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aluminium(III) bis(2-methyl-8-quinolinolate)phenolate | 146162-49-4

中文名称
——
中文别名
——
英文名称
aluminium(III) bis(2-methyl-8-quinolinolate)phenolate
英文别名
bis(2-methyl-8-quinolinolato)phenolatealuminium(III);[Al(2-methylquinolin-8-olate)2(OC6H5)];2Meq2AlOPh;Al(Mq)2(OPh);Bis[(2-methylquinolin-8-yl)oxy]-phenoxyalumane
aluminium(III) bis(2-methyl-8-quinolinolate)phenolate化学式
CAS
146162-49-4
化学式
C26H21AlN2O3
mdl
——
分子量
436.446
InChiKey
CCAADOWYZMBENE-UHFFFAOYSA-K
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

物化性质

  • 熔点:
    >250 °C

计算性质

  • 辛醇/水分配系数(LogP):
    5.92
  • 重原子数:
    32
  • 可旋转键数:
    2
  • 环数:
    5.0
  • sp3杂化的碳原子比例:
    0.08
  • 拓扑面积:
    53.5
  • 氢给体数:
    0
  • 氢受体数:
    5

上下游信息

  • 上游原料
    中文名称 英文名称 CAS号 化学式 分子量

反应信息

  • 作为产物:
    参考文献:
    名称:
    True Blue:  Blue-Emitting Aluminum(III) Quinolinolate Complexes
    摘要:
    Blue-emitting heteroleptic aluminum(III) bis(2-methyl-8-quinolinolate) phenolate complexes were synthesized. A tunable, blue-to-green emission is achieved by attaching electron-withdrawing modulators to the emisssive quinaldinate ligand. The electronic nature of modulator substituents attached to the position of the highest HOMO (highest occupied molecular orbital) density is used to modulate ligand HOMO levels to achieve effective emission tuning to obtain blue-emitting materials. Optical and electrochemical properties of the resulting complexes were investigated and compared to the results of density functional theory (DFT/B3LYP/6-31G*) studies. The resulting materials may find application as organic light-emitting device materials.
    DOI:
    10.1021/ic061051l
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文献信息

  • Novel aluminum–BODIPY dyads: intriguing dual-emission via photoinduced energy transfer
    作者:Changho Sohn、Jisu Jeong、Ji Hye Lee、Byung Hoon Choi、Hyonseok Hwang、Gyun-Tack Bae、Kang Mun Lee、Myung Hwan Park
    DOI:10.1039/c5dt05067g
    日期:——
    were also determined by single crystal X-ray analysis. In particular, the salen-based heterodinuclear complexes 6 and 7 exhibited higher thermal stability (Td5 = 309 and 306 °C, respectively) than that of the closely related mononuclear aluminum or BODIPY compounds, except for 8. The UV/vis absorption and PL spectra for 6 and 7 indicated a significant photoinduced energy transfer from the aluminum–salen
    三种新颖的基于BODIPY的异双核配合物[salen(3,5- t Bu)2 Al-(OC 6 H 4 -BODIPY)](6),[salen(3,5- t Bu)2 Al-(OC 6 F 2 H 2 -BODIPY)](7)和[(mq)2 Al-(OC 6 H 4 -BODIPY)](8)(salen = N,N'-双(杨基)乙二胺,BODIPY = 4, 4-二-4--3a,4a-二氮杂-小号制备并通过多核NMR表征m- =并四烯和mq =甲基-8-喹啉基。6–8的特定结构也通过单晶X射线分析确定。特别是,除8以外,与紧密相关的单核铝或BODIPY化合物相比,基于salen的异双核配合物6和7表现出更高的热稳定性(分别为T d5 = 309和306°C)。6和7的UV / vis吸收和PL光谱表示以分子内方式从铝salen基团到BODIPY基团的显着光诱导能量转移。理论计算表明,Al
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