1-methyl-cyclotetradecanol | 67639-36-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-methyl-cyclotetradecanol
• 英文别名: 1-Methylcyclotetradecan-1-ol
• CAS: 67639-36-5
• 化学式: C₁₅H₃₀O
• 分子量: 226.403
• InChiKey: UCPQWKYSQIGROD-UHFFFAOYSA-N

物化性质

• 沸点：
  320.2±10.0 °C(Predicted)
• 密度：
  0.858±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  环十四烷-1-酮 、 甲基锂 生成 1-methyl-cyclotetradecanol
  参考文献：
  名称：

  A study of multiple ring expansion and ring contraction rearrangements in observable cycloalkyl cations

  摘要：

  DOI：

  10.1021/ja00484a037

文献信息

• Trisoxetane compound, process for producing the same, and opitcal waveguide using the same
  申请人：Hikita Takami

  公开号：US20080221341A1

  公开（公告）日：2008-09-11

  The present invention relates to a trisoxetane compound represented by the following formula (1): wherein each of R 1 and R 3 's represents a hydrogen atom or an alkyl group having 1 to 6 carbon atom(s); R 2 represents a divalent aliphatic chained organic group having 0 to 16 carbon atom(s); and A represents a carbon atom or a trivalent organic group derived from a cycloalkane having 3 to 12 carbon atoms; a process for producing the same; and an optical waveguide including the same.

  本发明涉及一种三氧杂环戊烷化合物，其表示为以下式子（1）：其中，R1和R3分别表示氢原子或具有1至6个碳原子的烷基基团；R2表示具有0至16个碳原子的二价脂肪链有机基团；A表示来自具有3至12个碳原子的环己烷衍生的三价有机基团的碳原子或有机基团；以及制备该化合物的方法和包括该化合物的光波导。
• METHOD FOR PRODUCING CARBOXYLIC ACID
  申请人：National Institute of Advanced Industrial Science and Technology

  公开号：EP1544190A1

  公开（公告）日：2005-06-22

  The present invention provides a safe, convenient and efficient method for producing carboxylic acid by a reaction of alicyclic alcohol with an aqueous hydrogen peroxide to thereby obtain carboxylic acid in high yield from alicyclic alcohol or alicyclic ketone under mild reaction conditions, wherein the reaction operation is simple and easy, a step for removing solvent after completion of the reaction is not necessary and influence and toxicity upon the environment and human body are markedly small. In order to provide it, an oily alicyclic alcohol is allowed to react with an aqueous hydrogen peroxide in the presence of a catalyst containing a metal compound belonging to Group 6 of the Periodic Table in a heterogeneous solution system.

  本发明提供了一种安全、方便、高效的生产羧酸的方法，该方法通过脂环醇与过氧化氢水溶液反应，从而在温和的反应条件下，从脂环醇或脂环酮中高产率地获得羧酸，反应操作简单易行，反应完成后无需去除溶剂的步骤，对环境和人体的影响和毒性明显较小。为了实现这一目标，需要在一个异相溶液体系中，在含有元素周期表第 6 族金属化合物的催化剂存在下，使油性脂环醇与过氧化氢水溶液发生反应。
• Method for producing carboxylic acid
  申请人：Sato Kazuhiko

  公开号：US20050215817A1

  公开（公告）日：2005-09-29

  The present invention provides a safe, convenient and efficient method for producing carboxylic acid by a reaction of alicyclic alcohol with an aqueous hydrogen peroxide to thereby obtain carboxylic acid in high yield from alicyclic alcohol or alicyclic ketone under mild reaction conditions, wherein the reaction operation is simple and easy, a step for removing solvent after completion of the reaction is not necessary and influence and toxicity upon the environment and human body are markedly small. In order to provide it, an oily alicyclic alcohol is allowed to react with an aqueous hydrogen peroxide in the presence of a catalyst containing a metal compound belonging to Group 6 of the Periodic Table in a heterogeneous solution system.

  本发明提供了一种安全、方便、高效的生产羧酸的方法，该方法通过脂环醇与过氧化氢水溶液反应，从而在温和的反应条件下，从脂环醇或脂环酮中高产率地获得羧酸，反应操作简单易行，反应完成后无需去除溶剂的步骤，对环境和人体的影响和毒性明显较小。为了实现这一目标，需要在一个异相溶液体系中，在含有元素周期表第 6 族金属化合物的催化剂存在下，使油性脂环醇与过氧化氢水溶液发生反应。
• METHOD FOR PRODUCING CARBOXYLIC ACIDS
  申请人：National Institute of Advanced Industrial Science and Technology

  公开号：EP1544190B1

  公开（公告）日：2011-08-31
• Novel indolopyrrolocarbazole derivative with antitumor activity
  申请人：Yamada Koji

  公开号：US20070042975A1

  公开（公告）日：2007-02-22

  The present invention relates to a novel indolopyrrolocarbazole derivative which is represented by the formula [I]: wherein: A represents O, NH, or CH 2 ; R 1 represents a single bond, a lower alkyl group, a lower alkenyl group, a lower alkynyl group, etc.; R 2 represents a phenyl group, a naphthyl group, or a five- or six-membered aromatic or aliphatic heterocyclic ring having at least one atom selected from N, S, or O, wherein the phenyl group, naphthyl group, aromatic or aliphatic heterocyclic ring may be substituted; and G represents a hexose group or a pentose group, or a pharmaceutically acceptable salt thereof.