2,2-二乙氧基-1,1,1-三氟乙烷 | 31224-45-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 2,2-二乙氧基-1,1,1-三氟乙烷
• 英文名称: trifluoroacetaldehyde ethyl hemiacetal
• 英文别名: Ethane, 1,1-diethoxy-2,2,2-trifluoro-；2,2-diethoxy-1,1,1-trifluoroethane
• CAS: 31224-45-0
• 化学式: C₆H₁₁F₃O₂
• mdl: MFCD01728731
• 分子量: 172.147
• InChiKey: MZCNVEUWTDUFAP-UHFFFAOYSA-N

物化性质

• 沸点：
  122.3±35.0 °C(Predicted)
• 密度：
  1.096±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  2,2-二乙氧基-1,1,1-三氟乙烷 、 苯胺 在 对甲苯磺酸 作用下， 以 乙醇 为溶剂， 生成 N-(1-ethoxy-2,2,2-trifluoroethyl)aniline
  参考文献：
  名称：

  Identification of potent and selective VEGFR receptor tyrosine kinase inhibitors having new amide isostere headgroups

  摘要：

  A novel series of malonamide-type dual VEGFR2/c-Met inhibitors in which one of the amide bonds was replaced by an amide isostere-a trifluoroethylamine unit, was designed, synthesized, and evaluated for their enzymatic and cellular inhibition of VEGFR2 and c-Met enzymes. Optimization of these molecular entities resulted in identification of potent and selective inhibitors of VEGFR2 enzyme. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.bmcl.2009.12.099

文献信息

• NON-AQUEOUS ELECTROLYTE SOLUTION, AND NON-AQUEOUS-ELECTROLYTE SECONDARY CELL USING SAME
  申请人：Mitsubishi Chemical Corporation

  公开号：EP3252861A1

  公开（公告）日：2017-12-06

  There is provided a non-aqueous electrolyte solution enabling fabrication of a non-aqueous electrolyte solution secondary battery which achieves suppressed gas generation when used under high temperature environment and the improved residual capacity of the battery, and the improved cycle characteristic thereof, and further, is excellent in discharge load characteristic (dischargeable at high rate), and a non-aqueous electrolyte solution secondary battery using the non-aqueous electrolyte solution. There is provided a non-aqueous electrolyte solution for use in a non-aqueous electrolyte solution secondary battery including a positive electrode having a positive electrode active material capable of absorbing and releasing a metal ion and a negative electrode having a negative electrode active material capable of absorbing and releasing a metal ion, which solution contains a bismaleimide compound having a specific structure, and a non-aqueous electrolyte solution secondary battery using the solution.

  本发明提供了一种非水电解质溶液，该溶液可用于制造非水电解质溶液二次电池，在高温环境下使用时可抑制气体生成，提高电池的剩余容量，改善循环特性，而且放电负载特性优异（可高速放电），还提供了一种使用该非水电解质溶液的非水电解质溶液二次电池。提供了一种用于非水电解质溶液二次电池的非水电解质溶液，该二次电池包括正极和负极，正极具有能够吸收和释放金属离子的正极活性材料，负极具有能够吸收和释放金属离子的负极活性材料，该溶液含有具有特定结构的双马来酰亚胺化合物，还提供了一种使用该溶液的非水电解质溶液二次电池。
• Production method for halogenated alpha-fluoroethers
  申请人：Central Glass Company, Limited

  公开号：US10882809B2

  公开（公告）日：2021-01-05

  A halogenated α-fluoroether of the formula (2) (where HaloR represents haloalkyl; R1 represents hydrogen, halogen, alkyl or substituted alkyl; and R2 represents alkyl or substituted alkyl) is produced efficiently on an industrial scale by reacting a halogenated aldehyde of the formula (1) (where HaloR represents haloalkyl) or an equivalent thereof with hydrogen fluoride.

  式（2）的卤代α-氟醚（其中 HaloR 代表卤代烷基；R1 代表氢、卤素、烷基或取代烷基；R2 代表烷基或取代烷基）可通过式（1）的卤代醛（其中 HaloR 代表卤代烷基）或其等效物与氟化氢反应，在工业规模上高效生产。
• WATSON, NIGEL STEPHEN;CHAN, CHUER;ROSS, BARRY CLIVE
  作者：WATSON, NIGEL STEPHEN、CHAN, CHUER、ROSS, BARRY CLIVE

  DOI：——

  日期：——
• NONAQUEOUS ELECTROLYTIC SOLUTION AND NONAQUEOUS-ELECTROLYTE BATTERY EMPLOYING THE SAME
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：US20150024284A1

  公开（公告）日：2015-01-22

  The present invention is to provide: a nonaqueous-electrolyte battery excellent in terms of safety during overcharge and high-temperature storability; and a nonaqueous electrolytic solution which gives the battery. The present invention relates to a nonaqueous electrolytic solution comprising an electrolyte and a nonaqueous solvent, wherein the nonaqueous electrolytic solution comprises at least one of specific compounds.
• NON-AQUEOUS ELECTROLYTE SOLUTION AND NON-AQUEOUS ELECTROLYTE SOLUTION SECONDARY BATTERY USING THE SAME
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：US20170324116A1

  公开（公告）日：2017-11-09

  There is provided a non-aqueous electrolyte solution enabling fabrication of a non-aqueous electrolyte solution secondary battery which achieves suppressed gas generation when used under high temperature environment and the improved residual capacity of the battery, and the improved cycle characteristic thereof, and further, is excellent in discharge load characteristic (dischargeable at high rate), and a non-aqueous electrolyte solution secondary battery using the non-aqueous electrolyte solution. There is provided a non-aqueous electrolyte solution used in a non-aqueous electrolyte solution secondary battery including a positive electrode having a positive electrode active material capable of absorbing and releasing a metal ion and a negative electrode having a negative electrode active material capable of absorbing and releasing a metal ion, which solution contains a bismaleimide compound having a specific structure, and a non-aqueous electrolyte solution secondary battery using the solution.