2'-norcocsuline | 39986-72-6

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物
• 英文名称: 2'-norcocsuline
• 英文别名: 12'-O-Desmethyltrilobin；7,6'-epoxy-6-methoxy-2'-methyl-(1'αH)-oxyacanthan-12'-ol；27-Methoxy-7-methyl-15,29,31-trioxa-7,22-diazaoctacyclo[19.9.3.216,19.14,30.110,14.03,8.025,33.028,32]heptatriaconta-1(30),2,4(34),10(37),11,13,16,18,25,27,32,35-dodecaen-13-ol；27-methoxy-7-methyl-15,29,31-trioxa-7,22-diazaoctacyclo[19.9.3.216,19.14,30.110,14.03,8.025,33.028,32]heptatriaconta-1(30),2,4(34),10(37),11,13,16,18,25,27,32,35-dodecaen-13-ol
• CAS: 39986-72-6
• 化学式: C₃₄H₃₂N₂O₅
• 分子量: 548.638
• InChiKey: AVICOTFUCGWABJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  41
• 可旋转键数：
  1
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  72.4
• 氢给体数：
  2
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  重氮甲烷 、 2'-norcocsuline 以 乙醚 为溶剂， 生成 Trilobin
  参考文献：
  名称：

  [来自Anisocyclea grandidieri H. Bn的生物碱。（Menispermaceae）]。

  摘要：

  AbstractFour alkaloids were isolated from Anisocyclea grandidieri (Fam. Menispermaceae). Trilobine and stebisimine have already been found in other menispermaceous plants, whereas (−)‐epistephanine and 12′‐O‐desmethyltrilobine have not been isolated before.

  DOI：

  10.1002/hlca.19720550625

文献信息

• Über die Alkaloide von Anisocyclea grandidieri H. Bn. (Menispermaceae)
  作者：Emil Schlittler、Nikolaus Weber

  DOI：10.1002/hlca.19720550625

  日期：1972.7.10

  AbstractFour alkaloids were isolated from Anisocyclea grandidieri (Fam. Menispermaceae). Trilobine and stebisimine have already been found in other menispermaceous plants, whereas (−)‐epistephanine and 12′‐O‐desmethyltrilobine have not been isolated before.