4-(p-tolyl)-1H-1,2,3-triazol-5-amine | 205942-76-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 4-(p-tolyl)-1H-1,2,3-triazol-5-amine
• 英文别名: 5-(4-methylphenyl)-2H-triazol-4-amine
• CAS: 205942-76-3
• 化学式: C₉H₁₀N₄
• 分子量: 174.205
• InChiKey: RQRKEEGUOVZQRL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  67.6
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-(p-tolyl)-1H-1,2,3-triazol-5-amine 在 盐酸 、 sodium azide 、 sodium nitrite 作用下， 生成 5-Azido-4-p-tolyl-1H-[1,2,3]triazole
  参考文献：
  名称：

  Rearrangement of substituted azido-1,2,3-triazolides to (α-diazoalkyl)tetrazolides

  摘要：

  标题过程的范围已被研究，显示具有R = H、（取代的）Ph和CO2Me的阴离子4′反应清晰（在R = Me的情况下仍然令人满意），而当R = COMe、COAr和CN时，出现了广泛的分解。实验结果（速率常数、活化参数）通过PM3计算得以阐明。

  DOI：

  10.1039/a708872h
• 作为产物：
  描述：

  对甲基苯乙腈 在 potassium tert-butylate 、 氨 、 sodium 、 氯化铵 作用下， 以 四氢呋喃 为溶剂， 生成 4-(p-tolyl)-1H-1,2,3-triazol-5-amine
  参考文献：
  名称：

  Rearrangement of substituted azido-1,2,3-triazolides to (α-diazoalkyl)tetrazolides

  摘要：

  标题过程的范围已被研究，显示具有R = H、（取代的）Ph和CO2Me的阴离子4′反应清晰（在R = Me的情况下仍然令人满意），而当R = COMe、COAr和CN时，出现了广泛的分解。实验结果（速率常数、活化参数）通过PM3计算得以阐明。

  DOI：

  10.1039/a708872h

文献信息

• Compositions for inhibition of corrosion in fuel systems, and methods for use
  申请人：PETROLITE CORPORATION

  公开号：EP0330416A1

  公开（公告）日：1989-08-30

  A composition adapted for use as a corrosion inhibitor in petroleum-based fuel. The composition com­prises an oil-soluble adduct of a triazole and a basic nitrogen compound selected from the group consisting of polyamines, alkoxyamines, aryloxyamines and monoalkyl­eneamines. Methods for preparation and use of such com­positions are also disclosed. In addition, a petroleum-­based fuel composition of reduced tendency to corrode copper and aluminum surfaces contacted by the fuel compo­sition is disclosed. The composition comprises a petro­leum-based fuel and an oil-soluble adduct of a triazole and a basic nitrogen compound.

  一种可用作石油基燃料缓蚀剂的组合物。该组合物包含一种三唑与碱性氮化合物的油溶性加合物，该碱性氮化合物选自多胺、烷氧基胺、芳氧基胺和单亚烷基胺组成的组。还公开了制备和使用这种组合物的方法。此外，还公开了一种石油基燃料组合物，该组合物降低了腐蚀与燃料组合物接触的铜和铝表面的倾向。该组合物包括一种石油基燃料和一种三唑与碱性氮化合物的油溶性加合物。
• Lubricant with improved anticorrosion properties
  申请人：The Lubrizol Corporation

  公开号：EP0578490A1

  公开（公告）日：1994-01-12

  An additive composition of (a) a substituted aromatic triazole and (b) a hydrocarbyl substituted succinic acylated polyamine dispersant, reacted with a boron compound, imparts improved corrosion resistance to lubricating oils which contain a multifunctional olefin copolymer viscosity index modifier.

  一种由(a)取代的芳香族三唑和(b)烃基取代的琥珀酰化聚胺分散剂与硼化合物反应而成的添加剂组合物，可提高含有多功能烯烃共聚物粘度指数调节剂的润滑油的抗腐蚀性。
• Reaction solution for ink jet recording and ink jet recording method using the same
  申请人：SEIKO EPSON CORPORATION

  公开号：EP0959112A1

  公开（公告）日：1999-11-24

  Disclosed is a reaction solution for an ink jet recording method wherein droplets of an ink composition and droplets of a reaction solution, which produces an agglomerate upon contact with the ink composition, are ejected and deposited onto a recording medium to perform printing. The reaction solution can realize goad print quality and possesses excellent storage stability and ejection stability. Specifically, it has been found that use of a reaction solution comprising at least a polyvalent metal salt, ammonia, and benzotriazole or a benzotriazole derivative in an ink jet recording method, wherein two liquids are printed, can realized good print quality and that the reaction solution possesses excellent storage stability and ejection stability. Further, it has been found that this reaction solution does not attack a nozzle plate having thereon a eutectoid plating and enables stable printing for a long period of time. Thus, the reaction solution of the present invention comprises at least a polyvalent metal salt, ammonia, and benzotriazole or a benzotriazole derivative.

