1,4,6-三氧杂螺[4.4]壬烷 | 176-37-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 1,4,6-三氧杂螺[4.4]壬烷
• 英文名称: 1,4,6-trioxa-spiro[4.4]nonane
• 英文别名: 1,4,6-Trioxa-spiro[4.4]nonan；1,4,6-Trioxaspiro[4.4]nonane
• CAS: 176-37-4
• 化学式: C₆H₁₀O₃
• 分子量: 130.144
• InChiKey: WQWHDRISACGTCO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  环氧乙烷 、 γ-丁内酯 在 四氯化碳 、 boron fluoride ether 作用下， 生成 1,4,6-三氧杂螺[4.4]壬烷
  参考文献：
  名称：

  Bodenbenner, Justus Liebigs Annalen der Chemie, 1959, vol. 623, p. 183,189

  摘要：

  DOI：

文献信息

• SULFONIUM SALT, HEAT- OR PHOTO-ACID GENERATOR, HEAT- OR PHOTO-CURABLE COMPOSITION, AND CURED PRODUCT THEREOF
  申请人：SAN APRO LTD.

  公开号：US20190284134A1

  公开（公告）日：2019-09-19

  The sulfonium salt does not contain a toxic metal and exhibits higher cationic polymerization performance and crosslinking performance than a tetrakis(pentafluorophenyl)borate salt. The heat- or photo-acid generator contains the sulfonium salt. The sulfonium salt is formed of a sulfonium cation selected from a group represented by general formulas (1), (9), (10) and (11) described below and a gallate anion represented by formula (a). The heat- or photo-acid generator contains the sulfonium salt. The heat- or energy ray-curable composition contains the acid generator and a cationically polymerizable compound. A cured product can be obtained by curing the same.

  硫铵盐不含有毒金属，表现出比四(五氟苯基)硼酸盐更高的阳离子聚合性能和交联性能。热或光酸发生剂含有硫铵盐。硫铵盐由下面描述的通用公式(1)、(9)、(10)和(11)所代表的一组硫铵阳离子和由公式(a)代表的镓酸根阴离子形成。热或光酸发生剂含有硫铵盐。热或能量射线固化组合物含有酸发生剂和阳离子聚合性化合物。通过固化可以获得固化产品。
• SULFONIUM SALT, PHOTOACID GENERATOR, PHOTOCURABLE COMPOSITION, AND CURED PRODUCT THEREOF
  申请人：SAN-APRO LTD.

  公开号：US20190300476A1

  公开（公告）日：2019-10-03

  A sulfonium salt is formed of a sulfonium cation selected from a group indicated by general formulas (1), (2), and (3) and a gallate anion represented by formula (a). A photoacid generator is characterized in that said sulfonium salt is contained therein. An energy-ray curable composition contains the acid generator and a cationic polymerizable compound. A cured product is formed by curing these substances.

  一种磺胺盐由通式（1）、（2）和（3）所示的一组磺胺阳离子以及由式（a）表示的没食子酸根阴离子组成。一种光酸发生剂的特征在于其中含有该磺胺盐。一种能量射线固化组合物包含该酸发生剂和一个阳离子可聚合化合物。通过固化这些物质形成一个固化产物。
• SULFONIUM SALT, PHOTOACID GENERATOR, CURABLE COMPOSITION, AND RESIST COMPOSITION
  申请人：SAN-APRO LTD.

  公开号：US20210147352A1

  公开（公告）日：2021-05-20

  The sulfonium salt has high photosensitivity to i-rays and high compatibility with cationically polymerizable compounds such as epoxy compounds, and is excellent storage stability in formulations containing such compounds. The sulfonium salt is represented by general formula (1). In formula (1), R represents an alkyl group or an aryl group; substituents, R1 to R5, each independently represent an alkyl group, a hydroxy group, an alkoxy group, an aryl group, an aryloxy group, a hydroxy(poly)alkyleneoxy group, or a halogen atom; R6 to R9 each independently represent an alkyl group, an aryl group, or a hydrogen atom; m 1 to m 5 each represent the number of occurrences of each of R1 to R5, m 1 and m 4 represent an integer of 0 to 3, m 2 and m 5 represent an integer of 0 to 4, m 3 represents an integer of 0 to 5, and X − represents a monovalent polyatomic anion.

