trimethylolpropane diethanoate | 115392-09-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: trimethylolpropane diethanoate
• 英文别名: [2-(Acetyloxymethyl)-2-(hydroxymethyl)butyl] acetate
• CAS: 115392-09-1
• 化学式: C₁₀H₁₈O₅
• 分子量: 218.25
• InChiKey: JPWLNERHYZNKEH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  15
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  72.8
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  三羟甲基丙烷 、 溶剂黄146 在 磷酸 作用下， 以 苯 为溶剂， 生成 2,2-双(羟甲基)乙酸丁酯 、 trimethylolpropane diethanoate 、 2-乙基-2-(乙酰氧基甲基)-1,3-丙烷二醇二乙酸酯
  参考文献：
  名称：

  三羟甲基丙烷和С2 –С 5酸的酯在DB-1固定相上的气相保留和吸附焓的特征

  摘要：

  在220–280°C的温度范围内，对21种三羟甲基丙烷和一元酸的单，二和三取代酯确定了保留特性及其温度依赖性以及DB-1非极性相上吸附的热力学特性。具有2至6个碳原子的各种结构。

  DOI：

  10.1134/s0036024417020194

文献信息

• Active energy ray-curable antistatic coating composition
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：EP1302514A2

  公开（公告）日：2003-04-16

  An active energy ray-curable antistatic coating composition which comprises (A) inorganic oxide fine particles having a side chain having a molecular weight of at least 300 and having a functional group and (B) an antistatic agent containing at least one member selected from the group consisting of a quaternary ammonium salt group-containing polymer, a quaternary ammonium salt group-containing silane coupling agent and a hydrolysis condensate of the silane coupling agent, and optionally contains (C) a polyfunctional (meth)acrylate having at least 3 (meth)acryloyl groups in a molecule.

  一种主动能射线固化抗静电涂料组合物，它包括 (A) 侧链分子量至少为 300 且带有官能团的无机氧化物微粒和 (B) 抗静电剂，抗静电剂至少含有一种选自以下组别的成员：含季铵盐基团的聚合物、含季铵盐基团的硅烷偶联剂和硅烷偶联剂的水解缩合物、(C) 分子中至少有 3 个(甲基)丙烯酰基的多官能(甲基)丙烯酸酯。
• Synthesis and GC-MS study of fluorinated esters derived from thrimethylolpropane
  作者：M. G. Pervova、V. E. Kirichenko、T. I. Gorbunova、A. Ya. Zapevalov、V. I. Saloutin

  DOI：10.1134/s1070363208090107

  日期：2008.9

  Zol-gel process was used to synthesize equilibrium mixtures of mono-, di-, and trimester derived from trimethylolpropane and perfluorocarboxylic acids. The elution order of the components of the mixtures from a weakly polar HP-5 column was established. The mass spectra of the synthesized compounds were studied. The GC-MS parameters of the products were compared with the respective parameters of their nonfluorinated analogs. The characteristics of the fluorinated esters have features determined by the esterification degree and the nature of the perfluoroalkyl groups, due to which these compounds can be identified in mixtures.
• US6921576B2
  申请人：——

  公开号：US6921576B2

  公开（公告）日：2005-07-26
• Characteristics of retention and enthalpies of sorption from the gas phase of esters of trimethylolpropane and С2–С5 acids on DB-1 stationary phase
  作者：E. L. Krasnykh、A. Yu. Aleksandrov、A. A. Sokolova、S. V. Levanova

  DOI：10.1134/s0036024417020194

  日期：2017.2

  along with the thermodynamic characteristics of sorption on DB-1 nonpolar phase, are determined in the temperature range of 220–280°C for 21 mono-, di-, and trisubstituted esters of trimethylolpropane and monobasic acids with a variety of structures containing from 2 to 6 carbon atoms.

  在220–280°C的温度范围内，对21种三羟甲基丙烷和一元酸的单，二和三取代酯确定了保留特性及其温度依赖性以及DB-1非极性相上吸附的热力学特性。具有2至6个碳原子的各种结构。