3-(4-(9H-carbazol-9-yl)phenyl)-9H-carbazole | 1060735-25-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 3-(4-(9H-carbazol-9-yl)phenyl)-9H-carbazole
• 英文别名: 3-(4-(carbazol-9-yl)phenyl)-9H-carbazole；3-(4-carbazol-9-ylphenyl)-9H-carbazole
• CAS: 1060735-25-2
• 化学式: C₃₀H₂₀N₂
• 分子量: 408.502
• InChiKey: QPILSZIQLNGTGC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  32
• 可旋转键数：
  2
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  20.7
• 氢给体数：
  1
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  9-(4-溴苯基)-10-苯基蒽 、 3-(4-(9H-carbazol-9-yl)phenyl)-9H-carbazole 在 三叔丁基膦 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ sodium t-butanolate 作用下， 以 正己烷 、 甲苯 为溶剂， 以81%的产率得到3-[4-(9H-carbazol-9-yl)phenyl]-9-[4-(10-phenyl-9-anthryl)phenyl]-9H-carbazole
  参考文献：
  名称：

  Organic compound, anthracene derivative, and light-emitting element, light-emitting device, and electronic device using anthracene derivative

  摘要：

  公开号：

  EP1972619B1
• 作为产物：
  描述：

  9-(4-溴苯基)咔唑 在 四(三苯基膦)钯 、 1,1'-双(二苯膦基)二茂铁二氯化钯(II)二氯甲烷复合物 、 potassium acetate 、 potassium carbonate 作用下， 以 1,4-二氧六环 、 乙醇 、 甲苯 为溶剂， 反应 96.0h， 生成 3-(4-(9H-carbazol-9-yl)phenyl)-9H-carbazole
  参考文献：
  名称：

  一种基于二苯甲基自由基的室温有机发光材 料及采用该材料制备的有机电致发光器件

  摘要：

  一种基于二苯甲基自由基的稳定室温有机发光材料及采用该材料制备的有机电致发光器件，属于有机发光技术领域。本发明制备的有机发光材料中，共同的特征是中心的碳自由基，由两个C‑C共价键和一个C‑N共价键构成。稳定性是发光自由基材料在应用时的关键性质，连接给电子基团有利于稳定自由基，本发明中通过将含氮杂环咔唑、吲哚、二甲基吖啶等给电子基团中的氮原子直接与二苯甲基相连，得到稳定的二苯甲基自由基，其稳定性与PTM、TTM相比大幅提高，并拥有室温荧光。采用该材料制备的有机电致发光器件利用双线态激子发光，可以避开传统有机电致发光器件中的三重态激子利用问题，器件的最大外量子效率为0.66％。

  公开号：

  CN108191739B

文献信息

• PHOTOELECTRIC CONVERSION DEVICE AND SENSOR AND ELECTRONIC DEVICE
  申请人：Samsung Electronics Co., Ltd.

  公开号：US20210135125A1

  公开（公告）日：2021-05-06

  Disclosed are a photoelectric conversion device includes a first electrode and a second electrode, a photoelectric conversion layer between the first electrode and the second electrode, the photoelectric conversion layer including a p-type semiconductor and an n-type semiconductor, and an organic buffer layer between the first electrode and the photoelectric conversion layer, the organic buffer layer including an organic buffer material, wherein a difference between a LUMO energy level of the organic buffer material and a LUMO energy level of the n-type semiconductor is greater than or equal to about 1.2 eV and the organic buffer material includes at least three carbazole moieties, and a sensor, and an electronic device including the same.

  揭示了一种光电转换装置，包括第一电极和第二电极，第一电极和第二电极之间的光电转换层，光电转换层包括p型半导体和n型半导体，以及第一电极和光电转换层之间的有机缓冲层，有机缓冲层包括有机缓冲材料，其中有机缓冲材料的LUMO能级与n型半导体的LUMO能级之间的差异大于或等于约1.2电子伏特，有机缓冲材料包括至少三个咔唑基团，以及传感器和包括该传感器的电子设备。
• 신규한 화합물 및 이를 이용한 유기 발광 소자
  申请人：LG CHEM, LTD. 주식회사 엘지화학(120010134563) Corp. No ▼ 110111-2207995BRN ▼107-81-98139

  公开号：KR20210075621A

  公开（公告）日：2021-06-23

  본 발명은 신규한 화합물 및 이를 이용한 유기 발광 소자를 제공한다.

