1-Vinyl-cyclohexane-1,2-diol | 674309-71-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-Vinyl-cyclohexane-1,2-diol
• 英文别名: 1-Ethenylcyclohexane-1,2-diol
• CAS: 674309-71-8
• 化学式: C₈H₁₄O₂
• 分子量: 142.198
• InChiKey: KISOOWMWOZIFDK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-Vinyl-cyclohexane-1,2-diol 在 lead(IV) acetate 作用下， 以 乙腈 为溶剂， 以94%的产率得到6-oxooct-7-enal
  参考文献：
  名称：

  分子内Baylis-Hillman反应：轻松制备通用底物，简便的反应和合成应用。

  摘要：

  我们已经开发了一种通用的高效方法，用于制备各种不同的小ω-甲酰基-小α，β-不饱和羰基化合物，并优化了这些化合物的分子内Baylis-Hillman反应的条件，以提供各种生物学上重要的多环化合物。

  DOI：

  10.1039/b311951c
• 作为产物：
  描述：

  乙烯基溴化镁 、 2-acetoxycyclohexanone 以 四氢呋喃 为溶剂， 反应 2.0h， 以61%的产率得到1-Vinyl-cyclohexane-1,2-diol
  参考文献：
  名称：

  Diels-Alder范式的抗衡离子定向方法：三环熔融环丙烷的级联合成。

  摘要：

  分子内Diels-Alder反应的方法已导致由三个稠合环和多达五个立体中心组成的复杂碳环的级联合成，并具有完全的立体控制。计算分析表明，该反应是通过迈克尔/迈克尔/环丙烷化/表观化级联反应进行的，其中抗衡离子的大小和配位是关键。

  DOI：

  10.1002/anie.201608534

文献信息

• Process to produce 4-(2-sulfoethyl) cyclohexane, 1,2-diol from 4-vinylcyclohexane-1,2-diol
  申请人：——

  公开号：US20040192971A1

  公开（公告）日：2004-09-30

  Disclosed herein is a process for preparing 4-(2-sulfoethylcyclohexane)-1,2 diol, at ambient condition and in the presence of a buffer and an initiator, from vinylcyclohexane-1,2-diol

  本文披露了一种在常温条件下，在缓冲剂和引发剂的存在下，从环己烯基环己烷-1,2-二醇制备4-(2-磺酸乙基环己烷)-1,2-二醇的方法。
• Methods For Preparing Fluoroalkyl Arylsulfinyl Compounds And Fluorinated Compounds Thereto
  申请人：Umemoto Teruo

  公开号：US20110190511A1

  公开（公告）日：2011-08-04

  Novel preparative methods for fluoroalkyl arylsulfinyl compounds are disclosed. Fluorinated compounds as useful fluorinated compounds, intermediates, or builing blocks are disclosed. Useful applications of the fluoroalkyl arylsulfinyl compounds are shown.

  本发明揭示了一种用于制备氟烷基芳基亚磺酰化合物的新型制备方法。本发明还揭示了氟化合物作为有用的氟化合物、中间体或构建块。同时，本发明还展示了氟烷基芳基亚磺酰化合物的有用应用。
• Methods for Preparing Fluoroalkyl Arylsulfinyl Compounds and Fluorinated Compounds Thereto
  申请人：Umemoto Teruo

  公开号：US20100152463A1

  公开（公告）日：2010-06-17

  Novel preparative methods for fluoroalkyl arylsulfinyl compounds are disclosed. Fluorinated compounds as useful fluorinated compounds, intermediates, or building blocks are disclosed. Useful applications of the fluoroalkyl arylsulfinyl compounds are shown.

  本发明公开了用于制备氟烷基芳基磺酰基化合物的新型制备方法。本发明还公开了作为有用的氟化合物、中间体或构建块的氟化合物。本发明还展示了氟烷基芳基磺酰基化合物的有用应用。
• Compositions, expoxidized compositions, a heat-curable resin composition, an epoxy resin composition, radically polymerized composition, a curable resin composition and a polymer having epoxy groups
  申请人：DAICEL CHEMICAL INDUSTRIES, LTD.