  砜盐对紫外线具有很高的光敏性，与环氧化合物等阳离子聚合物化合物具有很高的相容性，并且在含有这些化合物的配方中具有优异的储存稳定性。砜盐的通用式表示为（1）。在式（1）中，R代表烷基或芳基；取代基R1至R5分别独立地代表烷基、羟基、烷氧基、芳基、芳氧基、羟基(聚)烷氧基或卤素原子；R6至R9分别独立地代表烷基、芳基或氢原子；m1至m5分别代表R1至R5的出现次数，m1和m4表示0到3的整数，m2和m5表示0到4的整数，m3表示0到5的整数，X−表示一价多原子阴离子。
• CURABLE COMPOSITION AND CURED ARTICLE USING SAME
  申请人：SAN-APRO LTD.

  公开号：US20180329297A1

  公开（公告）日：2018-11-15

  The heat- or energy ray-curable composition for members contains an onium gallate salt having a specific structure. The invention is a heat- or energy ray-curable composition comprising a cationic polymerizable compound and an acid generator containing an onium gallate salt represented by general formula (1). In formula (1), R 1 -R 4 are each independently an alkyl group having 1 to 18 carbon atoms or Ar; however, at least one is Ar; Ar is an aryl group having 6 to 14 carbon atoms (not including the number of carbon atoms in the following substituents); some of the hydrogen atoms in the aryl group may be substituted by alkyl groups having 1 to 18 carbon atoms or the like; E represents an element of valence n of group 15 to group 17 (IUPAC notation); n is an integer of 1-3; and R 5 is an organic group bonded to E.

  该成员的热固化或能量光固化组合物包含具有特定结构的酚酸盐。该发明是一种热固化或能量光固化组合物，包括阳离子可聚合化合物和含有由通式（1）表示的酚酸盐的酸发生剂。在通式（1）中，R1-R4分别是具有1至18个碳原子的烷基基团或Ar；但至少有一个是Ar；Ar是具有6至14个碳原子的芳基团（不包括以下取代基中的碳原子数）；芳基团中的一些氢原子可以被具有1至18个碳原子的烷基基团或类似物所取代；E表示15族到17族（IUPAC符号）的n价元素；n是1-3的整数；R5是与E结合的有机基团。
• [EN] DENTAL COMPOSITION<br/>[FR] COMPOSITION DENTAIRE
  申请人：DENTSPLY DETREY GMBH

