4-[4,7-diphenyl-9-[4-(N-phenylanilino)phenyl]-1,10-phenanthrolin-2-yl]-N,N-diphenylaniline | 1123553-91-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 4-[4,7-diphenyl-9-[4-(N-phenylanilino)phenyl]-1,10-phenanthrolin-2-yl]-N,N-diphenylaniline
• CAS: 1123553-91-2
• 化学式: C₆₀H₄₂N₄
• 分子量: 819.02
• InChiKey: XRACBPVADFLCHA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.5
• 重原子数：
  64
• 可旋转键数：
  10
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  32.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  4,7-二苯基-1,10-菲罗啉 在 tris-(dibenzylideneacetone)dipalladium(0) 、 三环己基膦 potassium phosphate 、 五氯化磷 、 水 、 氧气 、 sodium hydroxide 、 potassium hexacyanoferrate(III) 、 三氯氧磷 作用下， 以 1,4-二氧六环 、 水 为溶剂， 反应 10.5h， 生成 4-[4,7-diphenyl-9-[4-(N-phenylanilino)phenyl]-1,10-phenanthrolin-2-yl]-N,N-diphenylaniline
  参考文献：
  名称：

  ELECTRONIC DEVICE INCLUDING PHENANTHROLINE DERIVATIVE

  摘要：

  提供一种有阳极、空穴注入层、光活性层、电子传输层和阴极的有机电子器件。光活性层和/或电子传输层中至少包括具有以下式I的化合物，其中：R1相同或不同，可以是苯基、联苯基、萘基、萘基苯基、三苯胺基或咔唑基苯基；并满足以下条件之一：（i）R2=R3且为H、苯基、联苯基、萘基、萘基苯基、芳基蒽基、苯并芘基、三苯胺基或咔唑基苯基；或（ii）R2为H或苯基；且R3为苯基、联苯基、萘基、萘基苯基、芳基蒽基、苯并芘基、三苯胺基和咔唑基苯基；当R1均为苯基时，R2和R3可以是2-萘基、萘基苯基、芳基蒽基、9-苯并芘基、三苯胺基或m-咔唑基苯基。

  公开号：

  US20120065402A1

文献信息

• PHOTOACTIVE COMPOSITION AND ELECTRONIC DEVICE MADE WITH THE COMPOSITION
  申请人：Gao Weiying

  公开号：US20130126852A1

  公开（公告）日：2013-05-23

  There is provided a photoactive composition including: (a) 50-99 wt % based on the total weight of the photoactive composition, of at least one host material having a HOMO energy level; (b) 1-10 wt % based on the total weight of the photoactive composition, of an emissive dopant; and (c) 0.1 to 10 wt % based on the total weight of the photoactive composition, of a non-emissive dopant. The non-emissive dopant is an organometallic iridium complex that has a HOMO energy level shallower than the HOMO energy level of the host.

  提供一种光致活性组合物，包括：(a)基于光致活性组合物的总重量，50-99重量％的至少一种具有HOMO能级的主体材料；(b)基于光致活性组合物的总重量，1-10重量％的发射掺杂剂；(c)基于光致活性组合物的总重量，0.1-10重量％的非发射掺杂剂。非发射掺杂剂是一种具有比主体HOMO能级更浅的有机金属铱配合物。
• ELECTROACTIVE COMPOSITION AND ELECTRONIC DEVICE MADE WITH THE COMPOSITION
  申请人：Howard, JR. Michael Henry

  公开号：US20110147718A1

  公开（公告）日：2011-06-23

  There is provided an electroactive composition including: a deuterated first host material and an electroluminescent dopant material. The first host is a compound having Formula I: The compound of Formula I is deuterated. In Formula I: Ar 1 to Ar 4 are the same or different and are aryl; Q is a multivalent aryl group or where T is (CR′) a , SiR 2 , S, SO 2 , PR, PO, PO 2 , BR, or R; R is the same or different at each occurrence and is an alkyl group or an ary group; R′ is the same or different at each occurrence and is selected H, D, or alkyl; a is an integer from 1-6; and m is an integer from 0-6.
• ORGANIC LIGHT-EMITTING DIODE LUMINAIRES
  申请人：Dobbs Kerwin D.

  公开号：US20110204335A1

  公开（公告）日：2011-08-25

  There is provided an organic light-emitting diode luminaire. The luminaire includes a patterned first electrode, a second electrode, and a light-emitting layer therebetween. The light-emitting layer includes a first plurality of pixels having an emission color that is blue-green and a second plurality of pixels having an emission color that is red/red-orange, the second plurality of pixels being laterally spaced from the first plurality of pixels. The additive mixing of the emitted colors results in an overall emission of white light.
• US8309731B2
  申请人：——

  公开号：US8309731B2

  公开（公告）日：2012-11-13
• US8436341B2
  申请人：——

  公开号：US8436341B2

  公开（公告）日：2013-05-07