  公开号：EP0540027A2

  公开（公告）日：1993-05-05

  Compositions(I), (II) and (III) comprising compounds having vinyl groups as side chains and epoxidized compositions(XI), (XII) and (XIII) thereof, which can be prepared by the various reaction combinations of (a) with (b) or (b)+(c), and or (d), are disclosed. (a) is at least one compound having at least one vinyl group and one epoxy group in the molecule; (b) is at least one of a polybasic compound, an anhydride thereof, a polymer having carboxylic groups at terminals and a polymer having carboxylic groups as side chains; (c) is at least one organic compound having at least one active hydrogen atom; and (d) is at least one of an unsaturated monocarboxylic compound or an unsaturated monocarboxylic ester having a hydroxyl group. Heat curable compositions and epoxy resin compositions can be made which comprise the above-mentioned compositions and a radical initiator or a curing agent, a polymer composition obtained by radically (co)polymerizing the compositions(III) or the epoxidized compositions(XIII) thereof. The epoxidized compositions(XI) and (XII) can provide a coating layer or a formed article having excellent properties such as heat resistance, outdoor durability and further electric properties.

  本发明公开了由具有乙烯基作为侧链的化合物组成的组合物(I)、(II)和(III)及其环氧化组合物(XI)、(XII)和(XIII)，这些组合物可以通过(a)与(b)或(b)+(c)和或(d)的各种反应组合来制备。 (a)是分子中至少具有一个乙烯基和一个环氧基的至少一种化合物；(b)是多基性化合物、其酸酐、末端具有羧基的聚合物和侧链具有羧基的聚合物中的至少一种；(c)是具有至少一个活泼氢原子的至少一种有机化合物；(d)是具有羟基的不饱和单羧基化合物或不饱和单羧基酯中的至少一种。 热固化组合物和环氧树脂组合物由上述组合物、自由基引发剂或固化剂、通过自由基（共）聚合组合物（III）或环氧化组合物（XIII）得到的聚合物组合物组成。 环氧化组合物(XI)和(XII)可以提供具有优异性能（如耐热性、室外耐久性和进一步的电性能）的涂层或成型制品。
• Epoxidised compositions
  申请人：DAICEL CHEMICAL INDUSTRIES, LTD.

  公开号：EP0859021A2

  公开（公告）日：1998-08-19

  Compositions(I), (II) and (III) comprising compounds having vinyl groups as side chains and epoxidized compositions(XI), (XII) and (XIII) thereof, which can be prepared by the various reaction combinations of (a) with (b) or (b)+(c), are disclosed. (a) is at least one compound having at least one vinyl group and one epoxy group in the molecule; (b) is at least one of a polybasic compound, an anhydride thereof, a polymer having carboxylic groups at terminals and a polymer having carboxylic groups as side chains; (c) is at least one organic compound having at least one active hydrogen atom. Heat curable compositions and epoxy resin compositions can be made which comprise the above-mentioned compositions and a radical initiator or a curing agent, a polymer composition obtained by radically (co)polymerizing the compositions(III) or the epoxidized compositions(XIII) thereof. The epoxidized compositions(XI) and (XII) can provide a coating layer or a formed article having excellent properties such as heat resistance, outdoor durability and further electric properties.

  本发明公开了由具有乙烯基作为侧链的化合物组成的组合物(I)、(II)和(III)及其环氧化组合物(XI)、(XII)和(XIII)，这些组合物可以通过(a)与(b)或(b)+(c)的各种反应组合制备。 (a)是分子中至少具有一个乙烯基和一个环氧基的化合物；(b)是多碱性化合物、其酸酐、末端具有羧基的聚合物和侧链具有羧基的聚合物中的至少一种；(c)是至少具有一个活泼氢原子的有机化合物。 热固化组合物和环氧树脂组合物可以由上述组合物和自由基引发剂或固化剂、通过自由基（共）聚合组合物（III）或环氧化组合物（XIII）得到的聚合物组合物组成。 环氧化组合物(XI)和(XII)可以提供具有优异性能（如耐热性、室外耐久性和进一步的电性能）的涂层或成型制品。