disulfanyl bis[11-undecyloxy-(3-benzaldehyde)] | 320722-49-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: disulfanyl bis[11-undecyloxy-(3-benzaldehyde)]
• 英文别名: 3-[11-[11-(3-Formylphenoxy)undecyldisulfanyl]undecoxy]benzaldehyde；3-[11-[11-(3-formylphenoxy)undecyldisulfanyl]undecoxy]benzaldehyde
• CAS: 320722-49-4
• 化学式: C₃₆H₅₄O₄S₂
• 分子量: 614.954
• InChiKey: FLZZVLJMXNFQIM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.4
• 重原子数：
  42
• 可旋转键数：
  29
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.61
• 拓扑面积：
  103
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  、 disulfanyl bis[11-undecyloxy-(3-benzaldehyde)] 在 2,3-二氯-5,6-二氰基-1,4-苯醌 作用下， 以 四氢呋喃 为溶剂， 反应 4.33h， 以53%的产率得到
  参考文献：
  名称：

  Disulfide-Strapped Porphyrins for Monolayer Formation on Gold

  摘要：

  [GRAPHICS]Porphyrins with a disulfide-containing strap have been prepared as an alternative to dithiols for self-assembled monolayer formation on gold surfaces. The strapped porphyrins have the advantage of greater air stability than their dithiol analogues. Cis and trans atropisomers of a strapped porphyrin were isolated. Gold electrodes modified with dithiol and disulfide porphyrins were not identical as evidenced by contact angle or electrochemical measurements.

  DOI：

  10.1021/ol006615i
• 作为产物：
  描述：

  11-溴-1-十一醇 在 碘 、 potassium carbonate 、 caesium carbonate 、 三乙胺 、 PEG 400 作用下， 以 甲醇 、 二氯甲烷 、 氯仿 、 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 112.25h， 生成 disulfanyl bis[11-undecyloxy-(3-benzaldehyde)]
  参考文献：
  名称：

  Disulfide-Strapped Porphyrins for Monolayer Formation on Gold

  摘要：

  [GRAPHICS]Porphyrins with a disulfide-containing strap have been prepared as an alternative to dithiols for self-assembled monolayer formation on gold surfaces. The strapped porphyrins have the advantage of greater air stability than their dithiol analogues. Cis and trans atropisomers of a strapped porphyrin were isolated. Gold electrodes modified with dithiol and disulfide porphyrins were not identical as evidenced by contact angle or electrochemical measurements.

  DOI：

  10.1021/ol006615i

文献信息

• Disulfide-Strapped Porphyrins for Monolayer Formation on Gold
  作者：James E. Redman、Jeremy K. M. Sanders

  DOI：10.1021/ol006615i

  日期：2000.12.1

  [GRAPHICS]Porphyrins with a disulfide-containing strap have been prepared as an alternative to dithiols for self-assembled monolayer formation on gold surfaces. The strapped porphyrins have the advantage of greater air stability than their dithiol analogues. Cis and trans atropisomers of a strapped porphyrin were isolated. Gold electrodes modified with dithiol and disulfide porphyrins were not identical as evidenced by contact angle or electrochemical measurements.