  公开号：WO2014067666A1

  公开（公告）日：2014-05-08

  A composition comprising a polymerizable compound of the following formula (I) A is a group of the following formula (II) wherein X1 is CO or CS; X2 is a single bond, CO, CS, CH2, or a group Z[X'Z']k, wherein X' is an oxygen atom, a sulfur atom or NR, (wherein R is a hydrogen atom, a straight chain or branched C1-16 alkyl group which may be substituted by a C3-6 cycloalkyl group, a C6-14 aryl or C3-14 heteroaryl group, -COOM, -PO3M, -0-PO3M2 or -SO3M, a C3-6 cycloalkyl group which may be substituted by a C1-16 alkyl group, a C6-14 aryl or C3-14 heteroaryl group, -COOM, -PO3M, -0-PO3M2 or -SO3M, a C6-14 aryl or C3-14 heteroaryl group which may be substituted by -COOM, -PO3M, -O-PO3M2 or -SO3M), Z is a straight chain or branched C1-4 alkylene group, Z' is a bond, a straight chain or branched C1-4 alkylene group, and k is an integer of from 1 to 50; is a monocylic, bicyclic or tricyclic cycloalkyl group having 3 to 20 carbon atoms or a monocylic, bicyclic or tricyclic heterocycloalkyi group having 2 to 20 carbon atoms and 1 to 4 heteroatoms selected from oxygen, sulfur and nitrogen atoms, which groups may be substituted with 1 to 3 groups selected from a C1-16 alkyl group, - COOM, -PO3M, -O-PO3M2 or -SO3M; R1 is a hydrogen atom, -COOM, a straight chain or branched C1-16 alkyl group which may be substituted by a C3-6 cycloalkyl group, a C6-14 aryl or C3-14 heteroaryl group, -COOM, -PO3M, -O-PO3M2 or -SO3M, a C3-6 cycloalkyl group which may be substituted by a C1-16 alkyl group, a C6-14 aryl or C3-14 heteroaryl group, -COOM, -PO3M, -O-PO3M2 or -SO3M, a C6-14 aryl or C3-14 heteroaryl group which may be substituted by -COOM, -PO3M, - O-PO3M2 or -SO3M, R2 is a hydrogen atom, -COOM, a straight chain or branched C1-16 alkyl group which may be substituted by a C6-14 aryl or C3-14 heteroaryl group, -COOM, -PO3M, -O-PO3M2 and -SO3M, a C3-6 cycloalkyl group which may be substituted by a C1-16 alkyl group, a C6-14 aryl or C3-14 heteroaryl group, -COOM, -PO3M, -O-PO3M2 or -SO3M, or a C6-14 aryl or C3-14 heteroaryl group which may be substituted by -COOM, -PO3M, - O-PO3M2 and -SO3M, L is a single bond or an (n+1 ) -valent linker group; B independently is a group according to the definition of A, a group of the following formula (III) wherein X1 independently has the same meaning as defined for X1 in formula (II), CH2, or a group [X'Z]k, wherein X' is an oxygen atom, a sulfur atom or NH, Z is a straight chain or branched C1-4 alkylene group, and k' is an integer of from 1 to 50; R1 and R2 are independent from each other and independently have the same meaning as defined for formula (II), a group of the following formula (IV) wherein X2 independently has the same meaning as defined for X1 in formula (III) wherein X1 independently has the same meaning as defined for X1 in formula (II), CH2, or a group [X'Z]k', wherein X' is an oxygen atom, a sulfur atom or NH, Z is a straight chain or branched C1-4 alkylene group, and k' is an integer of from 1 to 50; R1 and R2 are independent from each other and independently have the same meaning as defined for formula (II), R is a hydrogen atom, a straight chain or branched C1-16 alkyl group which may be substituted by a C3-6 cycloalkyl group, a C6-14 aryl or C3-14 heteroaryl group, -COOM, -PO3M, -O-PO3M2 or -SO3M, a C3-6 cycloalkyl group which may be substituted by a C1-16 alkyl group, a C6-14 aryl or C3-14 heteroaryl group, -COOM, -PO3M, -O- PO3M2 or -SO3M, a C6-14 aryl or C3-14 heteroaryl group which may be substituted by - COOM, -PO3M, -O-PO3M2 or -SO3M, a group of the following formula (V) wherein X3 is CH2, CO, -CH2CO-, CS, or -CH2CS-, R1 and R2 which are independent from each other and independently have the same meaning as defined for formula (II), or a group [ Z'X"]mE, wherein Z' is a straight chain or branched C1-4 alkylene group, X" is an oxygen atom, a sulfur atom or NR, (wherein R is a hydrogen atom, a straight chain or branched C1-16 alkyl group which may be substituted by a C3-6 cycloalkyl group, a C6-14 aryl or C3-14 heteroaryl group, -COOM, -PO3M, -O-PO3M2 or -SO3M, a C3-6 cycloalkyl group which may be substituted by a C1-16 alkyl group, a C6-14 aryl or C3-14 heteroaryl group, -COOM, -PO3M, -O-PO3M2 or-SO3M, a C6-14 aryl or C3-14 heteroaryl group which may be substituted by -COOM, - PO3M, -O-PO3M2 or -SO3M), E is a hydrogen atom, PO3M2, a straight chain or branched C1-16 alkyl group which may be substituted by a C3-6 cycloalkyl group, a C6-14 aryl or C3-14 heteroaryl group, -COOM, -PO3M, -O-PO3M2 or -SO3M, a C3-6 cycloalkyl group which may be substituted by a C1-16 alkyl group, a C6-14 aryl or C3-14 heteroaryl group, -COOM, -PO3M, -O- PO3M2 or -SO3M, a C6-14 aryl or C3-14 heteroaryl group which may be substituted by - COOM, -PO3M, -O-PO3M2 or -SO3M, and m is an integer of from 1 to 10; and n is an integer of from from 1 to 6; wherein M which are independent from each other each represent a hydrogen atom or a metal atom; provided that in case L is a single bond, B cannot be a group according to the definition of A or a group of the formula (III) or (IV).