  这项发明提供了一种新的化合物及其用于有机发光器件的应用。
• ORGANIC COMPOUND, ANTHRACENE DERIVATIVE, AND LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, AND ELECTRONIC DEVICE USING ANTHRACENE DERIVATIVE
  申请人：KAWAKAMI Sachiko

  公开号：US20100200847A1

  公开（公告）日：2010-08-12

  Objects of the present invention are to provide novel anthracene derivatives and novel organic compounds; a light-emitting element that has high emission efficiency; a light-emitting element that is capable of emitting blue light with high luminous efficiency; a light-emitting element that is capable of operation for a long time; and a light-emitting device and an electronic device that have lower power consumption. An anthracene derivative represented by a general formula (1) and an organic compound represented by a general formula (17) are provided. A light-emitting element that has high emission efficiency can be obtained by use of the anthracene derivative represented by the general formula (1). Further, a light-emitting element that has a long life can be obtained by use of the anthracene derivative represented by the general formula (1).

  本发明的目的是提供新颖的蒽衍生物和新颖的有机化合物；具有高发射效率的发光元件；能够发射高亮度蓝光的发光元件；能够长时间运行的发光元件；以及具有较低功耗的发光装置和电子设备。本发明提供了由通式（1）表示的蒽衍生物和由通式（17）表示的有机化合物。通过使用通式（1）表示的蒽衍生物，可以获得具有高发射效率的发光元件。此外，通过使用通式（1）表示的蒽衍生物，可以获得具有长寿命的发光元件。
• ORGANIC COMPOUND, ANTHRACENE DERIVATIVE, AND LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, AND ELECTRONIC DEVICE USING THE ANTHRACENE DERIVATIVE
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20150004731A1

  公开（公告）日：2015-01-01

  Objects of the present invention are to provide novel anthracene derivatives and novel organic compounds; a light-emitting element that has high emission efficiency; a light-emitting element that is capable of emitting blue light with high luminous efficiency; a light-emitting element that is capable of operation for a long time; and a light-emitting device and an electronic device that have lower power consumption. An anthracene derivative represented by a general formula (1) and an organic compound represented by a general formula (17) are provided. A light-emitting element that has high emission efficiency can be obtained by use of the anthracene derivative represented by the general formula (1). Further, a light-emitting element that has a long life can be obtained by use of the anthracene derivative represented by the general formula (1).

  本发明的目的是提供新型蒽衍生物和新型有机化合物；具有高发射效率的发光元件；能够以高亮度发射蓝光的发光元件；能够长时间运行的发光元件；以及具有较低功耗的发光设备和电子设备。提供了由通式（1）表示的蒽衍生物和由通式（17）表示的有机化合物。通过使用由通式（1）表示的蒽衍生物，可以获得具有高发射效率的发光元件。此外，通过使用由通式（1）表示的蒽衍生物，可以获得具有长寿命的发光元件。
• Organic compound, anthracene derivative, and light-emitting element, light-emitting device, and electronic device using the anthracene derivative
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US08816098B2

  公开（公告）日：2014-08-26

  Objects of the present invention are to provide novel anthracene derivatives and novel organic compounds; a light-emitting element that has high emission efficiency; a light-emitting element that is capable of emitting blue light with high luminous efficiency; a light-emitting element that is capable of operation for a long time; and a light-emitting device and an electronic device that have lower power consumption. An anthracene derivative represented by a general formula (1) and an organic compound represented by a general formula (17) are provided. A light-emitting element that has high emission efficiency can be obtained by use of the anthracene derivative represented by the general formula (1). Further, a light-emitting element that has a long life can be obtained by use of the anthracene derivative represented by the general formula (1).

  本发明的目的是提供新的蒽衍生物和新的有机化合物；具有高发光效率的发光元件；能够以高亮度发射蓝光的发光元件；能够长时间运行的发光元件；以及具有较低功耗的发光装置和电子设备。提供了一种由通式（1）表示的蒽衍生物和一种由通式（17）表示的有机化合物。通过使用由通式（1）表示的蒽衍生物，可以获得具有高发射效率的发光元件。此外，通过使用由通式（1）表示的蒽衍生物，可以获得寿命长的发光元件。