1-(6-溴己基)-4-乙烯基苯 | 250140-20-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1-(6-溴己基)-4-乙烯基苯
• 英文名称: 1-(6-bromohexyl)-4-vinylbenzene
• 英文别名: 1-(6-Bromohexyl)-4-ethenylbenzene
• CAS: 250140-20-6
• 化学式: C₁₄H₁₉Br
• 分子量: 267.209
• InChiKey: HKRCCUWLVOOAIH-UHFFFAOYSA-N

物化性质

• 沸点：
  104 °C(Press: 0.045 Torr)
• 密度：
  1.174±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  15
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-(6-溴己基)-4-乙烯基苯 在 一水合肼 作用下， 以 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 19.5h， 生成 4-(6-aminohexyl)styrene hydrochloride
  参考文献：
  名称：

  Monomers containing substrate or inhibitor residues for copper amine oxidases and their hydrophilic beaded resins designed for enzyme interaction studies

  摘要：

  Five styrenic monomers, four with aminoalkyl residues typical of copper containing amine oxidase substrates and one with a 2,6-dialkoxybenzylamine residue which mimics previously prepared selective substrate-like benzylamine oxidase inhibitors, have been synthesized and transformed into radical homopolymers, copolymers with N,N-dimethylacrylamide (DMAA), and hydrophilic beaded resins, designed for enzyme interaction studies aimed in finding new materials for highly biospecific chromatographic separations. The five monomers have given beaded resins of 125-500 mum swellable in water with a volume increase of 1200-1500%. The four aminoalkyl monomers have given water soluble copolymers some of which are good substrates of benzylamine oxidase (BAO), diamine oxidase (DAO) and lysyl oxidase (LO), up to 9.7 times better than elastin for LO. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2004.09.083
• 作为产物：
  描述：

  1,6-二溴己烷 在 四(三苯基膦)钯 、 正丁基锂 、 caesium carbonate 作用下， 以 四氢呋喃 、 正己烷 、 水 、 丙酮 为溶剂， 反应 7.0h， 生成 1-(6-溴己基)-4-乙烯基苯
  参考文献：
  名称：

  플루오렌계 화합물, 이를 이용한 유기 발광 소자 및 이의 제조방법

  摘要：

  本规范涉及一种化学式为1的芴类化合物，包括化学式为1的芴类化合物的涂层组合物，有机发光器件以及其制造方法。

  公开号：

  KR20180092270A

文献信息

• 플루오렌계 화합물, 이를 이용한 유기 발광 소자 및 이의 제조방법
  申请人：LG CHEM, LTD. 주식회사 엘지화학(120010134563) Corp. No ▼ 110111-2207995BRN ▼107-81-98139

  公开号：KR20180092270A

  公开（公告）日：2018-08-17

  본 명세서는 화학식 1의 플루오렌계 화합물, 상기 화학식 1의 플루오렌계 화합물을 포함하는 코팅 조성물, 이를 이용한 유기 발광 소자 및 이의 제조 방법에 관한 것이다.

  本规范涉及一种化学式为1的芴类化合物，包括化学式为1的芴类化合物的涂层组合物，有机发光器件以及其制造方法。
• Multi-branched polymer, process for producing the same, and applications thereof
  申请人：——

  公开号：US20040220346A1

  公开（公告）日：2004-11-04

  A group of polymers comprising a plurality of polyolefin chains and polar polymer chains and having a multi-branched structure such as a block structure, a graft structure and a star-shaped structure is produced efficiently by polymerizing or reacting a combination of various polar monomers and their polymers i.e. polar polymer chains by using a functional group-containing polyolefin as a macroinitiator, a macromonomer or a reactive polymer. The resulting multi-branched polymer has a specific shape such as a block structure, a graft structure or a star-shaped structure, and has properties of both the polyolefin and polar polymer, thus exhibiting useful performance in various uses in films and compatibilizing agents as a novel polyolefin-based polymer.

  通过使用含有功能性基团的聚烯烃作为宏启动剂、宏单体或反应性聚合物，聚合或反应各种极性单体及其聚合物即极性聚合物链，可以高效地生产出由多个聚烯烃链和极性聚合物链组成的聚合物群，其具有诸如块状结构、嫁接结构和星形结构等多分支结构。所得到的多分支聚合物具有特定形状，如块状结构、嫁接结构或星形结构，并具有聚烯烃和极性聚合物的性质，因此在薄膜和相容剂等各种用途中表现出有用的性能，是一种新型的基于聚烯烃的聚合物。
• Polyolefin macromonomer, graft polymer obtained from the polyolefin macromonomer, and use thereof
  申请人：——

  公开号：US20040242791A1

  公开（公告）日：2004-12-02

  A novel graft polymer useful in various uses that has a polyolefin backbone having polyolefin segments excellent in moldability can be obtained by homopolymerizing a novel polyolefin macromonomer or polymerizing the novel polyolefin macromonomer in the coexistence of other olefins depending on need, wherein the macromonomer has at the terminal of its polyolefin chain a vinyl group whose &agr;-position may be substituted, and the macromonomer can be efficiently obtained by a method, for example, successively carrying out i) a step of producing a polyolefin having a hydroxyl group at the terminal of the polyolefin chain and ii) a step of converting the terminal hydroxyl group of the polyolefin in chain into an acryloyl group, a methacryloyl group or a styryl group.

  一种新型的移植聚合物，可用于各种用途，具有聚烯烃骨架，其聚烯烃段具有优异的成型性能，可以通过聚合新型聚烯烃大分子单体或在需要时在其他烯烃的共存下聚合新型聚烯烃大分子单体来获得。其中，大分子单体在其聚烯烃链的末端具有一个乙烯基，其α-位可以被取代，通过一种方法可以高效地获得大分子单体，例如连续进行i）生成在聚烯烃链末端具有羟基的聚烯烃的步骤和ii）将聚烯烃的末端羟基转化为丙烯酰基、甲基丙烯酰基或苯乙烯基的步骤。
• FLUORINE-BASED COMPOUND, ORGANIC LIGHT-EMITTING DEVICE USING SAME AND METHOD FOR PREPARING SAME
  申请人：LG Chem, Ltd.

  公开号：EP3514140A1

  公开（公告）日：2019-07-24

  The present specification relates to a fluorene-based compound of Formula 1, a coating composition comprising the fluorene-based compound of Formula 1, an organic light emitting device using the same, and a manufacturing method thereof.

  本说明书涉及式 1 的芴基化合物、包含式 1 的芴基化合物的涂层组合物、使用该化合物的有机发光器件及其制造方法。
• METHOD FOR PRODUCING INK COMPOSITON AND ORGANIC LIGHT EMITTING DEVICE
  申请人：LG CHEM, LTD.

  公开号：EP3663368A1

  公开（公告）日：2020-06-10

  The present specification relates to an ink composition including: a compound represented by Formula 1; and a solvent represented by the Formula 2, and a method for manufacturing an organic light emitting device formed by using the ink composition.

  本说明书涉及一种油墨组合物，其中包括：由式 1 表示的化合物；和由式 2 表示的溶剂，以及使用该油墨组合物形成的有机发光器件的制造方法。