  一种组合物，包括下式（I）的可聚合化合物，其中A是下式（II）的基团，其中X1是CO或CS；X2是单键，CO，CS，CH2或组Z[X'Z']k，其中X'是氧原子，硫原子或NR（其中R是氢原子，直链或支链C1-16烷基，可被C3-6环烷基，C6-14芳基或C3-14杂芳基取代，-COOM，-PO3M，-0-PO3M2或-SO3M，可被C1-16烷基取代的C3-6环烷基，可被C6-14芳基或C3-14杂芳基取代，-COOM，-PO3M，-0-PO3M2或-SO3M，可被-COOM，-PO3M，-O-PO3M2或-SO3M取代的C6-14芳基或C3-14杂芳基），Z是直链或支链C1-4亚烷基，Z'是键，直链或支链C1-4亚烷基，k是1至50的整数；是具有3至20个碳原子的单环、双环或三环环烷基或具有2至20个碳原子和1至4个氧、硫和氮原子中选择的杂原子的单环、双环或三环杂环烷基，这些基团可以被1至3个C1-16烷基，-COOM，-PO3M，-O-PO3M2或-SO3M取代；R1是氢原子，-COOM，可被C3-6环烷基取代的直链或支链C1-16烷基，可被C6-14芳基或C3-14杂芳基取代，-COOM，-PO3M，-O-PO3M2或-SO3M，可被C1-16烷基取代的C3-6环烷基，可被C6-14芳基或C3-14杂芳基取代，-COOM，-PO3M，-O-PO3M2或-SO3M，可被-COOM，-PO3M，-O-PO3M2或-SO3M取代的C6-14芳基或C3-14杂芳基，R2是氢原子，-COOM，可被C6-14芳基或C3-14杂芳基取代的直链或支链C1-16烷基，-COOM，-PO3M，-O-PO3M2和-SO3M，可被C1-16烷基取代的C3-6环烷基，可被C6-14芳基或C3-14杂芳基取代，-COOM，-PO3M，-O-PO3M2或-SO3M，可被-COOM，-PO3M，-O-PO3M2或-SO3M取代的C6-14芳基或C3-14杂芳基，L是单键或（n+1）-价连接基团；B独立地是A定义的基团，下式（III）的基团，其中X1独立地具有与式（II）中定义的X1相同的含义，CH2或组[X'Z]k'，其中X'是氧原子，硫原子或NH，Z是直链或支链C1-4亚烷基，k'是1至50的整数；R1和R2彼此独立并且独立地具有与式（II）中定义的相同含义，下式（IV）的基团，其中X2独立地具有与式（III）中定义的X1相同的含义，其中X1独立地具有与式（II）中定义的X1相同的含义，CH2或组[X'Z]k'，其中X'是氧原子，硫原子或NH，Z是直链或支链C1-4亚烷基，k'是1至50的整数；R1和R2彼此独立并且独立地具有与式（II）中定义的相同含义，R是氢原子，可被C3-6环烷基取代的直链或支链C1-16烷基，可被C6-14芳基或C3-14杂芳基取代，-COOM，-PO3M，-O-PO3M2或-SO3M，可被C1-16烷基取代的C3-6环烷基，可被C6-14芳基或C3-14杂芳基取代，-COOM，-PO3M，-O-PO3M2或-SO3M，可被-COOM，-PO3M，-O-PO3M2或-SO3M取代的C6-14芳基或C3-14杂芳基，下式（V）的基团，其中X3是CH2，CO，-CH2CO-，CS或-CH2CS-，R1和R2彼此独立并且独立地具有与式（II）中定义的相同含义，或组[Z'X"]mE，其中Z'是直链或支链C1-4亚烷基，X"是氧原子，硫原子或NR（其中R是氢原子，直链或支链C1-16烷基，可被C3-6环烷基，C6-14芳基或C3-14杂芳基取代，-COOM，-PO3M，-O-PO3M2或-SO3M，可被C1-16烷基取代的C3-6环烷基，可被C6-14芳基或C3-14杂芳基取代，-COOM，-PO3M，-O-PO3M2或-SO3M，可被-COOM，-PO3M，-O-PO3M2或-SO3M取代的C6-14芳基或C3-14杂芳基），E是氢原子，PO3M2，可被C3-6环烷基取代的直链或支链C1-16烷基，可被C6-14芳基或C3-14杂芳基取代，-COOM，-PO3M，-O-PO3M2或-SO3M，可被C1-16烷基取代的C3-6环烷基，可被C6-14芳基或C3-14杂芳基取代，-COOM，-PO3M，-O-PO3M2或-SO3M，可被-COOM，-PO3M，-O-PO3M2或-SO3M取代的C6-14芳基或C3-14杂芳基，m是1至10的整数；n是1至6的整数；其中M互相独立地表示氢原子或金属原子；但是，如果L是单键，则B不能是A定义的基团或式（III）或（IV）的基团。