non-1-en-4-yl acrylate | 1439924-53-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: non-1-en-4-yl acrylate
• 英文别名: Non-1-en-4-yl prop-2-enoate
• CAS: 1439924-53-4
• 化学式: C₁₂H₂₀O₂
• 分子量: 196.29
• InChiKey: DDPVOLOODCJFQW-UHFFFAOYSA-N

物化性质

• 沸点：
  253.3±19.0 °C(Predicted)
• 密度：
  0.889±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  14
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.58
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  non-1-en-4-yl acrylate 在 RuCl2(1,3-dimesityl-imidazolidin-2-yl)(PCy3)(=CHPh) 、 N-溴代丁二酰亚胺(NBS) 、 偶氮二异丁腈 、 三乙胺 作用下， 以 氯苯 、 甲苯 为溶剂， 反应 105.5h， 生成 6-戊基-2H-吡喃-2-酮
  参考文献：
  名称：

  2H-Pyran-2-ones from Trichoderma viride and Trichoderma asperellum

  摘要：

  土壤真菌绿色木霉 272 和木霉 328 释放的挥发物通过使用闭环汽提分析 (CLSA) 顶空技术收集，并通过 GC/MS 分析获得的提取物。几种烷基-和链烯基-2H-吡喃-2-酮，包括已知化合物 6-pentyl-2H-pyran-2-one 和 (E)-6-(pent-1-en-1-yl)-2H-pyran -2-one，以及新的衍生物 (E)-6-(pent-2-en-1-yl)-2H-pyran-2-one、6-丙基-2H-pyran-2-one 和 6-发现了庚基-2H-吡喃-2-one。还检测到烯基衍生物 (E)-6-(hept-1-en-1-yl)-2H-pyran-2-one，之前通过 MS 分析从海洋贵腐菌中初步鉴定出来。所有链烯基吡喃酮均通过使用报道的 Stille 偶联合成，然后进行内酯化，而烷基化吡喃酮是通过报道的合成方法通过 5-烷基戊-2-烯-5-内酯的自由基溴

  DOI：

  10.1002/ejoc.201300049
• 作为产物：
  描述：

  正己醛 在 四(三苯基膦)钯 、 diethylzinc 、 三乙胺 作用下， 以 正己烷 为溶剂， 反应 4.0h， 生成 non-1-en-4-yl acrylate
  参考文献：
  名称：

  2H-Pyran-2-ones from Trichoderma viride and Trichoderma asperellum

  摘要：

  土壤真菌绿色木霉 272 和木霉 328 释放的挥发物通过使用闭环汽提分析 (CLSA) 顶空技术收集，并通过 GC/MS 分析获得的提取物。几种烷基-和链烯基-2H-吡喃-2-酮，包括已知化合物 6-pentyl-2H-pyran-2-one 和 (E)-6-(pent-1-en-1-yl)-2H-pyran -2-one，以及新的衍生物 (E)-6-(pent-2-en-1-yl)-2H-pyran-2-one、6-丙基-2H-pyran-2-one 和 6-发现了庚基-2H-吡喃-2-one。还检测到烯基衍生物 (E)-6-(hept-1-en-1-yl)-2H-pyran-2-one，之前通过 MS 分析从海洋贵腐菌中初步鉴定出来。所有链烯基吡喃酮均通过使用报道的 Stille 偶联合成，然后进行内酯化，而烷基化吡喃酮是通过报道的合成方法通过 5-烷基戊-2-烯-5-内酯的自由基溴

  DOI：

  10.1002/ejoc.201300049

文献信息

• High-Performance Isocyanide Scavengers for Use in Low-Waste Purification of Olefin Metathesis Products
  作者：Grzegorz Szczepaniak、Katarzyna Urbaniak、Celina Wierzbicka、Krzysztof Kosiński、Krzysztof Skowerski、Karol Grela

  DOI：10.1002/cssc.201500784

  日期：2015.12

  even with challenging polar products. The performance of these scavengers is compared and contrasted with other known techniques, such as silica gel filtration and the use of self‐scavenging catalysts. As a result, a new hybrid purification method is devised, which gives better results than using either a self‐scavenging catalyst or a scavenger alone. Additionally, isocyanide II is shown to be a deactivating

  研究了三种含叔氮原子的异氰化物，用作烯烃复分解反应后处理中的小分子钌清除剂。所提出的化合物是无味的，易于获得，并且在去除金属残留物方面非常有效，有时使金属含量低于0.0015 ppm。即使使用极具挑战性的极性产品，测试中最成功的化合物II的性能也非常好。将这些清除剂的性能与其他已知技术（例如硅胶过滤和使用自清除催化剂）进行了比较和对比。结果，设计了一种新的杂化纯化方法，该方法比单独使用自清除催化剂或单独使用清除剂可获得更好的结果。此外，异氰化物II 被证明是烯烃复分解的减活剂（反应猝灭剂），优于乙基乙烯基醚。
• PREPARATIONS COMPRISING DISPERSE DYE AND/OR UV ABSORBER
  申请人：DyStar Colours Distribution GmbH

  公开号：EP2268745B1

  公开（公告）日：2013-12-04
• Mixture Composition Containing Unsaturated Carboxylic Acid and Alkene Ether Derivative Based Copolymers and Copolymers and Terpolymers Containing Sulfo Groups and Use Thereof
  申请人：Maier Markus

  公开号：US20070287817A1

  公开（公告）日：2007-12-13

  The invention relates to a mixture composition having dispersing properties, containing copolymers based on unsaturated mono or dicarboxylic acid derivatives and oxyalkylene ethers as component I and water-soluble copolymers and terpolymers containing sulfo groups having an average molecular weight of 50 000-20 000 000 g/mol as component II. By combining both components, which can be respectively characterized by four different structural units, it is possible to obtain mixture compositions which can, more particularly, be used as dispersing agents for organic and/or inorganic pigments and fillers, in addition to known applications in the field of structural chemistry. In the field of structural chemistry, the mixture compositions are suitable for use on account of the dispersing properties thereof, particularly in ceramic systems and in water-based painting and coating systems. Independently of the dispersing effect thereof, the described mixture compositions are also excellent solvents, wherein they can be used more particularly as casein substitutes, even in self-levelling gap-filling materials and trowelling compounds by virtue of the stabilizing effect thereof. The inventive mixture composition combines known positive properties of components I and II and can be used in new fields of application, even in the non-structural chemistry field.
• Ink composition, ink jet recording method, method for producing planographic printing plate, and planographic printing plate
  申请人：Nakamura Ippei

  公开号：US20080108747A1

  公开（公告）日：2008-05-08

  The invention provides an ink composition comprising a polymerization initiator, a (meth)acrylate having a double bond with a carbon atom having an sp 3 hybrid orbital at an α position, and a colorant; an ink jet recording method using the ink composition; a planographic printing plate obtained by using the ink composition; and a method for producing the planographic printing plate.
• AQUEOUS DISPERSIONS OF SILICA FOR INCREASING EARLY STRENGTH IN CEMENTITIOUS PREPARATIONS
  申请人：Fischer Ulrich

  公开号：US20100324173A1

  公开（公告）日：2010-12-23

  Dispersion which is free of binders and which contains silica and at least one superplasticizer, the silica being a precipitated silica having a surface area greater than 50 m 2 /g, the aggregates and/or agglomerates in the dispersion having a median diameter of less than 1 μm and the proportion of silica being from 5 to 50% by weight, based on the total amount of the dispersion, and a process for the preparation thereof and the use thereof as a concrete admixture in cement-containing preparations.