4,4-Dimethyl-1-phenylhexane-1,3-dione | 107970-97-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4,4-Dimethyl-1-phenylhexane-1,3-dione
• CAS: 107970-97-8
• 化学式: C₁₄H₁₈O₂
• 分子量: 218.296
• InChiKey: QPSQKNYIPKXIFV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  3,3-二甲基-2-戊酮 在 N-ethyl-N-phenylaminomagnesium bromide 、 硫酸 作用下， 以 乙醇 为溶剂， 生成 4,4-Dimethyl-1-phenylhexane-1,3-dione
  参考文献：
  名称：

  Sosnovskikh, V. Ya.; Kostrikova, T. P., Journal of Organic Chemistry USSR (English Translation), 1986, vol. 22, # 4, p. 790 - 791

  摘要：

  DOI：

文献信息

• PHOTO-LATENT TITANIUM CATALYSTS
  申请人：Hintermann Tobias

  公开号：US20120220685A1

  公开（公告）日：2012-08-30

  The present invention provides a photolatent Ti-chelate catalyst formulation, comprising (i) at least one compound of the formula (I) wherein R 1 is C 1 -C 20 alkyl or C 2 -C 20 alkyl which is interrupted by one or more non-consecutive O-atoms; Y is formula (II) or optionally substituted phenyl; Y 1 is formula (III) or optionally substituted phenyl; Y 2 is formula (IV) or optionally substituted phenyl; Y 3 is formula (V) or optionally substituted phenyl; R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 and R 13 independently of each other are hydrogen, halogen, optionally substituted C 1 -C 20 alkyl, or R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 and R 13 independently of each other are optionally substituted C 6 -C 14 aryl, provided that only one of R 2 , R 3 , R 4 is hydrogen and only one of R 5 , R 6 , R 7 is hydrogen and only one of R 8 , R 9 , R 10 is hydrogen and only one of R 11 , R 12 , R 13 is hydrogen; and (ii) at least one chelate ligand compound of the formula IIa, IIb or IIc, wherein Y′ is formula (VI) or formula (VII); Y′ 1 is formula (VIII) or formula (IX); R′ 2 , R′ 3 , R′ 4 , R′ 5 , R′ 6 and R′ 7 independently of each other have on of the meanings as given for R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 and R 13 ; and R′ 14 , R′ 15 and R′ 16 independently of each other have on of the meanings as given for R 14 , R 15 and R 16 .

  本发明提供了一种光潜性钛螯合催化剂配方，包括（i）至少一种式（I）化合物，其中R1是C1-C20烷基或被一个或多个不连续的氧原子打断的C2-C20烷基；Y是式（II）或可选取代的苯基；Y1是式（III）或可选取代的苯基；Y2是式（IV）或可选取代的苯基；Y3是式（V）或可选取代的苯基；R2、R3、R4、R5、R6、R7、R8、R9、R10、R11、R12和R13独立地为氢、卤素、可选取代的C1-C20烷基，或R2、R3、R4、R5、R6、R7、R8、R9、R10、R11、R12和R13独立地为可选取代的C6-C14芳基，但仅有R2、R3、R4中的一个为氢，仅有R5、R6、R7中的一个为氢，仅有R8、R9、R10中的一个为氢，仅有R11、R12、R13中的一个为氢；和（ii）至少一种螯合配体化合物，其为式IIa、IIb或IIc，其中Y'是式（VI）或式（VII）；Y'1是式（VIII）或式（IX）；R'2、R'3、R'4、R'5、R'6和R'7独立地具有R2、R3、R4、R5、R6、R7、R8、R9、R10、R11、R12和R13所给出的含义；R'14、R'15和R'16独立地具有R14、R15和R16所给出的含义之一。
• Photo-latent titanium catalysts
  申请人：Hintermann Tobias

  公开号：US10207261B2

  公开（公告）日：2019-02-19

  The present invention provides a photolatent Ti-chelate catalyst formulation, comprising (i) at least one compound of the formula (I) wherein R1 is C1-C20alkyl or C2-C20alkyl which is interrupted by one or more non-consecutive O-atoms; Y is formula (II) or optionally substituted phenyl; Y1 is formula (III) or optionally substituted phenyl; Y2 is formula (IV) or optionally substituted phenyl; Y3 is formula (V) or optionally substituted phenyl; R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13 independently of each other are hydrogen, halogen, optionally substituted C1-C20alkyl, or R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13 independently of each other are optionally substituted C6-C14aryl, provided that only one of R2, R3, R4 is hydrogen and only one of R5, R6, R7 is hydrogen and only one of R8, R9, R10 is hydrogen and only one of R11, R12, R13 is hydrogen; and (ii) at least one chelate ligand compound of the formula IIa, IIb or IIc, wherein Y′ is formula (VI) or formula (VII); Y′1 is formula (VIII) or formula (IX); R′2, R′3, R′4, R′5, R′6 and R′7 independently of each other have on of the meanings as given for R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13; and R′14, R′15 and R′16 independently of each other have on of the meanings as given for R14, R15 and R16.

  本发明提供了一种光螯合钛催化剂配方，包括(i)至少一种式(I)化合物 其中R1是被一个或多个非连续O原子打断的C1-C20烷基或C2-C20烷基；Y是式(II)或任选取代的苯基；Y1是式(III)或任选取代的苯基；Y2是式(IV)或任选取代的苯基；Y3是式(V)或任选取代的苯基；R2、R3、R4、R5、R6、R7、R8、R9、R10、R11、R12 和 R13 相互独立地是氢、卤素、任选取代的 C1-C20 烷基，或 R2、R3、R4、R5、R6、R7、R8、R9、R10、R11、R12 和 R13 相互独立地是氢、卤素、任选取代的 C1-C20 烷基、R12 和 R13 相互独立地为任选取代的 C6-C14 芳基，条件是 R2、R3、R4 中只有一个是氢，R5、R6、R7 中只有一个是氢，R8、R9、R10 中只有一个是氢，R11、R12、R13 中只有一个是氢；和(ii)至少一种式 IIa、IIb 或 IIc 的螯合配体化合物，其中 Y′为式(VI)或式(VII)；Y′1 为式(VIII)或式(IX)R′2、R′3、R′4、R′5、R′6 和 R′7 相互独立地具有 R2、R3、R4、R5、R6、R7、R8、R9、R10、R11、R12 和 R13 所给出的含义；R′14、R′15 和 R′16 相互独立地具有 R14、R15 和 R16 所具有的含义。
• Sosnovskikh, V. Ya.; Ovsyannikov, I. S., Journal of Organic Chemistry USSR (English Translation), 1990, vol. 26, # 10, p. 1801 - 1805
  作者：Sosnovskikh, V. Ya.、Ovsyannikov, I. S.

  DOI：——

  日期：——
• SOSNOVSKIX, V. YA.;OVSYANNIKOV, I. S., ZH. ORGAN. XIMII, 26,(1990) N0, S. 2086-2091
  作者：SOSNOVSKIX, V. YA.、OVSYANNIKOV, I. S.

  DOI：——

  日期：——
• SOSNOVSKIX, V. YA.;KOSTRIKOVA, T. P., ZH. ORGAN. XIMII, 1986, 22, N 4, 883-884
  作者：SOSNOVSKIX, V. YA.、KOSTRIKOVA, T. P.

  DOI：——

  日期：——