  本发明公开了一种用于喷墨记录方法的反应溶液，其中墨水组合物的液滴和反应溶液的液滴在与墨水组合物接触时产生团聚，反应溶液喷出后沉积到记录介质上进行打印。反应溶液可实现良好的印刷质量，并具有出色的储存稳定性和喷射稳定性。具体而言，研究发现，在喷墨记录方法中使用至少由多价金属盐、氨和苯并三唑或苯并三唑衍生物组成的反应溶液，其中打印两种液体，可以实现良好的打印质量，并且反应溶液具有出色的存储稳定性和弹射稳定性。此外，还发现这种反应溶液不会侵蚀喷嘴板上的共晶电镀层，并能实现长时间稳定打印。因此，本发明的反应溶液至少包括一种多价金属盐、氨和苯并三唑或苯并三唑衍生物。
• Wire harness material and wire harness comprising same
  申请人：Sumitomo Wiring Systems, Ltd.

  公开号：EP1312657A2

  公开（公告）日：2003-05-21

  A wire harness protective material comprising a tape-like substrate made of a nonhalogen-based resin or vinyl chloride resin coated with an adhesive comprising an acrylic resin as a main component on at least one side thereof. Preferably, the adhesive and/or the substrate comprises an age resistor and/or a copper inhibitor incorporated therein. The content of the age resistor is defined to be from 10% to 500% based on the content of the age resistor in the covering material for the wire coated with a nonhalogen-based resin in the bundle of wires on which the wire harness protective material is wound. The content of the copper inhibitor is defined to be from 0.001 to 5 parts by weight based on 100 parts by weight of the adhesive resin component or from 0.001 to 5 parts by weight based on 100 parts by weight of the substrate resin component.

  一种线束保护材料，包括由无卤素树脂或氯乙烯树脂制成的带状基材，基材的至少一面涂有以丙烯酸树脂为主要成分的粘合剂。粘合剂和/或基材最好含有抗老化剂和/或铜抑制剂。根据线束保护材料所缠绕的线束中涂有无卤素树脂的导线包覆材料中抗老化剂的含量，抗老化剂的含量为 10%至 500%。铜抑制剂的含量为 0.001 至 5 份（以 100 份粘合剂树脂组分的重量为基准）或 0.001 至 5 份（以 100 份基材树脂组分的重量为基准）。
• Wire-harness-protecting material and wire harness comprising said material
  申请人：Sumitomo Wiring Systems, Ltd.

  公开号：EP1329491A2

  公开（公告）日：2003-07-23

  A harness-protecting material comprises a base material which comprises two faces, at least one face of which is coated with an adhesive. The base material comprises a base organic material portion which includes a base polymer portion formed of a halogen-free resin or a substantially halogen-free resin. The adhesive comprises an adhesive adjuvant which contains at least one compound selected from the group consisting of a hydrogenated terpene-type resin, a hydrogenated aromatic resin, a hydrogenated aliphatic-type resin, a cumarone-indene type resin, a phenol-type resin and a styrene-type resin. The adhesive may contain acrylic acid-type resin as base polymer portion. The base material and/or adhesive may contain an anti-oxidizing agent, a copper damage inhibitor and/or an adsorbent.

  一种线束保护材料由基材组成，基材包括两个面，其中至少一个面涂有粘合剂。基底材料包括基底有机材料部分，其中包括由无卤素树脂或基本无卤素树脂形成的基底聚合物部分。粘合剂包括一种粘合剂佐剂，其中含有至少一种选自以下组别的化合物：氢化萜烯类树脂、氢化芳香族树脂、氢化脂肪族类树脂、积雪草烯-茚类树脂、苯酚类树脂和苯乙烯类树脂。粘合剂可以含有丙烯酸类树脂作为基础聚合物部分。基材和/或粘合剂可含有抗氧化剂、铜损伤抑制剂和/或吸附剂。