzothiophene ring at position 1, 2, or 3. In addition, the organic EL device includes, between an anode and a cathode laminated on a substrate, at least one organic layer, in which the at least one organic layer includes the carborane compound.

  揭示了一种具有改善发光效率、充分保证驱动稳定性和简单结构的有机电致发光器件（有机EL器件），以及有机EL器件的材料。用于有机EL器件的材料包括一种碳硼烷化合物，其结构中至少存在一个碳硼烷环和至少一个二苯并噻吩环，且至少一个碳硼烷环与至少一个二苯并噻吩环在1、2或3位置上结合。此外，有机EL器件在衬底上层叠的阳极和阴极之间包括至少一个有机层，其中至少一个有机层包括碳硼烷化合物。